Fluoroimidogen


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas59.500kcal/molReviewChase, 1998Data last reviewed in June, 1965
Quantity Value Units Method Reference Comment
gas,1 bar51.453cal/mol*KReviewChase, 1998Data last reviewed in June, 1965

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1000.1000. to 6000.
A 4.7603118.865682
B 9.7375410.149206
C -8.714291-0.009164
D 2.8655810.000647
E 0.025531-0.334586
F 57.8048055.94799
G 54.8151160.82579
H 59.5001059.50010
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1965 Data last reviewed in June, 1965

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
B - John E. Bartmess

View reactions leading to FN+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.499990EIAESidirov, 1982value altered from reference due to conversion from electron convention to ion convention; B

Ionization energy determinations

IE (eV) Method Reference Comment
12.1 ± 0.4EITarnovsky, Levin, et al., 1994LL
12.26 ± 0.01PEDyke, Jonathan, et al., 1982LBLHLM
12.63 ± 0.01PEDyke, Jonathan, et al., 1982Vertical value; LBLHLM

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Sidirov, 1982
Sidirov, L.N., Molecules with a high electron affinity, Russ. Chem. Rev., 1982, 51, 356. [all data]

Tarnovsky, Levin, et al., 1994
Tarnovsky, V.; Levin, A.; Becker, K., Absolute cross sections for the electron impact ionization of the NF2 and NF free radicals, J. Chem. Phys., 1994, 100, 5626. [all data]

Dyke, Jonathan, et al., 1982
Dyke, J.M.; Jonathan, N.; Lewis, A.E.; Morris, A., Vacuum ultraviolet photoelectron spectroscopy of transient species. Part 14. A study of the ground state of NF+ via the ionization processes NF+(X 2Π)←NF(X3Σ-,a1Δ), J. Chem. Soc. Faraday Trans. 2, 1982, 78, 1445. [all data]


Notes

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