Nitrosyl hydride


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas23.80kcal/molReviewChase, 1998Data last reviewed in March, 1993
Quantity Value Units Method Reference Comment
gas,1 bar52.753cal/mol*KReviewChase, 1998Data last reviewed in March, 1993

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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View table.

Temperature (K) 298. to 1200.1200. to 6000.
A 4.74650112.48960
B 11.474300.742321
C -6.073292-0.142961
D 1.2511100.009537
E 0.054999-1.781081
F 22.1105016.24260
G 55.6452962.91900
H 23.8000023.80000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1993 Data last reviewed in March, 1993

Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Nitric oxide anion + Hydrogen cation = Nitrosyl hydride

By formula: NO- + H+ = HNO

Quantity Value Units Method Reference Comment
Δr361.27 ± 0.15kcal/molD-EATravers, Cowles, et al., 1989gas phase; ground state triplet anion
Quantity Value Units Method Reference Comment
Δr354.68 ± 0.34kcal/molH-TSTravers, Cowles, et al., 1989gas phase; ground state triplet anion

Fluorine anion + Nitrosyl hydride = (Fluorine anion • Nitrosyl hydride)

By formula: F- + HNO = (F- • HNO)

Quantity Value Units Method Reference Comment
Δr33.0 ± 3.0kcal/molIMRBJanaway, Zhong, et al., 1997gas phase; Actual structure probably HF..NO-

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
B - John E. Bartmess
LL - Sharon G. Lias and Joel F. Liebman

View reactions leading to HNO+ (ion structure unspecified)

Electron affinity determinations

EA (eV) Method Reference Comment
0.338 ± 0.015LPESEllis and Ellison, 1983B

Ionization energy determinations

IE (eV) Method Reference Comment
10.1DERLias, Bartmess, et al., 1988LL

De-protonation reactions

Nitric oxide anion + Hydrogen cation = Nitrosyl hydride

By formula: NO- + H+ = HNO

Quantity Value Units Method Reference Comment
Δr361.27 ± 0.15kcal/molD-EATravers, Cowles, et al., 1989gas phase; ground state triplet anion; B
Quantity Value Units Method Reference Comment
Δr354.68 ± 0.34kcal/molH-TSTravers, Cowles, et al., 1989gas phase; ground state triplet anion; B

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Fluorine anion + Nitrosyl hydride = (Fluorine anion • Nitrosyl hydride)

By formula: F- + HNO = (F- • HNO)

Quantity Value Units Method Reference Comment
Δr33.0 ± 3.0kcal/molIMRBJanaway, Zhong, et al., 1997gas phase; Actual structure probably HF..NO-

References

Go To: Top, Gas phase thermochemistry data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Travers, Cowles, et al., 1989
Travers, M.J.; Cowles, D.C.; Ellison, G.B., Reinvestigation of the Electron Affinities of O2 and NO, Chem. Phys. Lett., 1989, 164, 5, 449, https://doi.org/10.1016/0009-2614(89)85237-6 . [all data]

Janaway, Zhong, et al., 1997
Janaway, G.A.; Zhong, M.; Gatev, G.G.; Chabinyc, M.L.; Brauman, J.I., [FHNO]-: An Intermediate in a Spin-Forbidden Proton Transfer Reaction, J. Am. Chem. Soc., 1997, 119, 48, 11697, https://doi.org/10.1021/ja9726872 . [all data]

Ellis and Ellison, 1983
Ellis, H.B., Jr.; Ellison, G.B., Photoelectron spectroscopy of HNO- and DNO-, J. Chem. Phys., 1983, 78, 6541. [all data]

Lias, Bartmess, et al., 1988
Lias, S.G.; Bartmess, J.E.; Liebman, J.F.; Holmes, J.L.; Levin, R.D.; Mallard, W.G., Gas-phase ion and neutral thermochemistry, J. Phys. Chem. Ref. Data, Suppl. 1, 1988, 17, 1-861. [all data]


Notes

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