HSO

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14367 gas A-X 520 960 Schurath, Weber, et al., 1977
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 SO stretch 702 ± 5 gas CL Schurath, Weber, et al., 1977

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 SH stretch 2325 ± 3 gas LF Yoshikawa, Watanabe, et al., 2009
2 Bend 1079 ± 3 gas CL LF Schurath, Weber, et al., 1977
Yoshikawa, Watanabe, et al., 2009
3 SO stretch 1009.36 gas LMR LF Sears and McKellar, 1983
Yoshikawa, Watanabe, et al., 2009

Additional references: Jacox, 1994, page 50; Jacox, 1998, page 154; Kakimoto, Saito, et al., 1980; Ohashi, Kakimoto, et al., 1980; Endo, Saito, et al., 1981; Kawasaki, Kasatani, et al., 1983; Ohashi, Saito, et al., 1988; Takehisa and Ohashi, 1988; Hung and Lee, 1993

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Schurath, Weber, et al., 1977
Schurath, U.; Weber, M.; Becker, K.H., Electronic spectrum and structure of the HSO radical, J. Chem. Phys., 1977, 67, 1, 110, https://doi.org/10.1063/1.434553 . [all data]

Yoshikawa, Watanabe, et al., 2009
Yoshikawa, T.; Watanabe, A.; Sumiyoshi, Y.; Endo, Y., Laser spectroscopy of the 2A´-2A´´ system for the HSO radical, J. Mol. Spectrosc., 2009, 254, 2, 119, https://doi.org/10.1016/j.jms.2009.01.018 . [all data]

Sears and McKellar, 1983
Sears, T.J.; McKellar, A.R.W., The laser magnetic resonance spectrum of the, Mol. Phys., 1983, 49, 1, 25, https://doi.org/10.1080/00268978300101011 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Kakimoto, Saito, et al., 1980
Kakimoto, M.; Saito, S.; Hirota, E., Doppler-limited dye laser excitation spectroscopy of the HSO radical, J. Mol. Spectrosc., 1980, 80, 2, 334, https://doi.org/10.1016/0022-2852(80)90145-9 . [all data]

Ohashi, Kakimoto, et al., 1980
Ohashi, N.; Kakimoto, M.; Saito, S.; Hirota, E., Doppler-limited dye laser excitation spectroscopy of the DSO radical, J. Mol. Spectrosc., 1980, 84, 1, 204, https://doi.org/10.1016/0022-2852(80)90254-4 . [all data]

Endo, Saito, et al., 1981
Endo, Y.; Saito, S.; Hirota, E., Microwave spectra of the HSO and DSO radicals, J. Chem. Phys., 1981, 75, 9, 4379, https://doi.org/10.1063/1.442600 . [all data]

Kawasaki, Kasatani, et al., 1983
Kawasaki, M.; Kasatani, K.; Tanahashi, S.; Sato, H.; Fujimura, Y., Fluorescence lifetimes of single vibrational levels in HSO (A 2A´), J. Chem. Phys., 1983, 78, 12, 7146, https://doi.org/10.1063/1.444754 . [all data]

Ohashi, Saito, et al., 1988
Ohashi, N.; Saito, S.; Suzuki, T.; Hirota, E., Dye laser excitation spectroscopy of two new bands of the DSO radical in 6100-Å region, J. Mol. Spectrosc., 1988, 127, 2, 481, https://doi.org/10.1016/0022-2852(88)90136-1 . [all data]

Takehisa and Ohashi, 1988
Takehisa, Y.; Ohashi, N., Dye laser excitation spectroscopy of the DSO radical in the A2A´(022) ← X2A´´(000) band, J. Mol. Spectrosc., 1988, 130, 1, 221, https://doi.org/10.1016/0022-2852(88)90295-0 . [all data]

Hung and Lee, 1993
Hung, W.C.; Lee, Y.P., J. Chin. Chem. Soc. (Taipei), 1993, 40, 407. [all data]

Notes

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