Biphenyl

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Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
GT - Glushko Thermocenter, Russian Academy of Sciences, Moscow

Quantity Value Units Method Reference Comment
Δfgas180. ± 3.kJ/molAVGN/AAverage of 6 values; Individual data points

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
50.3550.Dorofeeva O.V., 1997None of the statistically calculated values of S(T) known from literature [ Trevissoi C., 1955, Katon J.E., 1959, Aleman H., 1973, Thermodynamics Research Center, 1997] is in full accord with experimental data (see also discussion in [ Chirico R.D., 1989]). Recommended values agree with experimental values within their uncertainties except for temperature range 340-460 K where discrepancies amount to 0.4-0.6 J/mol*K.; GT
64.83100.
84.28150.
108.91200.
151.47273.15
166.7 ± 1.0298.15
167.80300.
225.53400.
273.62500.
311.78600.
342.14700.
366.75800.
387.07900.
404.061000.
418.421100.
430.641200.
441.101300.
450.091400.
457.861500.

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
DH - Eugene S. Domalski and Elizabeth D. Hearing
DRB - Donald R. Burgess, Jr.
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Quantity Value Units Method Reference Comment
Δfsolid98.2 ± 2.5kJ/molReviewRoux, Temprado, et al., 2008There are sufficient high-quality literature values to make a good evaluation with a high degree of confidence. In general, the evaluated uncertainty limits are on the order of (0.5 to 2.5) kJ/mol.; DRB
Δfsolid96.7 ± 2.6kJ/molCcbMontgomery, Rossini, et al., 1978ALS
Δfsolid100.5 ± 1.5kJ/molCcbColeman and Pilcher, 1966ALS
Δfsolid96.8 ± 4.0kJ/molCcbMackle and O'Hare, 1963ALS
Δfsolid97.2 ± 1.6kJ/molCcbParks and Vaughan, 1951Reanalyzed by Cox and Pilcher, 1970, Original value = 96.65 kJ/mol; ALS
Quantity Value Units Method Reference Comment
Δcsolid-6250. ± 20.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
solid,1 bar209.38J/mol*KN/AChirico, Knipmeyer, et al., 1989DH
solid,1 bar209.00J/mol*KN/ASaito, Atake, et al., 1988DH
solid,1 bar205.9J/mol*KN/AHuffman, Parks, et al., 1930Extrapolation below 90 K, 65.4 J/mol*K.; DH

Constant pressure heat capacity of liquid

Cp,liquid (J/mol*K) Temperature (K) Reference Comment
285.3370.Walker, Brooks, et al., 1958T = 200 to 600°F.; DH
301.2422.McEwen, March 31 1956T = 300 to 600°C.; DH
300.0370.Kurbatov, 1950T = 98 to 255°C. Mp 70.8°C.; DH
263.2350.8Forrest, Brugmann, et al., 1931T = 350 to 620 K. Value is unsmoothed experimental datum.; DH
259.54298.Newton, Kaura, et al., 1931T = 100 to 300°C, equation only, in t°C. Cp(liq) = 0.388 + 0.00057t cal/g*K.; DH

Constant pressure heat capacity of solid

Cp,solid (J/mol*K) Temperature (K) Reference Comment
198.39298.15Chirico, Knipmeyer, et al., 1989T = 5 to 700 K.; DH
198.17298.15Saito, Atake, et al., 1988T = 3 to 300 K.; DH
197.7298.15O'Rourke and Mraw, 1983T = 220 to 475 K. Cp = 0.7143 (T/K) - 15.3 (220 to 342.2 K) J/mol*K.; DH
190.300.Wasicki, Radomska, et al., 1982T = 180 to 350 K. Data given graphically. Value estimated from graph.; DH
190.8298.15Ueberreiter and Orthmann, 1950T = 293 to 368 K. Equation only.; DH
197.9298.1Schmidt, 1941T = 20 to 200°C, equations only, in t°C. Cp(c) = 0.2745 + 0.001235t cal/g*K (20 to 69°C); Cp(liq) = 0.3917 + 0.0005206t cal/g*K (69 to 200°C).; DH
197.9303.Spaght, Thomas, et al., 1932T = 30 to 100°C.; DH
194.1294.4Huffman, Parks, et al., 1930T = 93 to 295 K. Value is unsmoothed experimental datum.; DH

