3,3-Dimethyl-3-silathietane
- Formula: C4H10SSi
- Molecular weight: 118.273
- IUPAC Standard InChI: InChI=1S/C4H10SSi/c1-6(2)3-5-4-6/h3-4H2,1-2H3
- IUPAC Standard InChIKey: LAIPGQCKIZSQTO-UHFFFAOYSA-N
- CAS Registry Number: 77205-52-8
- Chemical structure:
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
View reactions leading to C4H10SSi+ (ion structure unspecified)
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.1 | PE | Traven, Rokitskaya, et al., 1986 | LBLHLM |
| 8.25 ± 0.03 | PI | Gusel'nikov, Volkova, et al., 1981 | LLK |
| 8.49 | PE | Traven, Rokitskaya, et al., 1986 | Vertical value; LBLHLM |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C2H6SSi+ | 9.23 ± 0.03 | C2H4 | PI | Gusel'nikov, Volkova, et al., 1981 | LLK |
| C3H8Si+ | 9.15 ± 0.04 | CH2S | PI | Gusel'nikov, Volkova, et al., 1981 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Traven, Rokitskaya, et al., 1986
Traven, V.F.; Rokitskaya, V.I.; Rodin, O.G.; Shvets, A.F.; Redchenko, V.V.; Voronkov, M.G.; Kirpichenko, S.V.; Suslova, E.N.,
Photoelectron spectrum and orbital structure of 3,3-dimethyl-3-silathietane,
Dokl. Phys. Chem., 1986, 288, 522. [all data]
Gusel'nikov, Volkova, et al., 1981
Gusel'nikov, L.E.; Volkova, V.V.; Zaikin, V.G.; Tarasenko, N.A.; Tishenkov, A.A.; Nametkin, N.S.; Voronkov, M.G.; Kirpichenko, S.V.,
Mass spectra of 3,3-dimethyl-3-silathietane and 3,3-diethyl-2,4-dimethyl-3-silathietane. First observation of silathione ions and calculation of their heats of formation,
J. Organomet. Chem., 1981, 215, 9. [all data]
Notes
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- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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