S3 anion

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

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Clustering reactions

(S3- • 4294967295sulfur) + sulfur = S3-

By formula: (S3- • 4294967295S) + S = S3-

Quantity Value Units Method Reference Comment
ΔrH°72.2 ± 5.3kcal/molN/ANimlos and Ellison, 1986gas phase

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Td = 17000 ± 110 gas Nimlos and Ellison, 1986
Hunsicker, Jones, et al., 1995

State:   D
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16152 ± 50 Ne D-X 537 619 Shnitko, Fulara, et al., 2008
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 446 Ne AB Shnitko, Fulara, et al., 2008
2 Bend 177 Ne AB Shnitko, Fulara, et al., 2008

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 14259 ± 40 Ne C-X 598 701 Shnitko, Fulara, et al., 2008
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a1 1 Sym. stretch 466 Ne AB Shnitko, Fulara, et al., 2008
2 Bend 184 Ne AB Shnitko, Fulara, et al., 2008

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
b2 3 Asym. stretch 594.2 T Ar IR Brabson, Mielke, et al., 1991

Additional references: Jacox, 1994, page 110; Jacox, 2003, page 148

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

Go To: Top, Ion clustering data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Nimlos and Ellison, 1986
Nimlos, M.R.; Ellison, G.B., Photoelectron spectroscopy of SO2-, S3-, and S2O-, J. Phys. Chem., 1986, 90, 2574. [all data]

Hunsicker, Jones, et al., 1995
Hunsicker, S.; Jones, R.O.; Gantefor, G., Rings and chains in sulfur cluster anions S- to S-9(-): Theory (simulated annealing) and experiment (photoelectron detachment), J. Chem. Phys., 1995, 102, 15, 5917, https://doi.org/10.1063/1.469326 . [all data]

Shnitko, Fulara, et al., 2008
Shnitko, I.; Fulara, J.; Garkusha, I.; Nagy, A.; Maier, J.P., Electronic transitions of and in neon matrixes, Chem. Phys., 2008, 346, 1-3, 8, https://doi.org/10.1016/j.chemphys.2008.01.005 . [all data]

Brabson, Mielke, et al., 1991
Brabson, G.D.; Mielke, Z.; Andrews, L., Infrared spectra and structures of isotopically enriched sulfur (S3 and S4) in solid argon, J. Phys. Chem., 1991, 95, 1, 79, https://doi.org/10.1021/j100154a019 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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