CCP


Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A


 Energy 
 (cm-1
 Med.   Transition   λmin 
 (nm) 
 λmax 
 (nm) 
 References

To = 15898.82 gas A-X 490 630 Sunahori, Wei, et al., 2007
Sunahori, Wei, et al., 2008


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Σ+ 1 CC stretch 1809.2 gas LF Sunahori, Wei, et al., 2008
Π 2 Bend (w) 305.2 gas LF Sunahori, Wei, et al., 2008
Σ+ 3 CP stretch 725.3 gas LF Sunahori, Wei, et al., 2008

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

Σ+ 1 CC stretch 1644.3 gas LF Sunahori, Wei, et al., 2007
Sunahori, Wei, et al., 2008
Π 2 Bend (w) 211 gas LF Sunahori, Wei, et al., 2008
Σ+ 3 CP stretch 834.8 gas LF Sunahori, Wei, et al., 2007
Sunahori, Wei, et al., 2008

Additional references: Halfen, Sun, et al., 2009

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Sunahori, Wei, et al., 2007
Sunahori, F.X.; Wei, J.; Clouthier, D.J., Spectroscopic Identification of C, J. Am. Chem. Soc., 2007, 129, 31, 9600, https://doi.org/10.1021/ja0738475 . [all data]

Sunahori, Wei, et al., 2008
Sunahori, F.X.; Wei, J.; Clouthier, D.J., The electronic spectrum of the C[sub 2]P free radical and a Renner--Teller analysis of the [sup 2]Δ and X [sup 2]Π electronic states, J. Chem. Phys., 2008, 128, 24, 244311, https://doi.org/10.1063/1.2939011 . [all data]

Halfen, Sun, et al., 2009
Halfen, D.T.; Sun, M.; Clouthier, D.J.; Ziurys, L.M., The rotational spectrum of the CCP (X [sup 2]Π[sub r]) radical and its [sup 13]C isotopologues at microwave, millimeter, and submillimeter wavelengths, J. Chem. Phys., 2009, 130, 1, 014305, https://doi.org/10.1063/1.3043367 . [all data]


Notes

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