gallium trichloride

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Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Quantity Value Units Method Reference Comment
Δsub89. ± 2.kJ/molTEBrunetti, Piacente, et al., 2010Based on data from 289. to 308. K.
Δsub87.1 ± 1.2kJ/molTChusova, Zelenina, et al., 2007Based on data from 313. to 349. K.

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
72.7 ± 0.2349.TChusova, Zelenina, et al., 2007Based on data from 351. to 421. K.

Enthalpy of fusion

ΔfusH (kJ/mol) Temperature (K) Method Reference
11.12349.6DSCChusova, Zelenina, et al., 2007

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
11.52PEDehmer, Berkowitz, et al., 1974 
11.96PEBarker, Lappert, et al., 1975Vertical value
11.96PELappert, Pedley, et al., 1974Vertical value

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Brunetti, Piacente, et al., 2010
Brunetti, Bruno; Piacente, Vincenzo; Scardala, Paolo, Vapor Pressures of Gallium Trifluoride, Trichloride, and Triiodide and Their Standard Sublimation Enthalpies, J. Chem. Eng. Data, 2010, 55, 1, 98-102, https://doi.org/10.1021/je900276q . [all data]

Chusova, Zelenina, et al., 2007
Chusova, T.P.; Zelenina, L.N.; Stenin, Yu.G.; Semenova, Z.I.; Titov, V.A., Thermodynamics of vaporization of gallium trichloride, Russ Chem Bull, 2007, 56, 7, 1313-1317, https://doi.org/10.1007/s11172-007-0200-3 . [all data]

Dehmer, Berkowitz, et al., 1974
Dehmer, J.L.; Berkowitz, J.; Cusachs, L.C.; Aldrich, H.S., Photoelectron spectroscopy of high temperature vapors. V. HeI spectra of GaX3 and InX3 (X = Cl, Br, I), J. Chem. Phys., 1974, 61, 594. [all data]

Barker, Lappert, et al., 1975
Barker, G.K.; Lappert, M.F.; Pedley, J.B.; Sharp, G.J.; Westwood, N.P.C., Bonding studies of boron and the group 3-5 elements. Part XV. He(I) photoelectron spectra of monomeric group 3 tri-halide, trimethyl, and mixed halogenomethyl species, J. Chem. Soc. Dalton Trans., 1975, 1765. [all data]

Lappert, Pedley, et al., 1974
Lappert, M.F.; Pedley, J.B.; Sharp, G.J.; Westwood, N.P.C., Bonding studies of compounds of boron and the Group III and IV elements. XII. Variable temperature HeI photoelectron spectra of Group III halides, 2MX3<=>M2X6(M=Al or Ga, X=Cl, Br, or I), J. Electron Spectrosc. Relat. Phenom., 1974, 3, 237. [all data]


Notes

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