Butanedioic acid, dimethyl ester

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Condensed phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δcsolid-707.1kcal/molCcbVerkade, Coops, et al., 1926Heat of combustion at 15°C; Corresponding Δfsolid = -198.8 kcal/mol (simple calculation by NIST; no Washburn corrections)

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Tboil470. ± 3.KAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus292. ± 1.KAVGN/AAverage of 11 values; Individual data points
Quantity Value Units Method Reference Comment
Δvap14.6 ± 0.07kcal/molGSVerevkin, Kozlova, et al., 2006Based on data from 286. to 340. K.; AC
Δvap14.7 ± 0.1kcal/molN/AKatayama, 1992Based on data from 342. to 468. K. See also Verevkin, Kozlova, et al., 2006.; AC
Δvap14.6 ± 0.1kcal/molEBDaubert, Jalowka, et al., 1987Based on data from 367. to 460. K. See also Verevkin, Kozlova, et al., 2006.; AC
Δvap14.9kcal/molEBVlasov, Granzhan, et al., 1963Based on data from 398. to 468. K. See also Verevkin, Kozlova, et al., 2006.; AC

Reduced pressure boiling point

Tboil (K) Pressure (atm) Reference Comment
353.20.014Weast and Grasselli, 1989BS

Enthalpy of vaporization

ΔvapH (kcal/mol) Temperature (K) Method Reference Comment
11.8364.AStephenson and Malanowski, 1987Based on data from 340. to 470. K.; AC

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Hydrogen + 2-Butenedioic acid (Z)-, dimethyl ester = Butanedioic acid, dimethyl ester

By formula: H2 + C6H8O4 = C6H10O4

Quantity Value Units Method Reference Comment
Δr-106.8kcal/molChydVeselova and Sul'man, 1980liquid phase

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Verkade, Coops, et al., 1926
Verkade, P.E.; Coops, J.; Hartman, H., Calorimetric researches. XIII. Heats of combustion of successive terms of homologous series: Dimethyl esters of the oxalic acid series. A general survey of the oscillation phenomena, Recl. Trav. Chim. Pays-Bas, 1926, 45, 585-606. [all data]

Verevkin, Kozlova, et al., 2006
Verevkin, Sergey P.; Kozlova, Svetlana A.; Emel'yanenko, Vladimir N.; Nikitin, Eugene D.; Popov, Alexander P.; Krasnykh, Eugen L., Vapor Pressures, Enthalpies of Vaporization, and Critical Parameters of a Series of Linear Aliphatic Dimethyl Esters of Dicarboxylic Acids, J. Chem. Eng. Data, 2006, 51, 5, 1896-1905, https://doi.org/10.1021/je0602418 . [all data]

Katayama, 1992
Katayama, Hirotake, Measurement and estimation of vapor pressures of dimethyl, diethyl, diisopropyl and dibutyl succinates at reduced pressure., J. Chem. Eng. Japan / JCEJ, 1992, 25, 4, 366-372, https://doi.org/10.1252/jcej.25.366 . [all data]

Daubert, Jalowka, et al., 1987
Daubert, T.E.; Jalowka, J.W.; Goren, V., AIChE Symp. Ser., 1987, 83, 128. [all data]

Vlasov, Granzhan, et al., 1963
Vlasov, O.N.; Granzhan, V.A.; Savenko, L.M., Zh. Prikl. Khim., 1963, 36, 2311. [all data]

Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Veselova and Sul'man, 1980
Veselova, M.E.; Sul'man, E.M., Effect of the chemical structure of α,β-unsaturated esters and ketones on the selectivity of their hydrogenation, Svoistva Veshchestv i Stroenie Molekul, Kalinin, 1980, 140-143. [all data]


Notes

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