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
DRB - Donald R. Burgess, Jr.
DH - Eugene S. Domalski and Elizabeth D. Hearing
CAL - James S. Chickos, William E. Acree, Jr., Joel F. Liebman, Students of Chem 202 (Introduction to the Literature of Chemistry), University of Missouri -- St. Louis

Quantity Value Units Method Reference Comment
Tboil527. ± 2.KAVGN/AAverage of 40 out of 42 values; Individual data points
Quantity Value Units Method Reference Comment
Tfus343. ± 1.KAVGN/AAverage of 285 out of 294 values; Individual data points
Quantity Value Units Method Reference Comment
Ttriple342.090KN/AChirico, Knipmeyer, et al., 1989, 2Uncertainty assigned by TRC = 0.01 K; TRC
Ttriple341.8KN/AParks and Huffman, 1931Uncertainty assigned by TRC = 0.3 K; TRC
Quantity Value Units Method Reference Comment
Tc780. ± 20.KAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Pc35. ± 6.barAVGN/AAverage of 8 values; Individual data points
Quantity Value Units Method Reference Comment
Vc0.497l/molN/ATsonopoulos and Ambrose, 1995 
Quantity Value Units Method Reference Comment
ρc2.0 ± 0.1mol/lN/ATsonopoulos and Ambrose, 1995 
ρc2.01mol/lN/AEllard and Yanko, 1963Uncertainty assigned by TRC = 0.065 mol/l; TRC
ρc2.09mol/lN/AReiter, 1963Uncertainty assigned by TRC = 0.065 mol/l; TRC
ρc1.99mol/lN/AMandel and Ewbank, 1960Uncertainty assigned by TRC = 0.097 mol/l; TRC
Quantity Value Units Method Reference Comment
Δvap62. ± 10.kJ/molAVGN/AAverage of 7 values; Individual data points
Quantity Value Units Method Reference Comment
Δsub82. ± 3.kJ/molAVGN/AAverage of 10 values; Individual data points

Reduced pressure boiling point

Tboil (K) Pressure (bar) Reference Comment
418.20.029Weast and Grasselli, 1989BS
418.0.029Buckingham and Donaghy, 1982BS
343. to 351.0.0003Buckingham and Donaghy, 1982BS

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
51.2510.DSCBack, Grzyll, et al., 1996Based on data from 495. to 688. K.; AC
57.4400.EBChirico, Knipmeyer, et al., 1989Based on data from 350. to 578. K.; AC
60.3360.EBChirico, Knipmeyer, et al., 1989Based on data from 350. to 578. K.; AC
50.4500.EBChirico, Knipmeyer, et al., 1989Based on data from 350. to 578. K.; AC
59.6363.GSSakoguchi, Iwai, et al., 1989Based on data from 348. to 453. K.; AC
60.4363.N/ASasse, N'guimbi, et al., 1989Based on data from 333. to 393. K.; AC
57.3405.AStephenson and Malanowski, 1987Based on data from 390. to 563. K.; AC
54.9417.GSNasir, Hwang, et al., 1980Based on data from 396. to 437. K.; AC
48.0647.N/AGlaser and Rüland, 1957Based on data from 528. to 766. K.; AC
59.4357.N/ACunningham, 1930Based on data from 342. to 544. K. See also Boublik, Fried, et al., 1984.; AC

Antoine Equation Parameters

log10(P) = A − (B / (T + C))
    P = vapor pressure (bar)
    T = temperature (K)

View plot Requires a JavaScript / HTML 5 canvas capable browser.

Temperature (K) A B C Reference Comment
342.3 to 544.34.356851987.623-71.556Cunningham, 1930, 2Coefficents calculated by NIST from author's data.

Enthalpy of sublimation

ΔsubH (kJ/mol) Temperature (K) Method Reference Comment
81.520298.15N/AChirico, Knipmeyer, et al., 1989DH
81.8383.GSNass, Lenoir, et al., 1995Based on data from 313. to 453. K.; AC
83.4311.EMSasse, N'guimbi, et al., 1989Based on data from 283. to 338. K.; AC
76.0 ± 4.0273. to 313.HSAChickos, 1975AC
80.4 ± 1.6319.TSGCClark, Knox, et al., 1975Based on data from 306. to 332. K.; AC
75.2298. to 318.MEPribilová and Pouchlý, 1974AC
83.6 ± 2.5283.VRadchenko and Kitaigorodskii, 1974ALS
75.81 ± 0.59342.5VAihara, 1959ALS
75.8 ± 0.6289.N/AAihara, 1955Based on data from 279. to 299. K.; AC
81.6 ± 1.7301.N/ABradley and Cleasby, 1953Based on data from 288. to 314. K.; AC
81.588288.05VBradley and Cleasby, 1953, 2ALS
75.1 ± 1.7297.N/ASeki and Suzuki, 1953Based on data from 287. to 307. K.; AC
68.6 ± 0.8292.QFWolf and Weghofer, 1938AC
68.6 ± 0.8295.VWolf and Weghofer, 1938, 2ALS

