Xe2H

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 50240 ± 20 Ar Kraas and Gurtler, 1990
Kraas and Gurtler, 1991
Kr Creuzburg and Wittl, 1990
Kraas and Gurtler, 1990
To = 50130 ± 10 Xe Creuzburg, Koch, et al., 1989
Wittl, Eberlein, et al., 1993
Tx = 39800 Ar Kraas and Gurtler, 1990
Kraas and Gurtler, 1991
Tx = 39600 Kr Creuzburg and Wittl, 1990
Kraas and Gurtler, 1990
Kunz, McCaffrey, et al., 1991
Tx = 39700 Xe Creuzburg and Wittl, 1990
Kraas and Gurtler, 1990
Wittl, Creuzburg, et al., 1991
Kunz, McCaffrey, et al., 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
645 ± 10 Ar AB Kraas and Gurtler, 1990
Kraas and Gurtler, 1991
600 T Kr AB Kraas and Gurtler, 1990
605 ± 10 Xe AB Creuzburg, Koch, et al., 1989

Additional references: Jacox, 1994, page 57; Gurtler, Kraas, et al., 1990; Kraas and Gurtler, 1992

Notes

TTentative assignment or approximate value
oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Kraas and Gurtler, 1990
Kraas, M.; Gurtler, P., Emission and excitation spectra of rare gas hydride trimers in rare gas matrices, Chem. Phys. Lett., 1990, 174, 5, 396, https://doi.org/10.1016/S0009-2614(90)87168-Q . [all data]

Kraas and Gurtler, 1991
Kraas, M.; Gurtler, P., Xenon hydrides and deuterides in argon matrices, Chem. Phys. Lett., 1991, 187, 5, 527, https://doi.org/10.1016/0009-2614(91)80294-8 . [all data]

Creuzburg and Wittl, 1990
Creuzburg, M.; Wittl, F., Hydrogen centers in solid noble gases, J. Mol. Struct., 1990, 222, 1-2, 127, https://doi.org/10.1016/0022-2860(90)80011-8 . [all data]

Creuzburg, Koch, et al., 1989
Creuzburg, M.; Koch, F.; Wittl, F., Low-temperature photolysis of hydrocarbons in solid xenon: Evidence for metastable XenH, Chem. Phys. Lett., 1989, 156, 4, 387, https://doi.org/10.1016/0009-2614(89)87113-1 . [all data]

Wittl, Eberlein, et al., 1993
Wittl, F.; Eberlein, J.; Epple, Th.; Dechant, M.; Creuzburg, M., Bleaching of hydrogen centers in solid xenon by thermally activated tunneling, J. Chem. Phys., 1993, 98, 12, 9554, https://doi.org/10.1063/1.464386 . [all data]

Kunz, McCaffrey, et al., 1991
Kunz, H.; McCaffrey, J.B.; Chergui, M.; Schriever, R.; Unal, O.; Stepanenko, V.; Schwentner, N., Rydberg series of charge-transfer excitations: Cl and H in rare gas crystals, J. Chem. Phys., 1991, 95, 3, 1466, https://doi.org/10.1063/1.461061 . [all data]

Wittl, Creuzburg, et al., 1991
Wittl, F.; Creuzburg, M.; Schriever, R., Formation and electronic energies of the matrix-isolated hydrogen-noble gas molecule, J. Lumin., 1991, 48/49, 611, https://doi.org/10.1016/0022-2313(91)90204-9 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Gurtler, Kraas, et al., 1990
Gurtler, P.; Kraas, M.; Tschentscher, T., Observation of XeD and Xe, Europhys. Lett., 1990, 11, 2, 115, https://doi.org/10.1209/0295-5075/11/2/004 . [all data]

Kraas and Gurtler, 1992
Kraas, M.; Gurtler, P., Rare gas hydrides in rare gas matrices, Phys. Stat. Sol. (a), 1992, 130, 2, K229, https://doi.org/10.1002/pssa.2211300252 . [all data]

Notes

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