Methyl Alcohol

Formula: CH₄O
Molecular weight: 32.0419
IUPAC Standard InChI: InChI=1S/CH4O/c1-2/h2H,1H3
IUPAC Standard InChIKey: OKKJLVBELUTLKV-UHFFFAOYSA-N
CAS Registry Number: 67-56-1
Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript.
Isotopologues:
Other names: Methanol; Carbinol; Methyl hydroxide; Methylol; Monohydroxymethane; Wood alcohol; CH3OH; Colonial spirit; Columbian spirit; Hydroxymethane; Wood naphtha; Alcool methylique; Alcool metilico; Columbian spirits; Metanolo; Methylalkohol; Metylowy alkohol; Pyroxylic spirit; Wood spirit; Rcra waste number U154; UN 1230; Pyro alcohol; Spirit of wood; Bieleski's solution; NSC 85232
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Information on this page:
Other data available:
- Condensed phase thermochemistry data
- Phase change data
- Reaction thermochemistry data: reactions 1 to 50, reactions 51 to 100, reactions 101 to 150, reactions 151 to 200, reactions 201 to 250, reactions 251 to 300
- Henry's Law data
- IR Spectrum
- Gas Chromatography
- Fluid Properties
Data at other public NIST sites:
- Gas Phase Kinetics Database
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Gas phase thermochemistry data

Go To: Top, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References, Notes

Data compiled as indicated in comments:
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity	Value	Units	Method	Reference	Comment
Δ_fH°_gas	-49. ± 3.	kcal/mol	AVG	N/A	Average of 9 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_cH°_gas	-182.52 ± 0.048	kcal/mol	Cm	Rossini, 1932	Flame Calorimetry; Corresponding Δ_fHº_gas = -48.157 kcal/mol (simple calculation by NIST; no Washburn corrections); ALS

Constant pressure heat capacity of gas

C_p,gas (cal/mol*K)	Temperature (K)	Reference	Comment
8.126	50.	Thermodynamics Research Center, 1997	p=1 bar. Recommended entropies and heat capacities are in good agreement with other statistically calculated values [ Ivash E.V., 1955, Zhuravlev E.Z., 1959, Chen S.S., 1977, Chao J., 1986, Gurvich, Veyts, et al., 1989]. Please also see Chao J., 1986, 2.; GT
8.831	100.
9.235	150.
9.491	200.
10.18	273.15
10.53 ± 0.007	298.15
10.56	300.
12.34	400.
14.27	500.
16.06	600.
17.65	700.
19.06	800.
20.30	900.
21.40	1000.
22.36	1100.
23.21	1200.
23.958	1300.
24.613	1400.
25.191	1500.
26.34	1750.
27.20	2000.
27.84	2250.
28.35	2500.
28.7	2750.
28.9	3000.

Constant pressure heat capacity of gas

C_p,gas (cal/mol*K)	Temperature (K)	Reference	Comment
10.13 ± 0.30	279.	Stromsoe E., 1970	Heat capacity at 279 K was obtained by thermal conductivity [ Halford J.O., 1957]. Vapor heat capacities from calorimetric measurements [ De Vries T., 1941] were converted to the ideal gas heat capacities by corrections for the gas imperfection effects [ Chen S.S., 1977, Chao J., 1986, 2]. Ideal gas heat capacities are given by [ Stromsoe E., 1970] as a linear function Cp=f1(a+bT). This expression approximates the experimental values with the average deviation of 1.17 J/molK. The accuracy of the experimental heat capacities [ Stromsoe E., 1970] is estimated as less than 0.3%. Please also see De Vries T., 1941, Weltner W., 1951, Halford J.O., 1957.; GT
11.46 ± 0.30	345.6
11.19 ± 0.28	347.35
11.01 ± 0.30	349.65
11.37 ± 0.28	356.55
11.17 ± 0.30	358.15
11.52 ± 0.30	358.85
11.67 ± 0.30	359.85
12.02 ± 0.30	368.15
11.71 ± 0.28	373.35
12.26 ± 0.30	382.15
12.22 ± 0.28	398.95
12.51 ± 0.30	401.15
12.27 ± 0.28	401.35
12.43 ± 0.10	403.2
12.72 ± 0.30	420.15
12.88 ± 0.28	431.45
13.09 ± 0.28	442.15
13.36 ± 0.30	442.65
13.39 ± 0.28	457.35
13.67 ± 0.10	464.0
13.80 ± 0.28	477.75
13.95 ± 0.28	485.05
14.23 ± 0.28	498.95
14.44 ± 0.30	521.2
14.68 ± 0.28	521.35
15.37 ± 0.28	555.95
15.88 ± 0.28	581.35
15.96 ± 0.28	585.35

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References, Notes

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

View reactions leading to CH₄O⁺ (ion structure unspecified)

Quantity	Value	Units	Method	Reference	Comment
IE (evaluated)	10.84 ± 0.01	eV	N/A	N/A	L
Quantity	Value	Units	Method	Reference	Comment
Proton affinity (review)	180.3	kcal/mol	N/A	Hunter and Lias, 1998	HL
Quantity	Value	Units	Method	Reference	Comment
Gas basicity	173.2	kcal/mol	N/A	Hunter and Lias, 1998	HL

Ionization energy determinations

IE (eV)	Method	Reference	Comment
10.85 ± 0.03	PI	Tao, Klemm, et al., 1992	LL
10.82 ± 0.05	EI	Holmes and Lossing, 1991	LL
10.84 ± 0.07	EI	Bowen and Maccoll, 1984	LBLHLM
10.9	EI	Mishchanchuk, Pokrovskii, et al., 1982	LBLHLM
10.84 ± 0.08	EI	Allam, Migahed, et al., 1982	LBLHLM
10.90 ± 0.03	EI	Sahini, Constantin, et al., 1978	LLK
10.85 ± 0.01	PI	Berkowitz, 1978	LLK
10.846 ± 0.002	PE	MacNeil and Dixon, 1977	LLK
10.90 ± 0.12	EI	Finney and Harrison, 1972	LLK
10.83 ± 0.03	PI	Warneck, 1971	LLK
10.85 ± 0.02	PE	Cocksey, Eland, et al., 1971	LLK
10.85	PE	Baker, Betteridge, et al., 1971	LLK
10.85	PE	Baker, Betteridge, et al., 1971	LLK
10.829 ± 0.015	PI	Omura, Kaneko, et al., 1969	RDSH
10.85	EI	Lifshitz, Shapiro, et al., 1969	RDSH
10.83	PE	Dewar and Worley, 1969	RDSH
10.84 ± 0.02	PI	Refaey and Chupka, 1968	RDSH
10.85	CI	Cermak, 1968	RDSH
10.83	PE	Al-Joboury and Turner, 1964	RDSH
10.85 ± 0.02	PI	Watanabe, 1954	RDSH
10.96	EI	Vorob'ev, Furlei, et al., 1989	Vertical value; LL
11.0	PE	Von Niessen, Bieri, et al., 1980	Vertical value; LLK
10.95	PE	Utsunomiya, Kobayashi, et al., 1980	Vertical value; LLK
10.95	PE	Kobayashi, 1978	Vertical value; LLK
10.86	PE	Benoit and Harrison, 1977	Vertical value; LLK
10.97 ± 0.03	PE	Peel and Willett, 1975	Vertical value; LLK
10.96	PE	Robin and Kuebler, 1973	Vertical value; LLK
10.95	PE	Ogata, Onizuka, et al., 1973	Vertical value; LLK
10.94	PE	Katsumata, Iwai, et al., 1973	Vertical value; LLK
10.95	PE	Ogata, Onizuka, et al., 1972	Vertical value; LLK
10.96	PE	Baker, Betteridge, et al., 1971	Vertical value; LLK

Appearance energy determinations

Ion	AE (eV)	Other Products	Method	Reference	Comment
CH⁺	22.31 ± 0.09	?	EI	Reed and Snedden, 1956	RDSH
CHO⁺	13.06 ± 0.10	H₂+H	PI	Warneck, 1971	LLK
CHO⁺	14.0 ± 0.2	H₂+H	EI	Lifshitz, Shapiro, et al., 1969	RDSH
CH₂⁺	14.05 ± 0.05	H₂O	PI	Warneck, 1971	LLK
CH₂⁺	15.3	H₂O	EI	Haney and Franklin, 1968	RDSH
CH₂O⁺	10.9	H₂	EI	Mishchanchuk, Pokrovskii, et al., 1982	LBLHLM
CH₂O⁺	12.05 ± 0.12	H₂	PI	Warneck, 1971	LLK
CH₂O⁺	12.45	H₂	PI	Refaey and Chupka, 1968	RDSH
CH₃⁺	13.82 ± 0.04	OH	PI	Warneck, 1971	LLK
CH₃⁺	13.5	OH	EI	Friedman, Long, et al., 1957	RDSH
CH₃O⁺	11.67 ± 0.09	H	EI	Bowen and Maccoll, 1984	LBLHLM
CH₃O⁺	10.4	H	EI	Mishchanchuk, Pokrovskii, et al., 1982	LBLHLM
CH₃O⁺	11.85 ± 0.08	H	EI	Allam, Migahed, et al., 1982	LBLHLM
CH₃O⁺	11.88 ± 0.05	H	EI	Selim and Helal, 1981	LLK
CH₃O⁺	11.69	H	EI	Lossing, 1977	LLK
CH₃O⁺	11.76 ± 0.11	H	EI	Finney and Harrison, 1972	LLK
CH₃O⁺	11.55 ± 0.03	H	PI	Warneck, 1971	LLK
CH₃O⁺	11.66 ± 0.04	H	PI	Omura, Kaneko, et al., 1969	RDSH
CH₃O⁺	11.67	H	EI	Lifshitz, Shapiro, et al., 1969	RDSH
CH₃O⁺	11.67 ± 0.03	H	PI	Refaey and Chupka, 1968	RDSH
CH₃O⁺[CH₂OH⁺]	11.649 ± 0.003	H	PI	Berkowitz, Ellison, et al., 1994	Unpublished results of B. Ruscic and J. Berkowitz; LL
CO⁺	13.7	2H₂	EI	Friedman, Long, et al., 1957	RDSH
CO⁺	14.31 ± 0.05	2H₂	EI	Friedland and Strakna, 1956	RDSH