Entropy of sublimation

ΔsubS (J/mol*K) Temperature (K) Reference Comment
273.42298.15Chirico, Knipmeyer, et al., 1989DH

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference Comment
18.5760342.098N/AChirico, Knipmeyer, et al., 1989DH
18.580342.2N/AO'Rourke and Mraw, 1983DH
18.800344.1N/ASmith, 1979DH
18.648341.5N/ASpaght, Thomas, et al., 1932DH
19.7342.3DSCKhimeche and Dahmani, 2006AC
19.27344.34DSCBenkhennouf, Kamel, et al., 2004AC
18.66341.5N/ADomalski and Hearing, 1996AC
18.575343.N/AUeberreiter and Orthmann, 1950DH
18.594342.N/ASchmidt, 1941DH
18.945314.3N/AEykman, 1889DH

Entropy of fusion

ΔfusS (J/mol*K) Temperature (K) Reference Comment
54.300342.098Chirico, Knipmeyer, et al., 1989DH
54.3342.2O'Rourke and Mraw, 1983DH
54.6344.1Smith, 1979DH
54.6341.5Spaght, Thomas, et al., 1932DH
54.81341.5Domalski and Hearing, 1996CAL
54.2343.Ueberreiter and Orthmann, 1950DH
54.4342.Schmidt, 1941DH
60.3314.3Eykman, 1889DH

Enthalpy of phase transition

ΔHtrs (kJ/mol) Temperature (K) Initial Phase Final Phase Reference Comment
0.0001516.8crystaline, IIIcrystaline, IISaito, Atake, et al., 1988DH
0.0050240.4crystaline, IIcrystaline, ISaito, Atake, et al., 1988Twist transition.; DH
0.0001516.8crystaline, IIIcrystaline, IIAtake, Saito, et al., 1983Anomalous region: 15.3 to 18.3 K.; DH
0.0050240.4crystaline, IIcrystaline, IAtake, Saito, et al., 1983Anomalous region: 30 to 47 K.; DH
0.00029311.0crystaline, IIIcrystaline, IIAtaki and Chihara, 1980DH
0.0050240.4crystaline, IIcrystaline, IAtaki and Chihara, 1980DH
19.900343.3crystaline, IliquidWasicki, Radomska, et al., 1982DH

Entropy of phase transition

ΔStrs (J/mol*K) Temperature (K) Initial Phase Final Phase Reference Comment
0.00916.8crystaline, III, Lockcrystaline, II, in transitionSaito, Atake, et al., 1988DH
0.12940.4crystaline, IIcrystaline, ISaito, Atake, et al., 1988Twist; DH
0.00916.8crystaline, IIIcrystaline, IIAtake, Saito, et al., 1983Anomalous; DH
0.12940.4crystaline, IIcrystaline, IAtake, Saito, et al., 1983Anomalous; DH
0.02511.0crystaline, IIIcrystaline, IIAtaki and Chihara, 1980DH
0.12940.4crystaline, IIcrystaline, IAtaki and Chihara, 1980DH
58.0343.3crystaline, IliquidWasicki, Radomska, et al., 1982DH

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
M - Michael M. Meot-Ner (Mautner) and Sharon G. Lias
MS - José A. Martinho Simões
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

C10H8+ + Biphenyl = (C10H8+ • Biphenyl)

By formula: C10H8+ + C12H10 = (C10H8+ • C12H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr56.5kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.297.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

C12H8+ + Biphenyl = (C12H8+ • Biphenyl)

By formula: C12H8+ + C12H10 = (C12H8+ • C12H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr56.1kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.279.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated; M

C17H24F3N3O3RuS (solution) + Biphenyl (solution) = C23H25F3O3RuS (solution) + 3Acetonitrile (solution)

By formula: C17H24F3N3O3RuS (solution) + C12H10 (solution) = C23H25F3O3RuS (solution) + 3C2H3N (solution)

