CH3SiH=CH2

• Formula: C₂H₆Si
• Molecular weight: 58.1545
• CAS Registry Number: 38063-40-0
• Information on this page:
  • Reaction thermochemistry data
  • Ion clustering data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
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Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

 + C₂H₆Si = ( • C₂H₆Si)

By formula: Fe⁺ + C₂H₆Si = (Fe⁺ • C₂H₆Si)

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

 + C₂H₆Si = ( • C₂H₆Si)

By formula: Fe⁺ + C₂H₆Si = (Fe⁺ • C₂H₆Si)

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   ?

State:   X

Additional references: Jacox, 1994, page 399; Jacox, 2003, page 385; Khabashesku, Kudin, et al., 1998

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Jacobson and Bakhtiar, 1993
Jacobson, D.B.; Bakhtiar, R., Generation, Characterization and Properties of Iron-Silylene and Iron-Sylene Cationic Complexes in the Gas Phase, J. Am. Chem. Soc., 1993, 115, 23, 10830, https://doi.org/10.1021/ja00076a046 . [all data]

Vatsa, Kumar, et al., 1996
Vatsa, R.K.; Kumar, A.; Naik, P.D.; Upadhyaya, H.P., et al., UV spectrum and decay kinetics of transient methylsilene produced in the 193 nm photolysis of gaseous 1-methyl-1-silacyclobutane, Chem. Phys. Lett., 1996, 255, 1-3, 129, https://doi.org/10.1016/0009-2614(96)00342-9 . [all data]

Drahnak, Michl, et al., 1981
Drahnak, T.J.; Michl, J.; West, R., Photoisomerization of dimethylsilylene to 2-silapropene and thermal reversion to dimethylsilylene, J. Am. Chem. Soc., 1981, 103, 7, 1845, https://doi.org/10.1021/ja00397a047 . [all data]

Arrington, Klingensmith, et al., 1984
Arrington, C.A.; Klingensmith, K.A.; West, R.; Michl, J., Polarized infrared spectroscopy of matrix-isolated dimethylsilylene and 1-methylsilene, J. Am. Chem. Soc., 1984, 106, 3, 525, https://doi.org/10.1021/ja00315a010 . [all data]

Maier, Mihm, et al., 1984
Maier, G.; Mihm, G.; Reisenauer, H.P.; Littmann, D., Hetero-π-Systeme, 9. Über die Beziehungen zwischen Silaethenen und Methylsilylenen, Chem. Ber., 1984, 117, 7, 2369, https://doi.org/10.1002/cber.19841170709 . [all data]

Raabe, Vancik, et al., 1986
Raabe, G.; Vancik, H.; West, R.; Michl, J., IR transition moment directions in matrix-isolated dimethylsilylene and 1-methylsilene, J. Am. Chem. Soc., 1986, 108, 4, 671, https://doi.org/10.1021/ja00264a017 . [all data]

Reisenauer, Mihm, et al., 1982
Reisenauer, H.P.; Mihm, G.; Maier, G., Reversible Photoisomerisierung zwischen Silaethenen und Methylsilylenen (Methylsilandiylen), Angew. Chem., 1982, 94, 11, 864, https://doi.org/10.1002/ange.19820941110 . [all data]

Trommer, Sander, et al., 1993
Trommer, M.; Sander, W.; Patyk, A., Oxidation of methylsilenes with molecular oxygen. A matrix isolation study, J. Am. Chem. Soc., 1993, 115, 25, 11775, https://doi.org/10.1021/ja00078a016 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Khabashesku, Kudin, et al., 1998
Khabashesku, V.N.; Kudin, K.N.; Margrave, J.L., Vibrational analysis of infrared spectra of matrix-isolated transient silenes on basis of density functional theory calculations, J. Mol. Struct., 1998, 443, 1-3, 175, https://doi.org/10.1016/S0022-2860(97)00398-0 . [all data]

Notes

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• Symbols used in this document:
  

  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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