De-protonation reactions

CH₃O^- + = Methyl Alcohol

By formula: CH₃O^- + H⁺ = CH₄O

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	382. ± 2.	kcal/mol	AVG	N/A	Average of 6 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	376.02 ± 0.62	kcal/mol	H-TS	Nee, Osterwalder, et al., 2006	gas phase; B
Δ_rG°	376.04 ± 0.55	kcal/mol	H-TS	Osborn, Leahy, et al., 1998	gas phase; B
Δ_rG°	374.0 ± 2.0	kcal/mol	IMRE	Bartmess, Scott, et al., 1979	gas phase; The acidity is 1.2 kcal/mol stronger than that from the D-EA cycle, due to the multi-compound fit for the acidity scale.; value altered from reference due to change in acidity scale; B
Δ_rG°	374.6 ± 2.1	kcal/mol	H-TS	Haas and Harrison, 1993	gas phase; Both metastable and 50 eV collision energy.; B
Δ_rG°	375.10 ± 0.60	kcal/mol	TDEq	Meot-ner and Sieck, 1986	gas phase; Experimental entropy: 21.5 eu, 0.6 less than H2O; B

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References, Notes

Data compiled as indicated in comments:
B - John E. Bartmess
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
RCD - Robert C. Dunbar

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

+ Methyl Alcohol = ( • )

By formula: Br^- + CH₄O = (Br^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.50 ± 0.10	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	13.9 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	17.6	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	8.00 ± 0.10	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	8.7 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B
Δ_rG°	8.4 ± 2.0	kcal/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..Br- of Hiraoka, Mizure, et al., 19882; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (Br^- • CH₄O) + CH₄O = (Br^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	12.00 ± 0.20	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	12.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20.7	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.62	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	6.3 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (Br^- • 2CH₄O) + CH₄O = (Br^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.50 ± 0.50	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	10.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.6	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.25	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	4.2 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (Br^- • 3CH₄O) + CH₄O = (Br^- • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.9 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.2	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.0 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 4 Methyl Alcohol ) + = ( • 5)

By formula: (Br^- • 4CH₄O) + CH₄O = (Br^- • 5CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.8 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.2	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.3 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 5 Methyl Alcohol ) + = ( • 6)

By formula: (Br^- • 5CH₄O) + CH₄O = (Br^- • 6CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.1 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.6	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.1 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 6 Methyl Alcohol ) + = ( • 7)

By formula: (Br^- • 6CH₄O) + CH₄O = (Br^- • 7CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.9	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.7 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 7 Methyl Alcohol ) + = ( • 8)

By formula: (Br^- • 7CH₄O) + CH₄O = (Br^- • 8CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.4 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.1	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.5 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 8 Methyl Alcohol ) + = ( • 9)

By formula: (Br^- • 8CH₄O) + CH₄O = (Br^- • 9CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.2 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.	cal/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.3 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

( • 9 Methyl Alcohol ) + = ( • 10)

By formula: (Br^- • 9CH₄O) + CH₄O = (Br^- • 10CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.0 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.	cal/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.1 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

CHO^- + Methyl Alcohol = (CHO^- • )

By formula: CHO^- + CH₄O = (CHO^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	28.8	kcal/mol	PHPMS	Meot-ner and Sieck, 1986	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.7	cal/mol*K	PHPMS	Meot-ner and Sieck, 1986	gas phase; M

+ Methyl Alcohol = ( • )

By formula: CHO₂^- + CH₄O = (CHO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.6 ± 1.0	kcal/mol	N/A	Meot-Ner and Sieck, 1986	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.6	cal/mol*K	PHPMS	Meot-Ner and Sieck, 1986	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.5 ± 1.6	kcal/mol	TDAs	Meot-Ner and Sieck, 1986	gas phase; B

CH₃O^- + Methyl Alcohol = (CH₃O^- • )

By formula: CH₃O^- + CH₄O = (CH₃O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	29.3 ± 1.0	kcal/mol	TDAs	Paul and Kebarle, 1990	gas phase; B,M
Δ_rH°	28.80 ± 0.30	kcal/mol	TDAs	Meot-ner and Sieck, 1986	gas phase; B,M
Δ_rH°	29.4 ± 2.5	kcal/mol	TDAs	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Δ_rH°	19.0 ± 2.0	kcal/mol	N/A	Moylan, Dodd, et al., 1985	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	31.8	cal/mol*K	PHPMS	Paul and Kebarle, 1990	gas phase; M
Δ_rS°	26.7	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	20.30	kcal/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	19.8 ± 1.0	kcal/mol	TDAs	Paul and Kebarle, 1990	gas phase; B
Δ_rG°	20.80 ± 0.50	kcal/mol	TDAs	Meot-ner and Sieck, 1986	gas phase; B
Δ_rG°	20.3 ± 1.6	kcal/mol	TDAs	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
19.1	296.	FA	MacKay and Bohme, 1978	gas phase; From thermochemical cycle,switching reaction(CH3O-)H2O; Meot-Ner(Mautner), 1986; M

(CH₃O^- • Methyl Alcohol ) + = (CH₃O^- • 2)

By formula: (CH₃O^- • CH₄O) + CH₄O = (CH₃O^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.4	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.8	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M

(CH₃O^- • 2 Methyl Alcohol ) + = (CH₃O^- • 3)

By formula: (CH₃O^- • 2CH₄O) + CH₄O = (CH₃O^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.0	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.3	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M

(CH₃O^- • 3 Methyl Alcohol ) + = (CH₃O^- • 4)

By formula: (CH₃O^- • 3CH₄O) + CH₄O = (CH₃O^- • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.4	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.4	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M

(CH₃O^- • ) + Methyl Alcohol = (CH₃O^- • • )

By formula: (CH₃O^- • H₂O) + CH₄O = (CH₃O^- • CH₄O • H₂O)

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
13.7	296.	FA	MacKay and Bohme, 1978	gas phase; From thermochemical cycle,switching reaction(CH3O-)2H2O; Meot-Ner(Mautner), 1986; M

CH₅O⁺ + Methyl Alcohol = (CH₅O⁺ • )

By formula: CH₅O⁺ + CH₄O = (CH₅O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	32.6	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	32.3	kcal/mol	PHPMS	Szulejko and McMahon, 1992	gas phase; M
Δ_rH°	32.1	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rH°	33.1	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Δ_rH°	33.7	kcal/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.0	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	29.2	cal/mol*K	PHPMS	Szulejko and McMahon, 1992	gas phase; M
Δ_rS°	26.6	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rS°	30.5	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Δ_rS°	28.5	cal/mol*K	N/A	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	25.2	kcal/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O; Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

(CH₅O⁺ • Methyl Alcohol ) + = (CH₅O⁺ • 2)

By formula: (CH₅O⁺ • CH₄O) + CH₄O = (CH₅O⁺ • 2CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.2	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	21.0	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rH°	21.3	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.0	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	25.8	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; M
Δ_rS°	28.2	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 2 Methyl Alcohol ) + = (CH₅O⁺ • 3)

By formula: (CH₅O⁺ • 2CH₄O) + CH₄O = (CH₅O⁺ • 3CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.0	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	16.1	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.0	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	28.9	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 3 Methyl Alcohol ) + = (CH₅O⁺ • 4)

By formula: (CH₅O⁺ • 3CH₄O) + CH₄O = (CH₅O⁺ • 4CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.3	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	13.5	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.3	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	28.7	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 4 Methyl Alcohol ) + = (CH₅O⁺ • 5)

By formula: (CH₅O⁺ • 4CH₄O) + CH₄O = (CH₅O⁺ • 5CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.2	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	12.5	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.5	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	31.1	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 5 Methyl Alcohol ) + = (CH₅O⁺ • 6)

By formula: (CH₅O⁺ • 5CH₄O) + CH₄O = (CH₅O⁺ • 6CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.3	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	11.9	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.5	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	32.9	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 6 Methyl Alcohol ) + = (CH₅O⁺ • 7)

By formula: (CH₅O⁺ • 6CH₄O) + CH₄O = (CH₅O⁺ • 7CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.0	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rH°	12.0	kcal/mol	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.7	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Δ_rS°	35.7	cal/mol*K	PHPMS	Grimsrud and Kebarle, 1973	gas phase; M

