Chloromethylene

• Formula: CHCl
• Molecular weight: 48.472
• IUPAC Standard InChI: InChI=1S/CHCl/c1-2/h1H Copy

  
• IUPAC Standard InChIKey: LKYXEULZVGJVTG-UHFFFAOYSA-N Copy
• CAS Registry Number: 2108-20-5
• Chemical structure:
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• Information on this page:
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A

State:   a

State:   X

Additional references: Jacox, 1994, page 42; Jacox, 1998, page 149; Jacox, 2003, page 37; Kakimoto, Saito, et al., 1983; Yamamoto, Habara, et al., 2001; Lee, Liu, et al., 2002; Lin, Kobayashi, et al., 2002; Tao, Mukarakate, et al., 2007

Notes

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Merer and Travis, 1966
Merer, A.J.; Travis, D.N., ABSORPTION SPECTRA OF HCCl AND DCCl, Can. J. Phys., 1966, 44, 3, 525, https://doi.org/10.1139/p66-047 . [all data]

Qiu, Zhou, et al., 1987
Qiu, Y.; Zhou, S.; Shi, J., Laser-induced fluorescence of HCF and HCCl, Chem. Phys. Lett., 1987, 136, 1, 93, https://doi.org/10.1016/0009-2614(87)87304-9 . [all data]

Xu, Beran, et al., 1994
Xu, S.; Beran, K.A.; Harmony, M.D., Production of Halomethylenes in Free-Jet Expansions from a Hot Nozzle: Identification and Characterization of HCBr and DCBr by Laser-Induced Fluorescence Excitation Spectroscopy, J. Phys. Chem., 1994, 98, 11, 2742, https://doi.org/10.1021/j100062a008 . [all data]

Chang and Sears, 1995
Chang, B.-C.; Sears, T.J., Frequency-modulation transient absorption spectrum of the HCCl A[sup 1]A´´(0,0,0)←X[sup 1]A´(0,0,0) transition, J. Chem. Phys., 1995, 102, 16, 6347, https://doi.org/10.1063/1.1703016 . [all data]

Chang and Sears, 1995, 2
Chang, B.-C.; Sears, T.J., Rotationally Resolved Near-Infrared Spectrum of the HCCI Ã1A´´ ← X1A´ Transition, J. Mol. Spectrosc., 1995, 173, 2, 391, https://doi.org/10.1006/jmsp.1995.1243 . [all data]

Chen, Tsai, et al., 2001
Chen, C.-W.; Tsai, T.-C.; Chang, B.-C., Dispersed fluorescence spectrum of the vibronic transition, Chem. Phys. Lett., 2001, 347, 1-3, 73, https://doi.org/10.1016/S0009-2614(01)01011-9 . [all data]

Fan, Ionescu, et al., 2004
Fan, H.; Ionescu, I.; Annesley, C.; Cummins, J.; Bowers, M.; Reid, S.A., Fluorescence excitation spectroscopy of the system of jet-cooled HCCl in the region 5150--6050Å, J. Mol. Spectrosc., 2004, 225, 1, 43, https://doi.org/10.1016/j.jms.2004.02.013 . [all data]

Lin, Chen, et al., 2004
Lin, C.-S.; Chen, Y.-E.; Chang, B.-C., New electronic spectra of the HCCl and DCCl A-X vibronic bands, J. Chem. Phys., 2004, 121, 9, 4164, https://doi.org/10.1063/1.1779572 . [all data]

Wang, Bird, et al., 2006
Wang, Z.; Bird, R.G.; Yu, H.-G.; Sears, T.J., Hot bands in jet-cooled and ambient temperature spectra of chloromethylene, J. Chem. Phys., 2006, 124, 7, 074314, https://doi.org/10.1063/1.2172238 . [all data]

Tao, Mukarakate, et al., 2006
Tao, C.; Mukarakate, C.; Reid, S.A., Fluorescence excitation and single vibronic level emission spectroscopy of the A [sup 1]A[sup ´´]←X [sup 1]A[sup ´] system of CHCl, J. Chem. Phys., 2006, 124, 22, 224314, https://doi.org/10.1063/1.2204916 . [all data]

