vanadium oxide
- Formula: OV
- Molecular weight: 66.9409
- IUPAC Standard InChIKey: IBYSTTGVDIFUAY-UHFFFAOYSA-N
- CAS Registry Number: 12035-98-2
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Vanadium monoxide
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
B - John E. Bartmess
View reactions leading to OV+ (ion structure unspecified)
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
1.2290 ± 0.0080 | LPES | Wu and Wang, 1998 | B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.2386 ± 0.0006 | TE | Harrington and Weisshaar, 1992 | LL |
7.5 | DER | Lias, Bartmess, et al., 1988 | LL |
8.4 | EI | Balducci, Gigli, et al., 1983 | LBLHLM |
8. ± 1. | EI | Farber, Uy, et al., 1972 | LLK |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Wu and Wang, 1998
Wu, H.; Wang, L.-S.,
A Photoelectron Spectroscopic Study of Monovanadium Oxide Anions (VOx-, x=1-4),
J. Phys. Chem., 1998, 108, 13, 5310, https://doi.org/10.1063/1.475966
. [all data]
Harrington and Weisshaar, 1992
Harrington, J.; Weisshaar, J.C.,
State-to-state photoionization of VO: Propensity for large positive changes in rotational quantum number,
J. Chem. Phys., 1992, 97, 2809. [all data]
Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G.,
Gas-phase ion and neutral thermochemistry,
J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]
Balducci, Gigli, et al., 1983
Balducci, G.; Gigli, G.; Guido, M.,
Thermodynamic study of gaseous ternary oxide molecules. The europium-vanadium-oxygen system,
J. Chem. Phys., 1983, 79, 5623. [all data]
Farber, Uy, et al., 1972
Farber, M.; Uy, O.M.; Srivastava, R.D.,
Effusion-mass spectrometric determination of the heats of formation of the gaseous molecules V4O10, V4O8, VO2, and VO,
J. Chem. Phys., 1972, 56, 5312. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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