(CH₅O⁺ • 7 Methyl Alcohol ) + = (CH₅O⁺ • 8)

By formula: (CH₅O⁺ • 7CH₄O) + CH₄O = (CH₅O⁺ • 8CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.4	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.9	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

(CH₅O⁺ • 8 Methyl Alcohol ) + = (CH₅O⁺ • 9)

By formula: (CH₅O⁺ • 8CH₄O) + CH₄O = (CH₅O⁺ • 9CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.1	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.9	200.	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

(CH₅O⁺ • 9 Methyl Alcohol ) + = (CH₅O⁺ • 10)

By formula: (CH₅O⁺ • 9CH₄O) + CH₄O = (CH₅O⁺ • 10CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.7	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.5	200.	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

(CH₅O⁺ • 10 Methyl Alcohol ) + = (CH₅O⁺ • 11)

By formula: (CH₅O⁺ • 10CH₄O) + CH₄O = (CH₅O⁺ • 11CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.6	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.8	184.	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

(CH₅O⁺ • 11 Methyl Alcohol ) + = (CH₅O⁺ • 12)

By formula: (CH₅O⁺ • 11CH₄O) + CH₄O = (CH₅O⁺ • 12CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.5	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.7	184.	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

(CH₅O⁺ • 12 Methyl Alcohol ) + = (CH₅O⁺ • 13)

By formula: (CH₅O⁺ • 12CH₄O) + CH₄O = (CH₅O⁺ • 13CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.6	kcal/mol	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.8	184.	PHPMS	Meot-Ner (Mautner), 1992	gas phase; M

(CH₅O⁺ • Methyl Alcohol • ) + = (CH₅O⁺ • 2 • )

By formula: (CH₅O⁺ • CH₄O • H₂O) + CH₄O = (CH₅O⁺ • 2CH₄O • H₂O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	16.4	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.5	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M

(CH₅O⁺ • ) + Methyl Alcohol = (CH₅O⁺ • • )

By formula: (CH₅O⁺ • H₂O) + CH₄O = (CH₅O⁺ • CH₄O • H₂O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	24.5	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.	cal/mol*K	N/A	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
11.6	452.	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n, Entropy change calculated or estimated; M

(CH₅O⁺ • 2) + Methyl Alcohol = (CH₅O⁺ • • 2)

By formula: (CH₅O⁺ • 2H₂O) + CH₄O = (CH₅O⁺ • CH₄O • 2H₂O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	18.0	kcal/mol	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.3	cal/mol*K	PHPMS	Meot-Ner(Mautner), 1986	gas phase; n; M

CH₆N⁺ + Methyl Alcohol = (CH₆N⁺ • )

By formula: CH₆N⁺ + CH₄O = (CH₆N⁺ • CH₄O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	19.0	kcal/mol	PHPMS	Meot-Ner, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.2	cal/mol*K	PHPMS	Meot-Ner, 1984	gas phase; M

CN^- + Methyl Alcohol = (CN^- • )

By formula: CN^- + CH₄O = (CN^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.70 ± 0.80	kcal/mol	TDAs	Larson, Szulejko, et al., 1988	gas phase; B,M
Δ_rH°	16.6 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988	gas phase; B
Δ_rH°	16.5 ± 3.5	kcal/mol	IMRE	Larson and McMahon, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.	cal/mol*K	PHPMS	Larson, Szulejko, et al., 1988	gas phase; M
Δ_rS°	24.3	cal/mol*K	N/A	Larson and McMahon, 1987	gas phase; switching reaction,Thermochemical ladder(CN-)H2O, Entropy change calculated or estimated; Payzant, Yamdagni, et al., 1971; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	8.80 ± 0.20	kcal/mol	TDAs	Larson, Szulejko, et al., 1988	gas phase; B
Δ_rG°	10.4 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988	gas phase; B
Δ_rG°	9.2 ± 2.3	kcal/mol	IMRE	Larson and McMahon, 1987	gas phase; B,M

C₂H^- + Methyl Alcohol = C₃H₅O^-

By formula: C₂H^- + CH₄O = C₃H₅O^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.6 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; Anchored to MeOH ΔGacid=375.2; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.90	kcal/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	11.6 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; Anchored to MeOH ΔGacid=375.2; B

+ Methyl Alcohol = ( • )

By formula: C₂H₃O₂^- + CH₄O = (C₂H₃O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.6 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.5 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988	gas phase; B

(C₂H₄N⁺ • Methyl Alcohol ) + = (C₂H₄N⁺ • 2)

By formula: (C₂H₄N⁺ • CH₄O) + CH₄O = (C₂H₄N⁺ • 2CH₄O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.9	kcal/mol	PHPMS	El-Shall, Olafsdottir, et al., 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.0	cal/mol*K	PHPMS	El-Shall, Olafsdottir, et al., 1991	gas phase; M

(C₂H₄N⁺ • 2 Methyl Alcohol ) + = (C₂H₄N⁺ • 3)

By formula: (C₂H₄N⁺ • 2CH₄O) + CH₄O = (C₂H₄N⁺ • 3CH₄O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.9	kcal/mol	PHPMS	El-Shall, Olafsdottir, et al., 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.4	cal/mol*K	PHPMS	El-Shall, Olafsdottir, et al., 1991	gas phase; M

(C₂H₄N⁺ • Methyl Alcohol • ) + = (C₂H₄N⁺ • 2 • )

By formula: (C₂H₄N⁺ • CH₄O • C₂H₃N) + CH₄O = (C₂H₄N⁺ • 2CH₄O • C₂H₃N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.7	kcal/mol	PHPMS	El-Shall, Olafsdottir, et al., 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.1	cal/mol*K	PHPMS	El-Shall, Olafsdottir, et al., 1991	gas phase; M

C₂H₄NO₂^- + Methyl Alcohol = C₃H₈NO₃^-

By formula: C₂H₄NO₂^- + CH₄O = C₃H₈NO₃^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.00 ± 0.50	kcal/mol	TDAs	Nieckarz, Atkins, et al., 2008	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	9.5 ± 1.0	kcal/mol	TDAs	Nieckarz, Atkins, et al., 2008	gas phase; B

C₂H₅O⁺ + Methyl Alcohol = (C₂H₅O⁺ • )

By formula: C₂H₅O⁺ + CH₄O = (C₂H₅O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	30.3	kcal/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.9	cal/mol*K	N/A	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	22.3	kcal/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C₂H₅O^- + Methyl Alcohol = (C₂H₅O^- • )

By formula: C₂H₅O^- + CH₄O = (C₂H₅O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	27.3 ± 2.9	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Δ_rH°	25.6 ± 1.9	kcal/mol	CIDT	DeTuri and Ervin, 1999	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.3	cal/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	18.6 ± 2.0	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
13.4	296.	FA	Mackay, Rakshit, et al., 1982	gas phase; From thermochemical cycle,switching reaction(CH3O-)CH3OH; Caldwell and Kebarle, 1986, Taft, 1983; M

C₂H₇O⁺ + Methyl Alcohol = (C₂H₇O⁺ • )

By formula: C₂H₇O⁺ + CH₄O = (C₂H₇O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	26.3	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.1	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

(C₂H₇O⁺ • Methyl Alcohol ) + = (C₂H₇O⁺ • 2)

By formula: (C₂H₇O⁺ • CH₄O) + CH₄O = (C₂H₇O⁺ • 2CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	18.8	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.9	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

(C₂H₇O⁺ • 2 Methyl Alcohol ) + = (C₂H₇O⁺ • 3)

By formula: (C₂H₇O⁺ • 2CH₄O) + CH₄O = (C₂H₇O⁺ • 3CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.9	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	31.2	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

(C₂H₇O⁺ • 3 Methyl Alcohol ) + = (C₂H₇O⁺ • 4)

By formula: (C₂H₇O⁺ • 3CH₄O) + CH₄O = (C₂H₇O⁺ • 4CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.7	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	30.8	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

(C₂H₇O⁺ • Methyl Alcohol • ) + = (C₂H₇O⁺ • 2 • )

By formula: (C₂H₇O⁺ • CH₄O • C₂H₆O) + CH₄O = (C₂H₇O⁺ • 2CH₄O • C₂H₆O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.1	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	30.6	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

(C₂H₇O⁺ • 2 Methyl Alcohol • ) + = (C₂H₇O⁺ • 3 • )

By formula: (C₂H₇O⁺ • 2CH₄O • C₂H₆O) + CH₄O = (C₂H₇O⁺ • 3CH₄O • C₂H₆O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	12.2	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.5	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

(C₂H₇O⁺ • ) + Methyl Alcohol = (C₂H₇O⁺ • • )

By formula: (C₂H₇O⁺ • C₂H₆O) + CH₄O = (C₂H₇O⁺ • CH₄O • C₂H₆O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	18.1	kcal/mol	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	30.6	cal/mol*K	PHPMS	Hiraoka, Grimsrud, et al., 1974	gas phase; n; M

C₂H₇O⁺ + Methyl Alcohol = (C₂H₇O⁺ • )

