CH2CH2OH


Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated by: Edward P. Hunter and Sharon G. Lias

View reactions leading to C2H5O+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
Proton affinity (review)178.kcal/molN/AHunter and Lias, 1998 
Quantity Value Units Method Reference Comment
Gas basicity170.3kcal/molN/AHunter and Lias, 1998 

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

Tod = 37700 gas Anastasi, Munk, et al., 1989

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

OH stretch 3625.8 T Ar IR Kuo, Wann, et al., 1993
CH stretch 2991.0 Ar IR Kuo, Wann, et al., 1993
CH stretch 2922.4 T Ar IR Kuo, Wann, et al., 1993
CH stretch 2842.7 Ar IR Kuo, Wann, et al., 1993
1355.4 Ar IR Kuo, Wann, et al., 1993
1172.5 Ar IR Kuo, Wann, et al., 1993
CO stretch 1040.1 Ar IR Kuo, Wann, et al., 1993
873.9 T Ar IR Kuo, Wann, et al., 1993

Additional references: Jacox, 1994, page 376; Jacox, 1998, page 337

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
dPhotodissociation threshold

References

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Anastasi, Munk, et al., 1989
Anastasi, C.; Munk, J.; Pagsberg, P.; Simpson, V.J., UV Spectrum and kinetics of the CH3CHOH radicals and their reaction with O2, Chem. Phys. Lett., 1989, 164, 1, 18, https://doi.org/10.1016/0009-2614(89)85195-4 . [all data]

Kuo, Wann, et al., 1993
Kuo, Y.-P.; Wann, G.-H.; Lee, Y.-P., Infrared absorption of 2-hydroxyethyl (HOCH2CH2) in solid Ar, J. Chem. Phys., 1993, 99, 5, 3272, https://doi.org/10.1063/1.465136 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

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