Quantity Value Units Method Reference Comment
Δr-15.1 ± 0.4kJ/molRSCNolan, Martin, et al., 1992solvent: Tetrahydrofuran; MS

3Hydrogen + Biphenyl = Benzene, cyclohexyl-

By formula: 3H2 + C12H10 = C12H16

Quantity Value Units Method Reference Comment
Δr-230.kJ/molEqkFrye, 1962liquid phase; ALS

Henry's Law data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

kH(T) = H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)

H (mol/(kg*bar)) d(ln(kH))/d(1/T) (K) Method Reference Comment
1.2 QN/A missing citation give several references for the Henry's law constants but don't assign them to specific species.
3.6 LN/A 
3.3 MN/A 
2.5 MMackay, Shiu, et al., 1979 
1.2 VBohon and Claussen, 1951 

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
MM - Michael M. Meot-Ner (Mautner)
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to C12H10+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
IE (evaluated)8.16 ± 0.13eVN/AN/AL
Quantity Value Units Method Reference Comment
Proton affinity (review)813.6kJ/molN/AHunter and Lias, 1998HL
Quantity Value Units Method Reference Comment
Gas basicity782.9kJ/molN/AHunter and Lias, 1998HL

Electron affinity determinations

EA (eV) Method Reference Comment
<0.130 ± 0.035ECDWojnarovits and Foldiak, 1981EA is an upper limit: Chen and Wentworth, 1989. G3MP2B3 calculations indicate an EA of ca. -0.02 eV, anion unbound.; B

Proton affinity at 298K

Proton affinity (kJ/mol) Reference Comment
808.8Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Gas basicity at 298K

Gas basicity (review) (kJ/mol) Reference Comment
780.7Aue, Guidoni, et al., 2000Experimental literature data re-evaluated by the authors using ab initio protonation entropies; MM

Ionization energy determinations

IE (eV) Method Reference Comment
8.80 ± 0.05EILoudon and Mazengo, 1974LLK
8.9EIKoppel, Schwarz, et al., 1974LLK
7.95 ± 0.02PEMaier and Turner, 1972LLK
8.23 ± 0.01PEDewar, Haselbach, et al., 1970RDSH
8.20 ± 0.05PEEland and Danby, 1968RDSH
8.46CTSSlifkin and Allison, 1967RDSH
8.22 ± 0.15EIEland, Shepherd, et al., 1966RDSH
8.27 ± 0.01PIWatanabe, Nakayama, et al., 1962RDSH
8.64CTSKinoshita, 1962RDSH
8.35CTSBriegleb, Czekalla, et al., 1961RDSH
8.4CTSBriegleb and Czekalla, 1959RDSH
8.39PEAkiyama, Li, et al., 1979Vertical value; LLK
8.34PERuscic, Kovac, et al., 1978Vertical value; LLK

Appearance energy determinations

Ion AE (eV) Other Products MethodReferenceComment
C6H4+18.1 ± 0.3?EINatalis and Franklin, 1965RDSH
C6H5+18.2 ± 0.5?EINatalis and Franklin, 1965RDSH
C7H5+20.9 ± 0.2?EINatalis and Franklin, 1965RDSH
C8H6+18.10 ± 0.05?EINatalis and Franklin, 1965RDSH
C9H7+16.08 ± 0.05?EINatalis and Franklin, 1965RDSH
C10H8+14.81 ± 0.05?EINatalis and Franklin, 1965RDSH
C11H7+14.8 ± 0.2CH3EILoudon and Mazengo, 1974LLK
C12H8+16.89 ± 0.08?EINatalis and Franklin, 1965RDSH
C12H9+13.6 ± 0.2HEILoudon and Mazengo, 1974LLK
C12H9+14.36HEINatalis and Franklin, 1965RDSH
C12H82+22.0 ± 1.0?EINatalis and Franklin, 1965RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

C10H8+ + Biphenyl = (C10H8+ • Biphenyl)

By formula: C10H8+ + C12H10 = (C10H8+ • C12H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr56.5kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
22.297.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

C12H8+ + Biphenyl = (C12H8+ • Biphenyl)

By formula: C12H8+ + C12H10 = (C12H8+ • C12H10)

Bond type: Charge transfer bond (positive ion)

Quantity Value Units Method Reference Comment
Δr56.1kJ/molPHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated
Quantity Value Units Method Reference Comment
Δr120.J/mol*KN/AMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