By formula: C₂H₇O⁺ + CH₄O = (C₂H₇O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	29.6	kcal/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.6	cal/mol*K	N/A	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	21.7	kcal/mol	ICR	Larson and McMahon, 1982	gas phase; switching reaction((CH3)2OH+)(CH3)2O, Entropy change calculated or estimated; Grimsrud and Kebarle, 1973, Lias, Liebman, et al., 1984, Keesee and Castleman, 1986; M

C₂H₇O₂^- + 2 Methyl Alcohol = C₃H₁₁O₃^-

By formula: C₂H₇O₂^- + 2CH₄O = C₃H₁₁O₃^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.4 ± 1.0	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	13.10 ± 0.50	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B

C₂H₇O₂^- + + Methyl Alcohol = C₂H₉O₃^-

By formula: C₂H₇O₂^- + H₂O + CH₄O = C₂H₉O₃^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.8 ± 1.0	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.10 ± 0.50	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B

C₂H₉O₃^- + 2 + Methyl Alcohol = C₂H₁₁O₄^-

By formula: C₂H₉O₃^- + 2H₂O + CH₄O = C₂H₁₁O₄^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.2 ± 1.0	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.90 ± 0.50	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B

+ Methyl Alcohol = ( • )

By formula: C₃H₃N₂^- + CH₄O = (C₃H₃N₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.1	kcal/mol	PHPMS	Meot-Ner (Mautner), 1988	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.2	cal/mol*K	PHPMS	Meot-Ner (Mautner), 1988	gas phase; M

C₃H₇O⁺ + Methyl Alcohol = (C₃H₇O⁺ • )

By formula: C₃H₇O⁺ + CH₄O = (C₃H₇O⁺ • CH₄O)

Bond type: Hydrogen bonds of the type OH-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.1	kcal/mol	PHPMS	Meot-Ner (Mautner), Ross, et al., 1985	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.3	cal/mol*K	PHPMS	Meot-Ner (Mautner), Ross, et al., 1985	gas phase; M

C₃H₇O^- + Methyl Alcohol = (C₃H₇O^- • )

By formula: C₃H₇O^- + CH₄O = (C₃H₇O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	26.9 ± 2.9	kcal/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.3	cal/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	18.2 ± 2.0	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

C₃H₉Si⁺ + Methyl Alcohol = (C₃H₉Si⁺ • )

By formula: C₃H₉Si⁺ + CH₄O = (C₃H₉Si⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	39.2	kcal/mol	PHPMS	Wojtyniak and Stone, 1986	gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.7	cal/mol*K	N/A	Wojtyniak and Stone, 1986	gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
25.3	468.	PHPMS	Wojtyniak and Stone, 1986	gas phase; switching reaction,Thermochemical ladder((CH3)3Si+)H2O, Entropy change calculated or estimated; M

C₃H₉Sn⁺ + Methyl Alcohol = (C₃H₉Sn⁺ • )

By formula: C₃H₉Sn⁺ + CH₄O = (C₃H₉Sn⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	32.6	kcal/mol	PHPMS	Stone and Splinter, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	32.	cal/mol*K	PHPMS	Stone and Splinter, 1984	gas phase; M

C₃H₁₀N⁺ + Methyl Alcohol = (C₃H₁₀N⁺ • )

By formula: C₃H₁₀N⁺ + CH₄O = (C₃H₁₀N⁺ • CH₄O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.1	kcal/mol	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.0	cal/mol*K	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M

(C₃H₁₀N⁺ • Methyl Alcohol ) + = (C₃H₁₀N⁺ • 2)

By formula: (C₃H₁₀N⁺ • CH₄O) + CH₄O = (C₃H₁₀N⁺ • 2CH₄O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.7	kcal/mol	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.8	cal/mol*K	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M

(C₃H₁₀N⁺ • 2 Methyl Alcohol ) + = (C₃H₁₀N⁺ • 3)

By formula: (C₃H₁₀N⁺ • 2CH₄O) + CH₄O = (C₃H₁₀N⁺ • 3CH₄O)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.5	kcal/mol	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.0	cal/mol*K	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M

(C₃H₁₀N⁺ • Methyl Alcohol • ) + = (C₃H₁₀N⁺ • 2 • )

By formula: (C₃H₁₀N⁺ • CH₄O • C₃H₉N) + CH₄O = (C₃H₁₀N⁺ • 2CH₄O • C₃H₉N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.5	kcal/mol	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M

(C₃H₁₀N⁺ • ) + Methyl Alcohol = (C₃H₁₀N⁺ • • )

By formula: (C₃H₁₀N⁺ • C₃H₉N) + CH₄O = (C₃H₁₀N⁺ • CH₄O • C₃H₉N)

Bond type: Hydrogen bonds of the type NH+-O between organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.6	kcal/mol	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.2	cal/mol*K	PHPMS	El-Shall, Daly, et al., 1992	gas phase; M

C₃H₁₁O₃^- + 3 Methyl Alcohol = C₄H₁₅O₄^-

By formula: C₃H₁₁O₃^- + 3CH₄O = C₄H₁₅O₄^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.0 ± 1.0	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	7.20 ± 0.50	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B

C₃H₁₁O₃^- + + 2 Methyl Alcohol = C₃H₁₃O₄^-

By formula: C₃H₁₁O₃^- + H₂O + 2CH₄O = C₃H₁₃O₄^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.8 ± 1.0	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.40 ± 0.50	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B

C₄H₂O₃^- + Methyl Alcohol = (C₄H₂O₃^- • )

By formula: C₄H₂O₃^- + CH₄O = (C₄H₂O₃^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.7 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
4.7	343.	PHPMS	Chowdhury, 1987	gas phase; M

+ Methyl Alcohol = ( • )

By formula: C₄H₄N^- + CH₄O = (C₄H₄N^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	18.6 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988, 2	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.5	cal/mol*K	PHPMS	Meot-ner, 1988, 2	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.4 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988, 2	gas phase; B

C₄H₉O^- + Methyl Alcohol = (C₄H₉O^- • )

By formula: C₄H₉O^- + CH₄O = (C₄H₉O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	25.5 ± 1.0	kcal/mol	TDEq	Meot-Ner and Sieck, 1986	gas phase; B,M
Δ_rH°	23.4 ± 2.2	kcal/mol	CIDT	DeTuri and Ervin, 1999	gas phase; B
Δ_rH°	26.0 ± 2.5	kcal/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.9	cal/mol*K	N/A	Meot-Ner and Sieck, 1986	gas phase; Entropy change calculated or estimated; M
Δ_rS°	29.3	cal/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.20	kcal/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	17.1 ± 1.6	kcal/mol	TDEq	Meot-Ner and Sieck, 1986	gas phase; B
Δ_rG°	17.3 ± 1.6	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; B,M

C₄H₁₁O₂⁺ + Methyl Alcohol = (C₄H₁₁O₂⁺ • )

By formula: C₄H₁₁O₂⁺ + CH₄O = (C₄H₁₁O₂⁺ • CH₄O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	22.0	kcal/mol	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.3	cal/mol*K	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M

(C₄H₁₁O₂⁺ • Methyl Alcohol ) + = (C₄H₁₁O₂⁺ • 2)

By formula: (C₄H₁₁O₂⁺ • CH₄O) + CH₄O = (C₄H₁₁O₂⁺ • 2CH₄O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.4	kcal/mol	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.6	cal/mol*K	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M

(C₄H₁₁O₂⁺ • 2 Methyl Alcohol ) + = (C₄H₁₁O₂⁺ • 3)

By formula: (C₄H₁₁O₂⁺ • 2CH₄O) + CH₄O = (C₄H₁₁O₂⁺ • 3CH₄O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	12.6	kcal/mol	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.0	cal/mol*K	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M

(C₄H₁₁O₂⁺ • 3 Methyl Alcohol ) + = (C₄H₁₁O₂⁺ • 4)

By formula: (C₄H₁₁O₂⁺ • 3CH₄O) + CH₄O = (C₄H₁₁O₂⁺ • 4CH₄O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.2	kcal/mol	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.3	cal/mol*K	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M

(C₄H₁₁O₂⁺ • 4 Methyl Alcohol ) + = (C₄H₁₁O₂⁺ • 5)

By formula: (C₄H₁₁O₂⁺ • 4CH₄O) + CH₄O = (C₄H₁₁O₂⁺ • 5CH₄O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.2	kcal/mol	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.2	cal/mol*K	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M

(C₄H₁₁O₂⁺ • 5 Methyl Alcohol ) + = (C₄H₁₁O₂⁺ • 6)

By formula: (C₄H₁₁O₂⁺ • 5CH₄O) + CH₄O = (C₄H₁₁O₂⁺ • 6CH₄O)

Bond type: Hydrogen bonds between protonated and neutral organics

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.9	kcal/mol	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.0	cal/mol*K	PHPMS	Meot-Ner (Mautner), Sieck, et al., 1994	gas phase; M

C₄H₁₅O₄^- + 4 Methyl Alcohol = C₅H₁₉O₅^-

By formula: C₄H₁₅O₄^- + 4CH₄O = C₅H₁₉O₅^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.4 ± 1.0	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.70 ± 0.50	kcal/mol	TDAs	Meot-Ner(Mautner), 1986	gas phase; B

+ Methyl Alcohol = ( • )

By formula: C₅H₅^- + CH₄O = (C₅H₅^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.2 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988, 2	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.9 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988, 2	gas phase; B

