Methyl amino radical

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess

View reactions leading to CH4N+ (ion structure unspecified)

Quantity Value Units Method Reference Comment
ΔfH°(+) ion199.kcal/molN/AN/A 

Electron affinity determinations

EA (eV) Method Reference Comment
0.504 ± 0.030LPESRadisic, Xu, et al., 2002B
0.45 ± 0.11D-EAMacKay, Hemsworth, et al., 1976B
<1.55998EIAECollin, Hubin-Franskin, et al., 1968From MeNH2; B

Ionization energy determinations

IE (eV) Method Reference Comment
6.7DERLias, Bartmess, et al., 1988LL

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Radisic, Xu, et al., 2002
Radisic, D.; Xu, S.J.; Bowen, K.H., Photoelectron spectroscopy of the anions, CH3NH- and (CH3)(2)N- and the anion complexes, H-(CH3NH2) and (CH3)(2)N-[(CH3)(2)NH), Chem. Phys. Lett., 2002, 354, 1-2, 9-13, https://doi.org/10.1016/S0009-2614(01)01470-1 . [all data]

MacKay, Hemsworth, et al., 1976
MacKay, G.J.; Hemsworth, R.S.; Bohme, D.K., Absolute gas-phase acidities of CH3NH2, C2H5NH2, (CH3)2NH, and (CH3)3N, Can. J. Chem., 1976, 54, 1624. [all data]

Collin, Hubin-Franskin, et al., 1968
Collin, J.E.; Hubin-Franskin, M.J.; D`Or, L., Negative Ions Produced by Electron Impact in Ammonia, Methylamine, and Deuterated Methylamine-Nd2, Adv. Mass Spectrom., 1968, 4, 713. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]

Notes

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