zirconium dioxide

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 17041 gas A-X 480 587 Le, Steimle, et al., 2011
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 832 gas LF Le, Steimle, et al., 2011
2 Bend 153 gas LF Le, Steimle, et al., 2011
b2 3 Asym. stretch 521 gas LF Le, Steimle, et al., 2011

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 898 gas LF Le, Steimle, et al., 2011
1 Sym. stretch 884.3 Ar IR Chertihin and Andrews, 1995
2 Bend 287 ± 2 gas LF Le, Steimle, et al., 2011
b2 3 Asym. stretch 808 ± 3 gas LF Le, Steimle, et al., 2011
3 Asym. stretch 818.0 Ar IR Chertihin and Andrews, 1995

Additional references: Jacox, 1998, page 176; Jacox, 2003, page 103; Brugh, Suenram, et al., 1999

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Le, Steimle, et al., 2011
Le, A.; Steimle, T.C.; Gupta, V.; Rice, C.A.; Maier, J.P.; Lin, S.H.; Lin, C.-K., The visible spectrum of zirconium dioxide, ZrO2, J. Chem. Phys., 2011, 135, 10, 104303, https://doi.org/10.1063/1.3632053 . [all data]

Chertihin and Andrews, 1995
Chertihin, G.V.; Andrews, L., Reactions of Laser Ablated Titanium, Zirconium, and Hafnium Atoms with Oxygen Molecules in Condensing Argon, J. Phys. Chem., 1995, 99, 17, 6356, https://doi.org/10.1021/j100017a015 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Brugh, Suenram, et al., 1999
Brugh, D.J.; Suenram, R.D.; Stevens, W.J., Fourier transform microwave spectroscopy of jet-cooled ZrO[sub 2] produced by laser vaporization, J. Chem. Phys., 1999, 111, 8, 3526, https://doi.org/10.1063/1.479674 . [all data]

Notes

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