C₅H₁₁O^- + Methyl Alcohol = (C₅H₁₁O^- • )

By formula: C₅H₁₁O^- + CH₄O = (C₅H₁₁O^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	25.7 ± 2.9	kcal/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	17.0 ± 2.0	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

C₆F₄O₂^- + Methyl Alcohol = (C₆F₄O₂^- • )

By formula: C₆F₄O₂^- + CH₄O = (C₆F₄O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.0 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.0	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄ClNO₂^- + Methyl Alcohol = (C₆H₄ClNO₂^- • )

By formula: C₆H₄ClNO₂^- + CH₄O = (C₆H₄ClNO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.4 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
5.4	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄ClNO₂^- + Methyl Alcohol = (C₆H₄ClNO₂^- • )

By formula: C₆H₄ClNO₂^- + CH₄O = (C₆H₄ClNO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.4 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
5.4	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄ClNO₂^- + Methyl Alcohol = (C₆H₄ClNO₂^- • )

By formula: C₆H₄ClNO₂^- + CH₄O = (C₆H₄ClNO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.6 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
5.6	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄FNO₂^- + Methyl Alcohol = (C₆H₄FNO₂^- • )

By formula: C₆H₄FNO₂^- + CH₄O = (C₆H₄FNO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.8 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
5.8	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄FNO₂^- + Methyl Alcohol = (C₆H₄FNO₂^- • )

By formula: C₆H₄FNO₂^- + CH₄O = (C₆H₄FNO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.0 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.0	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄FNO₂^- + Methyl Alcohol = (C₆H₄FNO₂^- • )

By formula: C₆H₄FNO₂^- + CH₄O = (C₆H₄FNO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.8 ± 2.0	kcal/mol	N/A	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.8	cal/mol*K	PHPMS	Chowdhury, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.6 ± 2.0	kcal/mol	TDAs	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₆H₄NO₃^- + Methyl Alcohol = (C₆H₄NO₃^- • )

By formula: C₆H₄NO₃^- + CH₄O = (C₆H₄NO₃^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.0 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₆H₄NO₃^- + Methyl Alcohol = (C₆H₄NO₃^- • )

By formula: C₆H₄NO₃^- + CH₄O = (C₆H₄NO₃^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.8 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₆H₄N₂O₄^- + Methyl Alcohol = (C₆H₄N₂O₄^- • )

By formula: C₆H₄N₂O₄^- + CH₄O = (C₆H₄N₂O₄^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.3 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
2.3	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄N₂O₄^- + Methyl Alcohol = (C₆H₄N₂O₄^- • )

By formula: C₆H₄N₂O₄^- + CH₄O = (C₆H₄N₂O₄^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.3 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.3	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₄N₂O₄^- + Methyl Alcohol = (C₆H₄N₂O₄^- • )

By formula: C₆H₄N₂O₄^- + CH₄O = (C₆H₄N₂O₄^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.8 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
3.8	343.	PHPMS	Chowdhury, 1987	gas phase; M

+ Methyl Alcohol = ( • )

By formula: C₆H₄O₂^- + CH₄O = (C₆H₄O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.5 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
5.5	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₆H₅NO₂^- + Methyl Alcohol = (C₆H₅NO₂^- • )

By formula: C₆H₅NO₂^- + CH₄O = (C₆H₅NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.10 ± 0.20	kcal/mol	TDAs	Sieck, 1985	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.1	cal/mol*K	PHPMS	Sieck, 1985	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	7.30 ± 0.40	kcal/mol	TDAs	Sieck, 1985	gas phase; B
Δ_rG°	6.3 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.3	343.	PHPMS	Chowdhury, 1987	gas phase; M

+ Methyl Alcohol = ( • )

By formula: C₆H₅S^- + CH₄O = (C₆H₅S^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.4	kcal/mol	PHPMS	Sieck and Meot-ner, 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.0	cal/mol*K	PHPMS	Sieck and Meot-ner, 1989	gas phase; M

+ Methyl Alcohol = C₇H₉OS^-

By formula: C₆H₅S^- + CH₄O = C₇H₉OS^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.40 ± 0.10	kcal/mol	TDAs	Sieck and Meot-ner, 1989	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.50 ± 0.30	kcal/mol	TDAs	Sieck and Meot-ner, 1989	gas phase; B

C₆H₉^- + Methyl Alcohol = C₇H₁₃O^-

By formula: C₆H₉^- + CH₄O = C₇H₁₃O^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.8 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; Anchored to MeOH ΔGacid=375.2; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	11.50	kcal/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	10.7 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; Anchored to MeOH ΔGacid=375.2; B

C₆H₁₁S₂^- + Methyl Alcohol = (C₆H₁₁S₂^- • )

By formula: C₆H₁₁S₂^- + CH₄O = (C₆H₁₁S₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.9 ± 2.5	kcal/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	13.2 ± 1.6	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B

+ Methyl Alcohol = ( • )

By formula: C₇F₁₄^- + CH₄O = (C₇F₁₄^- • CH₄O)

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.4	308.	PHPMS	Knighton, Zook, et al., 1990	gas phase; M

C₇H₄F₃NO₂^- + Methyl Alcohol = (C₇H₄F₃NO₂^- • )

By formula: C₇H₄F₃NO₂^- + CH₄O = (C₇H₄F₃NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.6 ± 2.0	kcal/mol	N/A	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.9 ± 1.6	kcal/mol	TDAs	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₇H₄N₂O₂^- + Methyl Alcohol = (C₇H₄N₂O₂^- • )

By formula: C₇H₄N₂O₂^- + CH₄O = (C₇H₄N₂O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.7 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
4.7	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₇H₄N₂O₂^- + Methyl Alcohol = (C₇H₄N₂O₂^- • )

By formula: C₇H₄N₂O₂^- + CH₄O = (C₇H₄N₂O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.5 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
4.5	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₇H₄N₂O₂^- + Methyl Alcohol = (C₇H₄N₂O₂^- • )

By formula: C₇H₄N₂O₂^- + CH₄O = (C₇H₄N₂O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.9 ± 2.0	kcal/mol	N/A	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.6	cal/mol*K	PHPMS	Chowdhury, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.1 ± 2.0	kcal/mol	TDAs	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₇H₇NO₂^- + Methyl Alcohol = (C₇H₇NO₂^- • )

By formula: C₇H₇NO₂^- + CH₄O = (C₇H₇NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.3 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.3	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₇H₇NO₂^- + Methyl Alcohol = (C₇H₇NO₂^- • )

By formula: C₇H₇NO₂^- + CH₄O = (C₇H₇NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.5 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.5	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₇H₇NO₂^- + Methyl Alcohol = (C₇H₇NO₂^- • )

By formula: C₇H₇NO₂^- + CH₄O = (C₇H₇NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.4 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₇H₇NO₃^- + Methyl Alcohol = (C₇H₇NO₃^- • )

By formula: C₇H₇NO₃^- + CH₄O = (C₇H₇NO₃^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.1 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.1	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₇H₇NO₃^- + Methyl Alcohol = (C₇H₇NO₃^- • )

By formula: C₇H₇NO₃^- + CH₄O = (C₇H₇NO₃^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.3 ± 2.0	kcal/mol	N/A	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.4	cal/mol*K	PHPMS	Chowdhury, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.3 ± 2.0	kcal/mol	TDAs	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

C₈H₅^- + Methyl Alcohol = (C₈H₅^- • )

By formula: C₈H₅^- + CH₄O = (C₈H₅^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.5 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; B
Δ_rH°	21.4 ± 2.9	kcal/mol	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.3	cal/mol*K	N/A	Caldwell, Rozeboom, et al., 1984	gas phase; switching reaction(CH3O-)CH3OH, Entropy change calculated or estimated; re-evaluated using Meot-Ner(Mautner), 1986 and Paul and Kebarle, 1990; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	11.0 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; B
Δ_rG°	12.7 ± 2.0	kcal/mol	IMRE	Caldwell, Rozeboom, et al., 1984	gas phase; Reanchored to average data from Paul and Kebarle, 1990 and Meot-ner and Sieck, 1986.; value altered from reference due to change in acidity scale; B,M

C₈H₉NO₂^- + Methyl Alcohol = (C₈H₉NO₂^- • )

By formula: C₈H₉NO₂^- + CH₄O = (C₈H₉NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.3 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
6.3	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₈H₁₇O₄⁺ + Methyl Alcohol = (C₈H₁₇O₄⁺ • )

By formula: C₈H₁₇O₄⁺ + CH₄O = (C₈H₁₇O₄⁺ • CH₄O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	19.5	kcal/mol	PHPMS	Sharma and Kebarle, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	34.0	cal/mol*K	PHPMS	Sharma and Kebarle, 1984	gas phase; M

C₉H₇^- + Methyl Alcohol = C₁₀H₁₁O^-

By formula: C₉H₇^- + CH₄O = C₁₀H₁₁O^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.6 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; Anchored to MeOH ΔGacid=375.2; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.20	kcal/mol	IMRE	Mustanir, Matsuoka, et al., 2006	gas phase; B
Δ_rG°	11.1 ± 2.0	kcal/mol	IMRE	Chabinyc and Brauman, 1999	gas phase; Anchored to MeOH ΔGacid=375.2; B

