HBNH

Formula: BH₂N
Molecular weight: 26.834
CAS Registry Number: 15119-97-8
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Vibrational and/or electronic energy levels

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


Σ⁺	1	NH stretch	3710.5	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	1	NH stretch	3700.5	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	2	BH stretch	2775.3		Ar	IR	Thompson, Andrews, et al., 1995
	3	BN stretch	1786.19		gas	DL	Kawashima, Kawaguchi, et al., 1987
	3	BN stretch	1788.7	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	3	BN stretch	1782.8	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
Π	4	BH deform.	676.9		Ar	IR	Thompson, Andrews, et al., 1995
	4	BH deform.	671.6		Ar	IR	Thompson, Andrews, et al., 1995
	5	NH deform.	463.3	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995
	5	NH deform.	461.0	m	Ar	IR	Lory and Porter, 1973 Thompson and Andrews, 1995 Thompson, Andrews, et al., 1995

Additional references: Jacox, 1994, page 137; Jacox, 1998, page 222; Baird and Datta, 1972; Armstrong and Clark, 1972

Notes

Medium

References

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Lory and Porter, 1973
Lory, E.R.; Porter, R.F., Infrared studies of matrix isolated species in the hydrogen-boron-nitrogen system, J. Am. Chem. Soc., 1973, 95, 6, 1766, https://doi.org/10.1021/ja00787a012 . [all data]

Thompson and Andrews, 1995
Thompson, C.A.; Andrews, L., Reactions of B Atoms with NH3 to Produce HBNH, BNBH, and B2N, J. Am. Chem. Soc., 1995, 117, 40, 10125, https://doi.org/10.1021/ja00145a029 . [all data]

Thompson, Andrews, et al., 1995
Thompson, C.A.; Andrews, L.; Martin, J.M.L.; El-Yazal, J., Infrared Spectra of Boron-Ammonia Reaction Products in Solid Argon, J. Phys. Chem., 1995, 99, 38, 13839, https://doi.org/10.1021/j100038a015 . [all data]

Kawashima, Kawaguchi, et al., 1987
Kawashima, Y.; Kawaguchi, K.; Hirota, E., Detection of HBNH by infrared diode laser spectroscopy, J. Chem. Phys., 1987, 87, 11, 6331, https://doi.org/10.1063/1.453462 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Baird and Datta, 1972
Baird, N.C.; Datta, R.K., Ab initio molecular orbital study of iminoborane, Inorg. Chem., 1972, 11, 1, 17, https://doi.org/10.1021/ic50107a004 . [all data]

Armstrong and Clark, 1972
Armstrong, D.R.; Clark, D.T., The electronic structures and energies of borazine, boronimide and dimeric boronimide, Theor. Chim. Acta, 1972, 24, 4, 307, https://doi.org/10.1007/BF01007549 . [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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