Zinc, [5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN21,κN22,κN23,κN24]-, (SP-4-1)-


Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub46.8 ± 0.7kcal/molMEPatiño, Campos, et al., 2002Based on data from 555. to 567. K.

Enthalpy of sublimation

ΔsubH (kcal/mol) Temperature (K) Method Reference Comment
43.7 ± 0.7559.MEPatiño, Campos, et al., 2002Based on data from 555. to 567. K.
50.9 ± 0.7563. to 663.N/APerlovich, Naneishvili, et al., 1994See also Patiño, Campos, et al., 2002.
26.1666.UV/VisEdwards, Dolphin, et al., 1971See also Patiño, Campos, et al., 2002.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
6.0 ± 0.2LENakato, Abe, et al., 1976 
6.42PEKhandelwal and Roebber, 1975Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Patiño, Campos, et al., 2002
Patiño, Rodrigo; Campos, Myriam; Torres, Luis Alfonso, A thermochemical study of 5,10,15,20-tetraphenylporphine zinc(II) by rotating bomb combustion calorimetry and by Knudsen effusion experiments, The Journal of Chemical Thermodynamics, 2002, 34, 2, 193-204, https://doi.org/10.1006/jcht.2001.0911 . [all data]

Perlovich, Naneishvili, et al., 1994
Perlovich, G.L.; Naneishvili, B.K.; Golubchikov, O.A., Thermodynamic characteristics of sublimation of tetraphenylporphyrin metal complexes, Zh. Fiz. Khim., 1994, 68, 11, 1932. [all data]

Edwards, Dolphin, et al., 1971
Edwards, L.; Dolphin, D.H.; Gouterman, M.; Adler, A.D., Porphyrins XVII. Vapor absorption spectra and redox reactions: Tetraphenylporphins and porphin, Journal of Molecular Spectroscopy, 1971, 38, 1, 16-32, https://doi.org/10.1016/0022-2852(71)90090-7 . [all data]

Nakato, Abe, et al., 1976
Nakato, Y.; Abe, K.; Tsubomura, H., Experimental determination of ionization potentials of tetraphenylporphine and metallotetraphenylporphines, Chem. Phys. Lett., 1976, 39, 358. [all data]

Khandelwal and Roebber, 1975
Khandelwal, S.C.; Roebber, J.L., The photoelectron spectra of tetraphenylporphine and some metallotetraphenylporphyrins, Chem. Phys. Lett., 1975, 34, 355. [all data]


Notes

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