C₁₀H₄Cl₂O₂^- + Methyl Alcohol = (C₁₀H₄Cl₂O₂^- • )

By formula: C₁₀H₄Cl₂O₂^- + CH₄O = (C₁₀H₄Cl₂O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	<1.5 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
1.5	343.	PHPMS	Chowdhury, 1987	gas phase; DG<; M

+ Methyl Alcohol = ( • )

By formula: C₁₀H₆O₂^- + CH₄O = (C₁₀H₆O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.6 ± 1.6	kcal/mol	IMRE	Chowdhury, Grimsrud, et al., 1987	gas phase; Free energy affinity at 70°C.; B

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
4.6	343.	PHPMS	Chowdhury, 1987	gas phase; M

C₁₀H₂₁O₅⁺ + Methyl Alcohol = (C₁₀H₂₁O₅⁺ • )

By formula: C₁₀H₂₁O₅⁺ + CH₄O = (C₁₀H₂₁O₅⁺ • CH₄O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.0	kcal/mol	PHPMS	Sharma and Kebarle, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.0	cal/mol*K	PHPMS	Sharma and Kebarle, 1984	gas phase; M

C₁₂H₂₅O₆⁺ + Methyl Alcohol = (C₁₂H₂₅O₆⁺ • )

By formula: C₁₂H₂₅O₆⁺ + CH₄O = (C₁₂H₂₅O₆⁺ • CH₄O)

Bond type: Hydrogen bonds with polydentate bonding in positive ions

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.0	kcal/mol	PHPMS	Sharma and Kebarle, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.5	cal/mol*K	PHPMS	Sharma and Kebarle, 1984	gas phase; M

+ Methyl Alcohol = ( • )

By formula: Cl^- + CH₄O = (Cl^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17. ± 3.	kcal/mol	AVG	N/A	Average of 8 values; Individual data points
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.6	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M
Δ_rS°	24.1	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	22.0	cal/mol*K	PHPMS	Sieck, 1985	gas phase; M
Δ_rS°	22.9	cal/mol*K	N/A	Larson and McMahon, 1984	gas phase; switching reaction(Cl-)t-C4H9OH, Entropy change calculated or estimated; French, Ikuta, et al., 1982; M
Δ_rS°	14.8	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; Entropy change is questionable; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	10.1 ± 0.8	kcal/mol	AVG	N/A	Average of 10 values; Individual data points

( • Methyl Alcohol ) + = ( • 2)

By formula: (Cl^- • CH₄O) + CH₄O = (Cl^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.10 ± 0.40	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	13.70 ± 0.20	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B,M
Δ_rH°	14.1 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	13.00 ± 0.70	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.2	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	22.0	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M
Δ_rS°	19.4	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	7.30	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	7.10	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	6.8 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	7.20 ± 0.40	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (Cl^- • 2CH₄O) + CH₄O = (Cl^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.50 ± 0.20	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	10.80 ± 0.30	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B,M
Δ_rH°	11.8 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	12.30 ± 0.60	kcal/mol	N/A	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.9	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	22.7	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M
Δ_rS°	23.6	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.06	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	4.00	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	4.9 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	5.20 ± 0.30	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (Cl^- • 3CH₄O) + CH₄O = (Cl^- • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	10.50	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rH°	11.20 ± 0.60	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.9	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	26.4	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	3.70	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	3.30 ± 0.20	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • 4 Methyl Alcohol ) + = ( • 5)

By formula: (Cl^- • 4CH₄O) + CH₄O = (Cl^- • 5CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.2 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Δ_rH°	10.50 ± 0.50	kcal/mol	N/A	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.7	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Δ_rS°	25.5	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.7 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B
Δ_rG°	2.90 ± 0.10	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • 5 Methyl Alcohol ) + = ( • 6)

By formula: (Cl^- • 5CH₄O) + CH₄O = (Cl^- • 6CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.9 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.2	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.2 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B

( • 6 Methyl Alcohol ) + = ( • 7)

By formula: (Cl^- • 6CH₄O) + CH₄O = (Cl^- • 7CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.0 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20.1	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.0 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B

( • 7 Methyl Alcohol ) + = ( • 8)

By formula: (Cl^- • 7CH₄O) + CH₄O = (Cl^- • 8CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	7.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	19.7	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.7 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B

( • 8 Methyl Alcohol ) + = ( • 9)

By formula: (Cl^- • 8CH₄O) + CH₄O = (Cl^- • 9CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	7.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20.6	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.4 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B

( • 9 Methyl Alcohol ) + = ( • 10)

By formula: (Cl^- • 9CH₄O) + CH₄O = (Cl^- • 10CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	7.4 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20.1	cal/mol*K	PHPMS	Hiraoka and Mizuse, 1987	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.4 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; B

( • 10 Methyl Alcohol ) + = ( • 11)

By formula: (Cl^- • 10CH₄O) + CH₄O = (Cl^- • 11CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	7.3 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; Estimated entropy; single temperature measurement; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20.	cal/mol*K	N/A	Hiraoka and Mizuse, 1987	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.3 ± 1.0	kcal/mol	TDAs	Hiraoka and Mizuse, 1987	gas phase; Estimated entropy; single temperature measurement; B

( • Methyl Alcohol • ) + = ( • 2 • )

By formula: (Cl^- • CH₄O • H₂O) + CH₄O = (Cl^- • 2CH₄O • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.8	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	19.	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • ) + Methyl Alcohol = ( • • )

By formula: (Cl^- • H₂O) + CH₄O = (Cl^- • CH₄O • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.2	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20.9	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • 2) + Methyl Alcohol = ( • • 2)

By formula: (Cl^- • 2H₂O) + CH₄O = (Cl^- • CH₄O • 2H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.4	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	18.1	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

+ Methyl Alcohol = ( • )

By formula: Co⁺ + CH₄O = (Co⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	35.4 ± 1.9	kcal/mol	CIDT	Rodgers and Armentrout, 2000	RCD

+ Methyl Alcohol = ( • )

By formula: Cu⁺ + CH₄O = (Cu⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.4	kcal/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.	cal/mol*K	N/A	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.9	kcal/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

( • Methyl Alcohol ) + = ( • 2)

By formula: (Cu⁺ • CH₄O) + CH₄O = (Cu⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.8	kcal/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.	cal/mol*K	N/A	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	6.3	kcal/mol	HPMS	El-Shall, Schriver, et al., 1989	gas phase; Entropy change calculated or estimated, Cu+ from laser desorption; M

+ Methyl Alcohol = CH₃D₄FO^-

By formula: F^- + CH₄O = CH₃D₄FO^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	29.8 ± 2.0	kcal/mol	TDEq	Wilkinson, Szulejko, et al., 1992	gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	22.4 ± 2.0	kcal/mol	TDEq	Wilkinson, Szulejko, et al., 1992	gas phase; Reported relative to ROH..F-, 0.5 kcal/mol weaker.; B

+ Methyl Alcohol = ( • )

By formula: F^- + CH₄O = (F^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	29.6 ± 2.0	kcal/mol	IMRE	Larson and McMahon, 1983	gas phase; B,M
Δ_rH°	29.4 ± 2.2	kcal/mol	CIDT	DeTuri and Ervin, 1999	gas phase; B
Δ_rH°	23.3 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.0	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Δ_rS°	22.6	cal/mol*K	N/A	Larson and McMahon, 1983	gas phase; switching reaction(F-)H2O, Entropy change calculated or estimated; Arshadi, Yamdagni, et al., 1970; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	22.8 ± 2.0	kcal/mol	IMRE	Larson and McMahon, 1983	gas phase; B,M
Δ_rG°	15.8 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (F^- • CH₄O) + CH₄O = (F^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.30 ± 0.30	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	19.3 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.2	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	12.97	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	12.4 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (F^- • 2CH₄O) + CH₄O = (F^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.10 ± 0.60	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	14.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.2	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	8.06	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	8.2 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (F^- • 3CH₄O) + CH₄O = (F^- • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	12.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.5	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.5 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 4 Methyl Alcohol ) + = ( • 5)

By formula: (F^- • 4CH₄O) + CH₄O = (F^- • 5CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.9 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.3	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.8 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 5 Methyl Alcohol ) + = ( • 6)

By formula: (F^- • 5CH₄O) + CH₄O = (F^- • 6CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.8	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.6 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 6 Methyl Alcohol ) + = ( • 7)

By formula: (F^- • 6CH₄O) + CH₄O = (F^- • 7CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.8 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.5	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.2 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 7 Methyl Alcohol ) + = ( • 8)

By formula: (F^- • 7CH₄O) + CH₄O = (F^- • 8CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.7 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.8	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.7 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 8 Methyl Alcohol ) + = ( • 9)

By formula: (F^- • 8CH₄O) + CH₄O = (F^- • 9CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.2 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.7	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.5 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 9 Methyl Alcohol ) + = ( • 10)

By formula: (F^- • 9CH₄O) + CH₄O = (F^- • 10CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.8 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.1	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.3 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 10 Methyl Alcohol ) + = ( • 11)

By formula: (F^- • 10CH₄O) + CH₄O = (F^- • 11CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.5	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.0 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 11 Methyl Alcohol ) + = ( • 12)

By formula: (F^- • 11CH₄O) + CH₄O = (F^- • 12CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	8.5 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.	cal/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.1 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