Jacox and Milligan, 1967
Jacox, M.E.; Milligan, D.E., Matrix-Isolation Study of the Reaction of Carbon Atoms with HCl. The Infrared Spectrum of the Free Radical HCCl, J. Chem. Phys., 1967, 47, 5, 1626, https://doi.org/10.1063/1.1712143 . [all data]

Tao, Mukarakate, et al., 2008
Tao, C.; Mukarakate, C.; Judge, R.H.; Reid, S.A., High resolution probe of spin-orbit coupling and the singlet-triplet gap in chlorocarbene, J. Chem. Phys., 2008, 128, 17, 171101, https://doi.org/10.1063/1.2918727 . [all data]

Tao, Mukarakate, et al., 2008, 2
Tao, C.; Mukarakate, C.; Terranova, Z.; Ebben, C.; Judge, R.H.; Reid, S.A., High resolution study of spin-orbit mixing and the singlet-triplet gap in chlorocarbene: Stimulated emission pumping spectroscopy of CH[sup 35]Cl and CD[sup 35]Cl, J. Chem. Phys., 2008, 129, 10, 104309, https://doi.org/10.1063/1.2977686 . [all data]

Murray, Leopold, et al., 1988
Murray, K.K.; Leopold, D.G.; Miller, T.M.; Lineberger, W.C., Photoelectron Spectroscopy of the Halocarbene Anions HCF^-, HCCl^-, HCBr^-, HCI^-, CF₂^-, and CCl₂^-, J. Chem. Phys., 1988, 89, 9, 5442, https://doi.org/10.1063/1.455596 . [all data]

Gilles, Ervin, et al., 1992
Gilles, M.K.; Ervin, K.M.; Ho, J.; Lineberger, W.C., Negative Ion Photoelectron Spectroscopy of HCF-, HCCl-, HCBr-, and HCI- - Photoelectron Angular Distributions and Neutral Triplet Excitation, J. Phys. Chem., 1992, 96, 3, 1130, https://doi.org/10.1021/j100182a021 . [all data]

Fridgen, Zhang, et al., 2000
Fridgen, T.D.; Zhang, X.K.; Parnis, J.M.; March, R.E., Isomerization and Fragmentation Products of CH, J. Phys. Chem. A, 2000, 104, 16, 3487, https://doi.org/10.1021/jp993162u . [all data]

Chang, Fei, et al., 1997
Chang, B.-C.; Fei, R.; Sears, T.J., Mid-Infrared Diode Laser Spectroscopy of1A´ HC35Cl, J. Mol. Spectrosc., 1997, 183, 2, 341, https://doi.org/10.1006/jmsp.1997.7291 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Kakimoto, Saito, et al., 1983
Kakimoto, M.; Saito, S.; Hirota, E., Doppler-limited dye laser excitation spectroscopy of HCCl, J. Mol. Spectrosc., 1983, 97, 1, 194, https://doi.org/10.1016/0022-2852(83)90345-4 . [all data]

Yamamoto, Habara, et al., 2001
Yamamoto, S.; Habara, H.; Kim, E.; Nagasaka, H., J. Cnem. Phys., 2001, 115, 6007. [all data]

Lee, Liu, et al., 2002
Lee, C.-L.; Liu, M.-L.; Chang, B.-C., Experimental study of the DCCl X[sup 1]A[sup ´] state vibrational structure by dispersed fluorescence spectroscopy, J. Chem. Phys., 2002, 117, 7, 3263, https://doi.org/10.1063/1.1485768 . [all data]

Lin, Kobayashi, et al., 2002
Lin, A.; Kobayashi, K.; Yu, H.-G.; Hall, G.E.; Muckerman, J.T.; Sears, T.J.; Merer, A.J., Axis-Switching and Coriolis Coupling in the Ã(010)--X(000) Transitions of DCCl and HCCl, J. Mol. Spectrosc., 2002, 214, 2, 216, https://doi.org/10.1006/jmsp.2002.8594 . [all data]

Tao, Mukarakate, et al., 2007
Tao, C.; Mukarakate, C.; Reid, S.A., Electronic spectroscopy of the system of CDCl, J. Mol. Spectrosc., 2007, 241, 2, 143, https://doi.org/10.1016/j.jms.2006.12.001 . [all data]

Notes

Go To: Top, Vibrational and/or electronic energy levels, References

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