Dialuminum monoxide

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx Ar 210 212 Abe and Kolb, 1983

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx Kr 202 217 Abe and Kolb, 1983

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Tx Xe 207 225 Abe and Kolb, 1983

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 37121 ± 15 Ar C-X 263 270 Douglas, Hauge, et al., 1983
To = 36444 ± 15 Kr C-X 267 283 Douglas, Hauge, et al., 1982
Douglas, Hauge, et al., 1983, 2
Douglas, Hauge, et al., 1983
Hebert, Schriever, et al., 1992
gas B-X 248 262 Cai, Carter, et al., 1991
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 Sym. stretch 451 ± 15 Ar AB Douglas, Hauge, et al., 1983
1 Sym. stretch 454 ± 15 Kr AB Douglas, Hauge, et al., 1982
Douglas, Hauge, et al., 1983, 2
Douglas, Hauge, et al., 1983
2 Bend 156 ± 15 Ar AB Douglas, Hauge, et al., 1983
2 Bend 186 ± 15 Kr AB Douglas, Hauge, et al., 1982
Douglas, Hauge, et al., 1983, 2
Douglas, Hauge, et al., 1983

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 23286 ± 15 Kr A-X 415 430 Douglas, Hauge, et al., 1983
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
1 Sym. stretch 482 ± 15 Kr AB Douglas, Hauge, et al., 1983
2 Bend 133 ± 15 Kr AB Douglas, Hauge, et al., 1983

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 Sym. stretch 525 gas LF Cai, Carter, et al., 1991
1 Sym. stretch 472 Ar Ra Ovchinnikov, Serebrennikov, et al., 1985
Rozhanskii, Serebrennikov, et al., 1990
1 Sym. stretch 471 ± 15 Kr LF Douglas, Hauge, et al., 1983
1 Sym. stretch 475 N2 Ra Rozhanskii, Serebrennikov, et al., 1990
Πu 2 Bend 99 gas LF Cai, Carter, et al., 1991
Σu+ 3 Asym. stretch 992 gas LF Cai, Carter, et al., 1991
3 Asym. stretch 992.8 Ar IR Linevsky, White, et al., 1964
Makowiecki, Lynch, et al., 1971
Lynch, Zehe, et al., 1974
Finn, Gruen, et al., 1976
Andrews, Burkholder, et al., 1992
3 Asym. stretch 989.4 Kr IR Linevsky, White, et al., 1964
Makowiecki, Lynch, et al., 1971
3 Asym. stretch 991 N2 IR Sonchik, Andrews, et al., 1983
Andrews, Burkholder, et al., 1992

Additional references: Jacox, 1994, page 63

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xEnergy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state.

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Abe and Kolb, 1983
Abe, H.; Kolb, D.M., Optical Spectra of Matrix-Isolated Aluminium, Ber. Bunsenges. Phys. Chem., 1983, 87, 6, 523, https://doi.org/10.1002/bbpc.19830870613 . [all data]

Douglas, Hauge, et al., 1983
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., High Temp. Sci., 1983, 16, 35. [all data]

Douglas, Hauge, et al., 1982
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., ACS Symposium Ser. 179, American Chemical Society, Washington, D. C., 1982. [all data]

Douglas, Hauge, et al., 1983, 2
Douglas, M.A.; Hauge, R.H.; Margrave, J.L., J. Chem. Soc., 1983, Faraday Trans. 1 79, 1533. [all data]

Hebert, Schriever, et al., 1992
Hebert, T.; Schriever, U.; Kolb, D.M., VIS-VUV spectroscopic study of the reaction between Al and N2O isolated in solid krypton, Chem. Phys. Lett., 1992, 200, 3, 258, https://doi.org/10.1016/0009-2614(92)80007-X . [all data]

Cai, Carter, et al., 1991
Cai, M.; Carter, C.C.; Miller, T.A.; Bondybey, V.E., Fluorescence excitation and resolved emission spectra of supersonically cooled Al2O, J. Chem. Phys., 1991, 95, 1, 73, https://doi.org/10.1063/1.461427 . [all data]

Ovchinnikov, Serebrennikov, et al., 1985
Ovchinnikov, I.V.; Serebrennikov, L.V.; Mal'tsev, A.A., Zh. Fiz. Khim., 1985, 59, 1558. [all data]

Rozhanskii, Serebrennikov, et al., 1990
Rozhanskii, I.L.; Serebrennikov, L.V.; Shevel'kov, A.F., Zh. Fiz. Khim., 1990, 64, 521. [all data]

Linevsky, White, et al., 1964
Linevsky, M.J.; White, D.; Mann, D.E., Infrared Spectrum and Structure of Gaseous Al2O, J. Chem. Phys., 1964, 41, 2, 542, https://doi.org/10.1063/1.1725905 . [all data]

Makowiecki, Lynch, et al., 1971
Makowiecki, D.M.; Lynch, D.A.; Carlson, K.D., Infrared spectra of the aluminum family suboxides, J. Phys. Chem., 1971, 75, 1963. [all data]

Lynch, Zehe, et al., 1974
Lynch, D.A., Jr.; Zehe, M.J.; Carlson, K.D., Reinvestigation of the symmetric stretching mode of matrix-isolated dialuminum monoxide, J. Phys. Chem., 1974, 78, 3, 236, https://doi.org/10.1021/j100596a009 . [all data]

Finn, Gruen, et al., 1976
Finn, P.A.; Gruen, D.M.; Page, D.L., Advan. Chem. Ser. 158, Amer. Chem. Soc., Washington, D. C., 1976. [all data]

Andrews, Burkholder, et al., 1992
Andrews, L.; Burkholder, T.R.; Yustein, J.T., Reactions of pulsed-laser evaporated aluminum atoms with oxygen: infrared spectra of the reaction products in solid argon, J. Phys. Chem., 1992, 96, 25, 10182, https://doi.org/10.1021/j100204a018 . [all data]

Sonchik, Andrews, et al., 1983
Sonchik, S.M.; Andrews, L.; Carlson, K.D., Matrix reactions of molecular oxygen and ozone with aluminum atoms, J. Phys. Chem., 1983, 87, 11, 2004, https://doi.org/10.1021/j100234a033 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Notes

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