F₆S^- + Methyl Alcohol = (F₆S^- • )

By formula: F₆S^- + CH₄O = (F₆S^- • CH₄O)

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
4.5	308.	PHPMS	Knighton, Zook, et al., 1990	gas phase; M

HS^- + Methyl Alcohol = (HS^- • )

By formula: HS^- + CH₄O = (HS^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.0 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988	gas phase; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	11.0 ± 1.0	kcal/mol	TDAs	Meot-ner, 1988	gas phase; B

H₄ClO₂^- + Methyl Alcohol + 2 = CH₈ClO₃^-

By formula: H₄ClO₂^- + CH₄O + 2H₂O = CH₈ClO₃^-

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	10.40 ± 0.20	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rH°	11.40 ± 0.30	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; For solvation by MeOH of core ion; B
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.80	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; B
Δ_rG°	6.00	kcal/mol	TDAs	Evans and Keesee, 1991	gas phase; For solvation by MeOH of core ion; B

+ Methyl Alcohol = ( • )

By formula: I^- + CH₄O = (I^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	11.90 ± 0.20	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	11.3 ± 1.0	kcal/mol	TDAs	Caldwell and Kebarle, 1984	gas phase; B,M
Δ_rH°	11.2	kcal/mol	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Δ_rH°	11.	kcal/mol	PHPMS	Caldwell, Masucci, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	17.1	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Δ_rS°	17.8	cal/mol*K	PHPMS	Caldwell and Kebarle, 1984	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.76	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	6.0 ± 1.0	kcal/mol	TDAs	Caldwell and Kebarle, 1984	gas phase; B
Δ_rG°	5.7 ± 2.0	kcal/mol	IMRE	Tanabe, Morgon, et al., 1996	gas phase; Anchored to H2O..I- of Caldwell and Kebarle, 1984; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (I^- • CH₄O) + CH₄O = (I^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.50 ± 0.20	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	11.1 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.6	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	4.25	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	4.4 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (I^- • 2CH₄O) + CH₄O = (I^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	7.70 ± 0.60	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rH°	9.8 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	22.4	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	3.41	kcal/mol	TDAs	Bogdanov, Peschke, et al., 1999	gas phase; B
Δ_rG°	3.1 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (I^- • 3CH₄O) + CH₄O = (I^- • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.7 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.8	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	2.3 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 4 Methyl Alcohol ) + = ( • 5)

By formula: (I^- • 4CH₄O) + CH₄O = (I^- • 5CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.1	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.5 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 5 Methyl Alcohol ) + = ( • 6)

By formula: (I^- • 5CH₄O) + CH₄O = (I^- • 6CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.6 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.4	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.4 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 6 Methyl Alcohol ) + = ( • 7)

By formula: (I^- • 6CH₄O) + CH₄O = (I^- • 7CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.4 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.0	cal/mol*K	PHPMS	Hiraoka and Yamabe, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	1.1 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; B

( • 7 Methyl Alcohol ) + = ( • 8)

By formula: (I^- • 7CH₄O) + CH₄O = (I^- • 8CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	9.1 ± 1.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.	cal/mol*K	N/A	Hiraoka and Yamabe, 1991	gas phase; Entropy change calculated or estimated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	0.8 ± 2.0	kcal/mol	TDAs	Hiraoka and Yamabe, 1991	gas phase; Entropy estimated.; B

+ Methyl Alcohol = ( • )

By formula: K⁺ + CH₄O = (K⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.9	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; switching reaction,n(K+)H2O; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	31.6	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; switching reaction,n(K+)H2O; M

( • Methyl Alcohol ) + = ( • 2)

By formula: (K⁺ • CH₄O) + CH₄O = (K⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	18.0	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	35.	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (K⁺ • 2CH₄O) + CH₄O = (K⁺ • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	14.5	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	28.	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (K⁺ • 3CH₄O) + CH₄O = (K⁺ • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	12.5	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	29.	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • Methyl Alcohol • ) + = ( • 2 • )

By formula: (K⁺ • CH₄O • H₂O) + CH₄O = (K⁺ • 2CH₄O • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.5	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.3	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • 2 Methyl Alcohol • ) + = ( • 3 • )

By formula: (K⁺ • 2CH₄O • H₂O) + CH₄O = (K⁺ • 3CH₄O • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	12.5	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.6	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • ) + Methyl Alcohol = ( • • )

By formula: (K⁺ • H₂O) + CH₄O = (K⁺ • CH₄O • H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	19.6	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	32.5	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; M

( • 2) + Methyl Alcohol = ( • • 2)

By formula: (K⁺ • 2H₂O) + CH₄O = (K⁺ • CH₄O • 2H₂O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	16.6	kcal/mol	HPMS	Evans and Keesee, 1991	gas phase; switching reaction,n(K+)3H2O; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	30.9	cal/mol*K	HPMS	Evans and Keesee, 1991	gas phase; switching reaction,n(K+)3H2O; M

+ Methyl Alcohol = ( • )

By formula: Li⁺ + CH₄O = (Li⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	36.8 ± 1.9	kcal/mol	CIDT	Rodgers and Armentrout, 2000	RCD
Δ_rH°	38.1	kcal/mol	ICR	Woodin and Beauchamp, 1978	gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Δ_rH°	38.	kcal/mol	ICR	Staley and Beauchamp, 1975	gas phase; switching reaction(Li+)H2O, from graph; Dzidic and Kebarle, 1970 extrapolated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.	cal/mol*K	N/A	Woodin and Beauchamp, 1978	gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	30.3	kcal/mol	ICR	Woodin and Beauchamp, 1978	gas phase; switching reaction(Li+)H20, Entropy change calculated or estimated; Dzidic and Kebarle, 1970 interpolated; M

+ Methyl Alcohol = ( • )

By formula: Mg⁺ + CH₄O = (Mg⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	34.7 ± 1.6	kcal/mol	CIDT	Andersen, Muntean, et al., 2000	RCD
Δ_rH°	61. ± 5.	kcal/mol	PDiss	Operti, Tews, et al., 1988	gas phase; M

( • Methyl Alcohol ) + = ( • 2)

By formula: (Mg⁺ • CH₄O) + CH₄O = (Mg⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	28.8 ± 1.6	kcal/mol	CIDT	Andersen, Muntean, et al., 2000	RCD

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (Mg⁺ • 2CH₄O) + CH₄O = (Mg⁺ • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	21.9 ± 2.1	kcal/mol	CIDT	Andersen, Muntean, et al., 2000	RCD

+ Methyl Alcohol = ( • )

By formula: NO₂^- + CH₄O = (NO₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.40 ± 0.20	kcal/mol	TDAs	Sieck, 1985	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.8	cal/mol*K	PHPMS	Sieck, 1985	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	9.70 ± 0.40	kcal/mol	TDAs	Sieck, 1985	gas phase; B

+ Methyl Alcohol = ( • )

By formula: Na⁺ + CH₄O = (Na⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	23.2 ± 1.3	kcal/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	21.9 ± 1.4	kcal/mol	CIDT	Armentrout and Rodgers, 2000	RCD
Δ_rH°	24.0 ± 0.2	kcal/mol	HPMS	Hoyau, Norrman, et al., 1999	RCD
Δ_rH°	26.6 ± 0.2	kcal/mol	HPMS	Guo, Conklin, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	20500.	cal/mol*K	HPMS	Hoyau, Norrman, et al., 1999	RCD
Δ_rS°	24.3	cal/mol*K	HPMS	Guo, Conklin, et al., 1989	gas phase; M

Free energy of reaction

Δ_rG° (kcal/mol)	T (K)	Method	Reference	Comment
17.3	298.	IMRE	McMahon and Ohanessian, 2000	Anchor alanine=39.89; RCD

( • Methyl Alcohol ) + = ( • 2)

By formula: (Na⁺ • CH₄O) + CH₄O = (Na⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	20.5 ± 1.4	kcal/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	21.4 ± 1.6	kcal/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	20.5 ± 1.6	kcal/mol	CIDC	Amicangelo and Armentrout, 2001	Anchor NH3=24.41; RCD
Δ_rH°	20.2 ± 0.2	kcal/mol	HPMS	Guo, Conklin, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.7	cal/mol*K	HPMS	Guo, Conklin, et al., 1989	gas phase; M

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (Na⁺ • 2CH₄O) + CH₄O = (Na⁺ • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.4 ± 0.4	kcal/mol	HPMS	Guo, Conklin, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	25.1	cal/mol*K	HPMS	Guo, Conklin, et al., 1989	gas phase; M

( • 3 Methyl Alcohol ) + = ( • 4)

By formula: (Na⁺ • 3CH₄O) + CH₄O = (Na⁺ • 4CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.7 ± 0.2	kcal/mol	HPMS	Guo, Conklin, et al., 1989	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	30.0	cal/mol*K	HPMS	Guo, Conklin, et al., 1989	gas phase; M

+ Methyl Alcohol = ( • )

By formula: O₂^- + CH₄O = (O₂^- • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	19.10	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	21.9	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	12.50	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • Methyl Alcohol ) + = ( • 2)

By formula: (O₂^- • CH₄O) + CH₄O = (O₂^- • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	15.50 ± 0.80	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	24.8	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	8.10 ± 0.40	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