Free energy of reaction

ΔrG° (kJ/mol) T (K) Method Reference Comment
23.279.PHPMSMeot-Ner (Mautner), 1980gas phase; Entropy change calculated or estimated

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Reaction thermochemistry data, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1997
Dorofeeva O.V., Unpublished results. Thermocenter of Russian Academy of Science, Moscow, 1997. [all data]

Trevissoi C., 1955
Trevissoi C., Specific heat and entropy of biphenyl, Ann. Chim. (Rome), 1955, 45, 943-959. [all data]

Katon J.E., 1959
Katon J.E., The vibrational spectra and geometrical configuration of biphenyl, Spectrochim. Acta, 1959, 15, 627-650. [all data]

Aleman H., 1973
Aleman H., Thermodynamic functions for biphenyl and the 4,4'-dihalogenobiphenyls, Thermochim. Acta, 1973, 7, 69-73. [all data]

Thermodynamics Research Center, 1997
Thermodynamics Research Center, Selected Values of Properties of Chemical Compounds., Thermodynamics Research Center, Texas A&M University, College Station, Texas, 1997. [all data]

Chirico R.D., 1989
Chirico R.D., The thermodynamic properties of biphenyl, J. Chem. Thermodyn., 1989, 21, 1307-1331. [all data]

Roux, Temprado, et al., 2008
Roux, M.V.; Temprado, M.; Chickos, J.S.; Nagano, Y., Critically Evaluated Thermochemical Properties of Polycyclic Aromatic Hydrocarbons, J. Phys. Chem. Ref. Data, 2008, 37, 4, 1855-1996. [all data]

Montgomery, Rossini, et al., 1978
Montgomery, R.L.; Rossini, F.D.; Mansson, M., Enthalpies of combustion, vaporization, and formation of phenylbenzene, cyclohexylbenzene, and cyclohexylcyclohexane; enthalpy of hydrogenation of certain aromatic systems, J. Chem. Eng. Data, 1978, 23, 125-129. [all data]

Coleman and Pilcher, 1966
Coleman, D.J.; Pilcher, G., Heats of combustion of biphenyl, bibenzyl, naphthalene, anthracene, and phenanthrene, Trans. Faraday Soc., 1966, 62, 821-827. [all data]

Mackle and O'Hare, 1963
Mackle, H.; O'Hare, P.A.G., A high-precision aneroid semi-micro combustion calorimeter, Trans. Faraday Soc., 1963, 59, 2693-2701. [all data]

Parks and Vaughan, 1951
Parks, G.S.; Vaughan, L.M., The heat of combustion of biphenyl, J. Am. Chem. Soc., 1951, 73, 2380-2381. [all data]

Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G., Thermochemistry of Organic and Organometallic Compounds, Academic Press, New York, 1970, 1-636. [all data]

Chirico, Knipmeyer, et al., 1989
Chirico, R.D.; Knipmeyer, S.E.; Nguyen, A.; Steele, W.V., The thermodynamic properties of biphenyl, J. Chem. Thermodyn., 1989, 21, 1307-1331. [all data]

Saito, Atake, et al., 1988
Saito, K.; Atake, T.; Chihara, H., Incommensurate phase transitions and anomalous lattice heat capacities of biphenyl, Bull. Chem. Soc. Japan, 1988, 61, 679-688. [all data]

Huffman, Parks, et al., 1930
Huffman, H.M.; Parks, G.S.; Daniels, A.C., Thermal data on organic compounds. VII. The heat capacities, entropies and free energies of twelve aromatic hydrocarbons, J. Am. Chem. Soc., 1930, 52, 1547-1558. [all data]

Walker, Brooks, et al., 1958
Walker, B.E., Jr.; Brooks, M.S.; Ewing, C.T.; Miller, R.R., Specific heat of biphenyl and other polyphenyls. Correlation of specific heat data for phenyl type compounds, J. Chem. Eng. Data, 1958, 3, 280-282. [all data]

McEwen, March 31 1956
McEwen, M., Preliminary engineering study of organic nuclear reactor coolant-moderators Monsanto Chemical Co, March 31 1956. [all data]

Kurbatov, 1950
Kurbatov, V.Ya., Specific heats of liquids. III. Specific heat of hydrocarbons with several noncondensed rings, Zhur. Obshch. Khim., 1950, 20, 1139-1144. [all data]

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Notes

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