CH3S

• Formula: CH₃S
• Molecular weight: 47.100
• CAS Registry Number: 7175-75-9
• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Other data available:
  • Gas phase ion energetics data
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Vibrational and/or electronic energy levels

Go To: Top, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B

State:   ?

State:   A

State:   X

Additional references: Jacox, 1994, page 237; Jacox, 1998, page 272; Jacox, 2003, page 259; Jacox, 1983; Endo, Saito, et al., 1986; Lee, Chiang, et al., 1990; Hsu and Ng, 1994; Pushkarsky, Applegate, et al., 2000

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Callear and Dickson, 1970
Callear, A.B.; Dickson, D.R., Transient spectra and primary processes in the flash photolysis of CH3SSCH3, CH3SCH3, CH3SH and C2H5SH, Trans. Faraday Soc., 1970, 66, 1987, https://doi.org/10.1039/tf9706601987 . [all data]

Anastasi, Broomfield, et al., 1991
Anastasi, C.; Broomfield, M.; Nielsen, O.J.; Pagsberg, P., Ultraviolet absorption spectra and kinetics of CH3S and CH2SH radicals, Chem. Phys. Lett., 1991, 182, 6, 643, https://doi.org/10.1016/0009-2614(91)90139-Z . [all data]

Bise, Choi, et al., 1999
Bise, R.T.; Choi, H.; Pedersen, H.B.; Mordaunt, D.H.; Neumark, D.M., Photodissociation spectroscopy and dynamics of the methylthio radical (CH[sub 3]S), J. Chem. Phys., 1999, 110, 2, 805, https://doi.org/10.1063/1.478048 . [all data]

Ohbayashi, Akimoto, et al., 1977
Ohbayashi, K.; Akimoto, H.; Tanaka, I., Emission spectrum of CH3S radical, Chem. Phys. Lett., 1977, 52, 1, 47, https://doi.org/10.1016/0009-2614(77)85117-8 . [all data]

Suzuki, Inoue, et al., 1984
Suzuki, M.; Inoue, G.; Akimoto, H., Laser induced fluorescence of CH3S and CD3S radicals, J. Chem. Phys., 1984, 81, 12, 5405, https://doi.org/10.1063/1.447685 . [all data]

Hsu, Liu, et al., 1989
Hsu, Y.-C.; Liu, X.; Miller, T.A., Rotational analysis of A 2A1↔X 2E electronic transition of the jet-cooled methylthio radical, J. Chem. Phys., 1989, 90, 12, 6852, https://doi.org/10.1063/1.456258 . [all data]

Chiang and Lee, 1991
Chiang, S.-Y.; Lee, Y.-P., Vibronic analysis of the A 2A1--X 2E laser-induced fluorescence of jet-cooled CH3S, J. Chem. Phys., 1991, 95, 1, 66, https://doi.org/10.1063/1.461786 . [all data]

Liu, Matsuda, et al., 2003
Liu, C.-P.; Matsuda, Y.; Lee, Y.-P., Highly predissociative levels of CH[sub 3]S (A [sup 2]A[sub 1]) detected with degenerate four-wave mixing, J. Chem. Phys., 2003, 119, 23, 12335, https://doi.org/10.1063/1.1624832 . [all data]

Liu, Reid, et al., 2005
Liu, C.-P.; Reid, S.A.; Lee, Y.-P., Two-color resonant four-wave mixing spectroscopy of highly predissociated levels in the A [sup 2]A[sub 1] state of CH[sub 3]S, J. Chem. Phys., 2005, 122, 12, 124313, https://doi.org/10.1063/1.1867333 . [all data]

Han, Fu, et al., 2011
Han, H.-L.; Fu, L.; Lee, Y.-P., Infrared spectrum of mass-selected CH3S radicals investigated with infrared+vacuum ultraviolet photoionization, Chem. Phys. Lett., 2011, 515, 1-3, 1, https://doi.org/10.1016/j.cplett.2011.06.090 . [all data]

Janousek and Brauman, 1980
Janousek, B.K.; Brauman, J.I., Electron photodetachment of thiomethoxyl and deuterothiomethoxyl anions: Electron affinities, vibrational frequencies, and spin-orbit splitting in CH₃S- and CD₃S-, J. Chem. Phys., 1980, 72, 694. [all data]

Engleking, Ellison, et al., 1978
Engleking, P.C.; Ellison, G.B.; Lineberger, W.C., Laser photodetachment electron spectrometry of methoxide, deuteromethoxide, and thiomethoxide: Electron affinities and vibrational structure of CH₃O, and CH₃S, J. Chem. Phys., 1978, 69, 1826. [all data]

Schwartz, Davico, et al., 2000
Schwartz, R.L.; Davico, G.E.; Lineberger, W.C., Negative-ion photoelectron spectroscopy of CH3S-, J. Electron Spectrosc. Relat. Phenom., 2000, 108, 1-3, 163, https://doi.org/10.1016/S0368-2048(00)00125-0 . [all data]

Bahou and Lee, 2010
Bahou, M.; Lee, Y.-P., Diminished cage effect in solid p-H[sub 2]: Infrared absorption of CH[sub 3]S observed from photolysis in situ of CH[sub 3]SH, CH[sub 3]SCH[sub 3], or CH[sub 3]SSCH[sub 3] isolated in p-H[sub 2] matrices, J. Chem. Phys., 2010, 133, 16, 164316, https://doi.org/10.1063/1.3502105 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Jacox, 1983
Jacox, M.E., The reaction of F atoms with CH, Can. J. Chem., 1983, 61, 5, 1036, https://doi.org/10.1139/v83-182 . [all data]

Endo, Saito, et al., 1986
Endo, Y.; Saito, S.; Hirota, E., The microwave spectrum of the thiomethoxy radical CH3S, J. Chem. Phys., 1986, 85, 4, 1770, https://doi.org/10.1063/1.451178 . [all data]

Lee, Chiang, et al., 1990
Lee, Y.-Y.; Chiang, S.-Y.; Lee, Y.-P., Radiative lifetimes of the A 2A1 (v3=0--2) states of CH3S, J. Chem. Phys., 1990, 93, 6, 4487, https://doi.org/10.1063/1.458687 . [all data]

Hsu and Ng, 1994
Hsu, C.-W.; Ng, C.Y., Nonresonant two-photon pulsed field ionization of CH3S formed in photodissociation of CH3SH and CH3SSCH3, J. Chem. Phys., 1994, 101, 7, 5596, https://doi.org/10.1063/1.467346 . [all data]

Pushkarsky, Applegate, et al., 2000
Pushkarsky, M.B.; Applegate, B.E.; Miller, T.A., Photofragmentation dynamics of the thiomethoxy radical, J. Chem. Phys., 2000, 113, 21, 9649, https://doi.org/10.1063/1.1289461 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.