( • 2 Methyl Alcohol ) + = ( • 3)

By formula: (O₂^- • 2CH₄O) + CH₄O = (O₂^- • 3CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	13.50 ± 0.70	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B,M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	27.9	cal/mol*K	PHPMS	Yamdagni, Payzant, et al., 1973	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rG°	5.20 ± 0.30	kcal/mol	TDAs	Yamdagni, Payzant, et al., 1973	gas phase; B

+ Methyl Alcohol = ( • )

By formula: Pb⁺ + CH₄O = (Pb⁺ • CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	23.3 ± 0.2	kcal/mol	HPMS	Guo and Castleman, 1990	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	23.3	cal/mol*K	HPMS	Guo and Castleman, 1990	gas phase; M

( • Methyl Alcohol ) + = ( • 2)

By formula: (Pb⁺ • CH₄O) + CH₄O = (Pb⁺ • 2CH₄O)

Quantity	Value	Units	Method	Reference	Comment
Δ_rH°	17.2 ± 0.3	kcal/mol	HPMS	Guo and Castleman, 1990	gas phase; M
Quantity	Value	Units	Method	Reference	Comment
Δ_rS°	26.6	cal/mol*K	HPMS	Guo and Castleman, 1990	gas phase; M

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Vibrational and/or electronic energy levels, References, Notes

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

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Origin	Japan AIST/NIMC Database- Spectrum MS-NW- 72
NIST MS number	229809

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Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), References, Notes

Data compiled by: Takehiko Shimanouchi

Gas Symmetry: C_s Symmetry Number σ = 1

Sym.	No	Approximate	Selected Freq.		Infrared		Raman		Comments

Species		type of mode	Value	Rating	Value	Phase	Value	Phase

a'	1	OH str	3681	A	3681 M	gas
a'	2	CH3 d-str	3000	C	3000 M	gas
a'	3	CH3 s-str	2844	A	2844 S	gas
a'	4	CH3 d-deform	1477	B	1477 M	gas			OV(ν₁₀)
a'	5	CH3 s-deform	1455	A	1455 M	gas
a'	6	OH bend	1345	B	1345 S	gas
a'	7	CH3 rock	1060	D	1060 W	gas			OV(ν₈)
a'	8	CO str	1033	A	1033 VS	gas	1032	gas
a	9	CH3 d-str	2960	C	2960 S	gas	2955	gas
a	10	CH3 d-deform	1477	B	1477 M	gas			OV(ν₄)
a	11	CH3 rock	1165	C			1165	liq.
a	12	Torsion	295	A	80~300	gas			?/? Value of ν₁₂ is undefined because of large coupling between internal & overall rotations.
a	12	Torsion	200	E	80~300	gas			?/? Value of ν₁₂ is undefined because of large coupling between internal & overall rotations.

Source: Shimanouchi, 1972

Liquid Symmetry: C_s Symmetry Number σ = 1

Sym.	No	Approximate	Selected Freq.		Infrared		Raman		Comments

Species		type of mode	Value	Rating	Value	Phase	Value	Phase

a'	1	OH str	3328	D	3328 vb	liq.	3270-3480	liq.
a'	2	CH3 d-str	2980	C	2980 M	liq.	2993	liq.
a'	3	CH3 s-str	2834	C	2834 S	liq.	2834	liq.
a'	4	CH3 d-deform	1480	C	1480 M	liq.	1464	liq.	OV(ν₁₀)
a'	5	CH3 s-deform	1450	C	1450 M	liq.
a'	6	OH bend	1418	C	1418 M b	liq.
a'	7	CH3 rock	1115	C	1115 M	liq.	1107	liq.
a'	8	CO str	1030	C	1030 VS	liq.	1033	liq.
a	9	CH3 d-str	2946	C	2946 S	liq.	2940	liq.
a	10	CH3 d-deform	1480	C	1480 M	liq.	1464	liq.	OV(ν₄)
a	11	CH3 rock	1165	C			1165	liq.
a	12	Torsion	655	D	655 vb	liq.

Source: Shimanouchi, 1972

Notes

Very strong

Strong

Medium

Weak

Broad

Very broad

Overlapped by band indicated in parentheses.

0~1 cm^-1 uncertainty

1~3 cm^-1 uncertainty

3~6 cm^-1 uncertainty

6~15 cm^-1 uncertainty

15~30 cm^-1 uncertainty

References

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, Notes

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Chowdhury, 1987
Chowdhury, S. Grimsrud, Bonding of Charge Delocalized Anions to Protic and Dipolar Aprotic Solvents, J. Phys. Chem., 1987, 91, 10, 2551, https://doi.org/10.1021/j100294a021 . [all data]

Meot-ner, 1988, 2
Meot-ner, M., The Ionic Hydrogen Bond and Solvation. 7. Interaction Energies of Carbanions with Solvent Molecules, J. Am. Chem. Soc., 1988, 110, 12, 3858, https://doi.org/10.1021/ja00220a022 . [all data]

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Sieck, 1985
Sieck, L.W., Thermochemistry of Solvation of NO₂^- and C₆H₅NO₂^- by Polar Molecules in the Vapor Phase. Comparison with Cl^- and Variation with Ligand Structure., J. Phys. Chem., 1985, 89, 25, 5552, https://doi.org/10.1021/j100271a049 . [all data]

Sieck and Meot-ner, 1989
Sieck, L.W.; Meot-ner, M., Ionic Hydrogen Bond and Ion Solvation. 8. RS-..HOR Bond Strengths. Correlation with Acidities., J. Phys. Chem., 1989, 93, 4, 1586, https://doi.org/10.1021/j100341a079 . [all data]

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Knighton, W.B.; Zook, D.R.; Grimsrud, E.P., Cluster-Assisted Decomposition Reactions of the Molecular Anions of SF6 and C7F14, J. Am. Soc. Mass Spectrom., 1990, 1, 5, 372, https://doi.org/10.1016/1044-0305(90)85017-G . [all data]

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Sharma, R.B.; Kebarle, P., Stabilites and Hydrogen Bonding in Complexes of H3O+ and CH3OH2+ with Crown Ethers, from Measurements of Gas - Phase Ion - Molecule Equilibria, J. Am. Chem. Soc., 1984, 106, 14, 3913, https://doi.org/10.1021/ja00326a005 . [all data]

Evans and Keesee, 1991
Evans, D.H.; Keesee, R.G., Thermodynamics of Gas-Phase Mixed-Solvent Cluster Ions - Water and Methanol on K+ and Cl- and Comparison to Liquid Solutions, J. Phys. Chem., 1991, 95, 9, 3558, https://doi.org/10.1021/j100162a024 . [all data]

Hiraoka and Mizuse, 1987
Hiraoka, K.; Mizuse, S., Gas-Phase Solvation of Cl- with H2O, CH3OH, C2H4OH, i-C3H7OH, n-C3H7OH, and t-C4H9OH, Chem. Phys., 1987, 118, 3, 457, https://doi.org/10.1016/0301-0104(87)85078-4 . [all data]

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French, M.A.; Ikuta, S.; Kebarle, P., Hydrogen bonding of O-H and C-H hydrogen donors to Cl^-. Results from mass spectrometric measurement of the ion-molecule equilibria RH + Cl^- = RHCl^-, Can. J. Chem., 1982, 60, 1907. [all data]

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Yamdagni, R.; Payzant, J.D.; Kebarle, P., Solvation of Cl- and O₂- with H₂O, CH₃OH, and CH₃CN in the gas phase, Can. J. Chem., 1973, 51, 2507. [all data]

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Rodgers, M.T.; Armentrout, P.B., Noncovalent Metal-Ligand Bond Energies as Studied by Threshold Collision-Induced Dissociation, Mass Spectrom. Rev., 2000, 19, 4, 215, https://doi.org/10.1002/1098-2787(200007)19:4<215::AID-MAS2>3.0.CO;2-X . [all data]

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Notes

Go To: Top, Gas phase thermochemistry data, Gas phase ion energetics data, Ion clustering data, Mass spectrum (electron ionization), Vibrational and/or electronic energy levels, References

Symbols used in this document:

AE	Appearance energy
C_p,gas	Constant pressure heat capacity of gas
IE (evaluated)	Recommended ionization energy
T	Temperature
Δ_cH°_gas	Enthalpy of combustion of gas at standard conditions
Δ_fH°_gas	Enthalpy of formation of gas at standard conditions
Δ_rG°	Free energy of reaction at standard conditions
Δ_rH°	Enthalpy of reaction at standard conditions
Δ_rS°	Entropy of reaction at standard conditions

Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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Methyl Alcohol

Data at NIST subscription sites:

Gas phase thermochemistry data

Constant pressure heat capacity of gas

Constant pressure heat capacity of gas

Gas phase ion energetics data

Ionization energy determinations

Appearance energy determinations

De-protonation reactions

Ion clustering data

Clustering reactions

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Free energy of reaction

Mass spectrum (electron ionization)

Spectrum

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Additional Data

Vibrational and/or electronic energy levels

Gas Symmetry: Cs Symmetry Number σ = 1

Liquid Symmetry: Cs Symmetry Number σ = 1

Notes

References

Notes

Gas Symmetry: C_s Symmetry Number σ = 1

Liquid Symmetry: C_s Symmetry Number σ = 1