Sulfur trifluoride
- Formula: F3S
- Molecular weight: 89.060
- IUPAC Standard InChIKey: PSCXEUSWZWRCMQ-UHFFFAOYSA-N
- CAS Registry Number: 30937-38-3
- Chemical structure:
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
Eq. SF2 s-str. | 843.8 | Ar | IR | Hassanzadeh and Andrews, 1992 | |||
Ax. SF2 a-str. | 681.8 | Ar | IR | Smardzewski and Fox, 1976 Smardzewski and Fox, 1977 Hassanzadeh and Andrews, 1992 | |||
Additional references: Jacox, 1994, page 226; Colussi, Morton, et al., 1974; Morton, Preston, et al., 1978
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Hassanzadeh and Andrews, 1992
Hassanzadeh, P.; Andrews, L.,
Matrix reactions of sulfur atoms and fluorine. Infrared spectra of sulfur monofluoride, sulfur difluoride and sulfur trifluoride in solid argon,
J. Phys. Chem., 1992, 96, 1, 79, https://doi.org/10.1021/j100180a018
. [all data]
Smardzewski and Fox, 1976
Smardzewski, R.R.; Fox, W.B.,
Photolysis of sulfur tetrafluoride in an argon matrix: infrared evidence for formation of the SF3· radical and SF2.,
J. Fluorine Chem., 1976, 7, 1-3, 353, https://doi.org/10.1016/S0022-1139(00)84007-5
. [all data]
Smardzewski and Fox, 1977
Smardzewski, R.R.; Fox, W.B.,
Vacuum ultraviolet photolysis of sulfur hexafluoride and its derivatives in argon matrices. The infrared spectrum of the SF5 radical,
J. Chem. Phys., 1977, 67, 5, 2309, https://doi.org/10.1063/1.435066
. [all data]
Jacox, 1994
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]
Colussi, Morton, et al., 1974
Colussi, A.J.; Morton, J.R.; Preston, K.F.; Fessenden, R.W.,
ESR spectra of PF2 and SF3 radicals,
J. Chem. Phys., 1974, 61, 3, 1247, https://doi.org/10.1063/1.1682004
. [all data]
Morton, Preston, et al., 1978
Morton, J.R.; Preston, K.F.; Strach, S.J.,
The EPR spectrum of SF3 trapped in SF3BF4 crystals,
J. Chem. Phys., 1978, 69, 4, 1392, https://doi.org/10.1063/1.436766
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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