Butanedioic acid, dimethyl ester
- Formula: C6H10O4
- Molecular weight: 146.1412
- IUPAC Standard InChIKey: MUXOBHXGJLMRAB-UHFFFAOYSA-N
- CAS Registry Number: 106-65-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Succinic acid, dimethyl ester; Dimethyl butanedioate; Dimethyl succinate; Methyl succinate; CH3OC(O)CH2CH2C(O)OCH3; Dimethyl ester of succinic acid; DBE-4
- Permanent link for this species. Use this link for bookmarking this species for future reference.
- Information on this page:
- Other data available:
- Data at other public NIST sites:
- Options:
Data at NIST subscription sites:
NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.
Phase change data
Go To: Top, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
BS - Robert L. Brown and Stephen E. Stein
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tboil | 470. ± 3. | K | AVG | N/A | Average of 8 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
Tfus | 292. ± 1. | K | AVG | N/A | Average of 11 values; Individual data points |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 14.6 ± 0.07 | kcal/mol | GS | Verevkin, Kozlova, et al., 2006 | Based on data from 286. to 340. K.; AC |
ΔvapH° | 14.7 ± 0.1 | kcal/mol | N/A | Katayama, 1992 | Based on data from 342. to 468. K. See also Verevkin, Kozlova, et al., 2006.; AC |
ΔvapH° | 14.6 ± 0.1 | kcal/mol | EB | Daubert, Jalowka, et al., 1987 | Based on data from 367. to 460. K. See also Verevkin, Kozlova, et al., 2006.; AC |
ΔvapH° | 14.9 | kcal/mol | EB | Vlasov, Granzhan, et al., 1963 | Based on data from 398. to 468. K. See also Verevkin, Kozlova, et al., 2006.; AC |
Reduced pressure boiling point
Tboil (K) | Pressure (atm) | Reference | Comment |
---|---|---|---|
353.2 | 0.014 | Weast and Grasselli, 1989 | BS |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
11.8 | 364. | A | Stephenson and Malanowski, 1987 | Based on data from 340. to 470. K.; AC |
References
Go To: Top, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Verevkin, Kozlova, et al., 2006
Verevkin, Sergey P.; Kozlova, Svetlana A.; Emel'yanenko, Vladimir N.; Nikitin, Eugene D.; Popov, Alexander P.; Krasnykh, Eugen L.,
Vapor Pressures, Enthalpies of Vaporization, and Critical Parameters of a Series of Linear Aliphatic Dimethyl Esters of Dicarboxylic Acids,
J. Chem. Eng. Data, 2006, 51, 5, 1896-1905, https://doi.org/10.1021/je0602418
. [all data]
Katayama, 1992
Katayama, Hirotake,
Measurement and estimation of vapor pressures of dimethyl, diethyl, diisopropyl and dibutyl succinates at reduced pressure.,
J. Chem. Eng. Japan / JCEJ, 1992, 25, 4, 366-372, https://doi.org/10.1252/jcej.25.366
. [all data]
Daubert, Jalowka, et al., 1987
Daubert, T.E.; Jalowka, J.W.; Goren, V.,
AIChE Symp. Ser., 1987, 83, 128. [all data]
Vlasov, Granzhan, et al., 1963
Vlasov, O.N.; Granzhan, V.A.; Savenko, L.M.,
Zh. Prikl. Khim., 1963, 36, 2311. [all data]
Weast and Grasselli, 1989
CRC Handbook of Data on Organic Compounds, 2nd Editon, Weast,R.C and Grasselli, J.G., ed(s)., CRC Press, Inc., Boca Raton, FL, 1989, 1. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Notes
Go To: Top, Phase change data, References
- Symbols used in this document:
Tboil Boiling point Tfus Fusion (melting) point ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
- The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
- Customer support for NIST Standard Reference Data products.