trinitromethane

• Formula: CHN₃O₆
• Molecular weight: 151.0351
• CAS Registry Number: 517-25-9
• Information on this page:
  • Phase change data
  • Gas phase ion energetics data
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias and Joel F. Liebman

Ionization energy determinations

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Lewis and Smyth, 1939
Lewis, G.L.; Smyth, C.P., The Dipole Moments and Structures of Ozone, Silicobromoform and Dichlorogermane, J. Am. Chem. Soc., 1939, 61, 3067-3070. [all data]

Carpenter, Zimmer, et al., 1970
Carpenter, G.A.; Zimmer, M.F.; Baroody, E.E.; Robb, R.A., Enthalpy of formation of bromotrinitromethane, J. Chem. Eng. Data, 1970, 15, 553-556. [all data]

Miroshnichenko and Vorob'eva, 1999
Miroshnichenko, E.O.; Vorob'eva, V.P., Thermochemical characteristics of nitroalkanes, Zh. Fiz. Khim., 1999, 73, 3, 419. [all data]

Mirishnichenko, Lebedev, et al., 1967
Mirishnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulevskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya., Thermochemistry of trinitromethane, Zh. Fiz. Khim., 1967, 41, 1477-1479. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Miroshnichenko, Lebedev, et al., 1967
Miroshnichenko, E.A.; Lebedev, Yu.A.; Shevelev, S.A.; Gulivskaya, V.I.; Fainzil'berg, A.A.; Apin, A.Ya., Zh. Fiz. Khim., 1967, 41, 6, 1477. [all data]

Koo, Chin, et al., 1990
Koo, L.K.; Chin, W.S.; Mok, C.Y.; Huang, H.H., A study of the pyrolysis of trinitro- and tetranitromethane by photoelectron spectroscopy, Bull. Singapore Natl. Inst. Chem., 1990, 18, 121. [all data]

Notes

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• Symbols used in this document:
  

  Tfus	Fusion (melting) point
  ΔsubH°	Enthalpy of sublimation at standard conditions
  ΔvapH	Enthalpy of vaporization
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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