Perfluoronaphthalene
- Formula: C10F8
- Molecular weight: 272.0942
- IUPAC Standard InChI: InChI=1S/C10F8/c11-3-1-2(5(13)9(17)7(3)15)6(14)10(18)8(16)4(1)12
- IUPAC Standard InChIKey: JDCMOHAFGDQQJX-UHFFFAOYSA-N
- CAS Registry Number: 313-72-4
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Octafluoronaphthalene; Naphthalene, octafluoro-
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
| ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
|---|---|---|---|---|
| 19.0 ± 0.60 | 308. | A | Stephenson and Malanowski, 1987 | Based on data from 293. to 323. K. See also Radchenko and Kataigorodskii, 1974. |
Enthalpy of fusion
| ΔfusH (kcal/mol) | Temperature (K) | Reference |
|---|---|---|
| 4.195 | 358.8 | Michaud, Negrier, et al., 1999 |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| IE (evaluated) | 8.87 ± 0.02 | eV | N/A | N/A | L |
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.85 | PE | Hohlneicher, Distler, et al., 1984 | LBLHLM |
| 8.90 ± 0.05 | PE | Bastide, Hall, et al., 1979 | LLK |
| 8.85 | PE | Brundle, Robin, et al., 1972 | LLK |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Radchenko and Kataigorodskii, 1974
Radchenko, L.G.; Kataigorodskii, A.I.,
Zh. Fiz. Khim., 1974, 48, 2702. [all data]
Michaud, Negrier, et al., 1999
Michaud, F.; Negrier, Ph.; Mikailitchenko, D.; Marbeuf, A.; Haget, Y.; Cuevas-diarte, M.; Oonk, H.A.J.,
Measurement and Analysis of the Naphthalene --- Octafluoronaphthalene Phase Diagram: Complex Formation in Solid and Liquid,
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals, 1999, 326, 1, 409-424, https://doi.org/10.1080/10587259908025429
. [all data]
Hohlneicher, Distler, et al., 1984
Hohlneicher, G.; Distler, D.; Muller, M.; Freund, H.-J.,
Identification of shake-up satellites in valence photoelectron spectra of organic compounds by comparison with electronic absorption spectra of radical cations. Case study: Octafluoronaphthalene,
Chem. Phys. Lett., 1984, 111, 151. [all data]
Bastide, Hall, et al., 1979
Bastide, J.; Hall, D.; Heilbronner, E.; Maier, J.P.,
He(Iα) photoelectron spectra of some higher aromatic perfluoro compounds,
J. Electron Spectrosc. Relat. Phenom., 1979, 16, 205. [all data]
Brundle, Robin, et al., 1972
Brundle, C.R.; Robin, M.B.; Kuebler, N.A.,
Perfluoro effect in photoelectron spectroscopy. II. Aromatic molecules,
J. Am. Chem. Soc., 1972, 94, 1466. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy ΔfusH Enthalpy of fusion ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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