Platinum, (η5-2,4-cyclopentadien-1-yl)trimethyl-
- Formula: C8H14Pt
- Molecular weight: 305.281
- CAS Registry Number: 1271-07-4
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°gas | 245.9 ± 3.2 | kJ/mol | Review | Martinho Simões |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°solid | 168.1 ± 2.4 | kJ/mol | Review | Martinho Simões | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°solid | -5317.0 ± 2.1 | kJ/mol | CC-SB | Tel'noi and Rabinovich, 1977 | Please also see Kharchevnikov and Rabinovich, 1972. |
Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 77.8 ± 2.0 | kJ/mol | N/A | Pilcher and Skinner, 1983 | See also Tel'noi and Rabinovich, 1977, 2.; AC |
ΔsubH° | 77.8 ± 2.1 | kJ/mol | CC-SB | Tel'noi and Rabinovich, 1977 | MS |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.90 | PE | Yang, Bancroft, et al., 1990 | Vertical value |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Martinho Simões
Martinho Simões, J.A.,
Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]
Tel'noi and Rabinovich, 1977
Tel'noi, V.I.; Rabinovich, I.B.,
Russ. Chem. Rev., 1977, 46, 689. [all data]
Kharchevnikov and Rabinovich, 1972
Kharchevnikov, V.M.; Rabinovich, I.B.,
Trudy Khim. Khim.Tekhnol., Gorky, 1972, No. 2, 40. [all data]
Pilcher and Skinner, 1983
Pilcher, G.; Skinner, H.A.,
Thermochemistry of organometallic compounds, 1983, 43-90, https://doi.org/10.1002/9780470771686.ch2
. [all data]
Tel'noi and Rabinovich, 1977, 2
Tel'noi, V.I.; Rabinovich, I.B.,
Thermochemistry of organic compounds of transition metals,
Usp. Khim., 1977, 46, 8, 1337. [all data]
Yang, Bancroft, et al., 1990
Yang, D.S.; Bancroft, G.M.; Puddephatt, R.J.; Tan, K.H.; Cutler, J.N.; Bozek, J.D.,
Assignment of the valence molecular orbitals of CpPtMe3 and Me2Pt(COD) using variable-energy photoelectron spectra,
Inorg. Chem., 1990, 29, 4956. [all data]
Notes
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- Symbols used in this document:
ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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