ClCP+

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 54100 ± 500 gas Dennis, Firth, et al., 1991

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 29200 ± 500 gas Dennis, Firth, et al., 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 CCl stretch 500 ± 50 gas PE Dennis, Firth, et al., 1991

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx = 22900 ± 500 gas Dennis, Firth, et al., 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 3 CCl stretch 485 ± 50 gas PE Dennis, Firth, et al., 1991

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σ+ 1 CP stretch 1350 ± 50 T gas PE Dennis, Firth, et al., 1991

Additional references: Jacox, 1994, page 81

Notes

TTentative assignment or approximate value
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dennis, Firth, et al., 1991
Dennis, T.J.; Firth, S.; Kroto, H.W.; Matti, G.Y.; Mok, C.-Y.; Suffolk, R.J.; Walton, D.R.M., J. Chem. Soc., 1991, Faraday Trans. 87, 917. [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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