Fullerene-C84
- Formula: C84
- Molecular weight: 1008.8988
- CAS Registry Number: 135113-16-5
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
48.3 ± 0.96 | 853. | ME | Boltalina, Markov, et al., 1998 | Based on data from 658. to 980. K. |
50. ± 1. | 950. | TE | Piacente, Palchetti, et al., 1997 | Based on data from 920. to 1190. K. |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
B - John E. Bartmess
Electron affinity determinations
EA (eV) | Method | Reference | Comment |
---|---|---|---|
0.615 ± 0.010 | LPES | Wang, Woo, et al., 2007 | D2d isomer; B |
0.820 ± 0.010 | LPES | Wang, Woo, et al., 2007 | D2 isomer; B |
0.410 ± 0.070 | LPES | Ehrler, Weber, et al., 2003 | Vertical Detachment Energy: 0.750±0.025 eV; B |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
7.1 | DTI | Beck, Weis, et al., 1994 | LL |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Boltalina, Markov, et al., 1998
Boltalina, Olga V.; Markov, Vitaliy Yu.; Borschevskii, Andrey Ya.; Davydov, Vladimir Ya.; Sidorov, Lev N.; Bezmelnitsin, Valery N.; Eletskii, Alexander V.; Taylor, Roger,
Saturated vapour pressure and enthalpy of sublimation of C84,
Mendeleev Communications, 1998, 8, 4, 141-142, https://doi.org/10.1070/MC1998v008n04ABEH000979
. [all data]
Piacente, Palchetti, et al., 1997
Piacente, V.; Palchetti, C.; Gigli, G.; Scardala, P.,
Preliminary Study on the Vapor Pressure of C 84 Fullerene,
J. Phys. Chem. A, 1997, 101, 24, 4303-4304, https://doi.org/10.1021/jp970821z
. [all data]
Wang, Woo, et al., 2007
Wang, X.B.; Woo, H.K.; Yang, J.; Kappes, M.M.; Wang, L.S.,
Photoelectron spectroscopy of singly and doubly charged higher fullerenes at low temperatures: C-76(-), C-78(-), C-84(-) and C-76(2-), C-78(2-), C-84(2-),
J. Phys. Chem. C, 2007, 111, 48, 17684-17689, https://doi.org/10.1021/jp0703861
. [all data]
Ehrler, Weber, et al., 2003
Ehrler, O.T.; Weber, J.M.; Furche, F.; Kappes, M.M.,
Photoelectron spectroscopy of C-84 dianions,
Phys. Rev. Lett., 2003, 91, 11, 391-402, https://doi.org/10.1103/PhysRevLett.91.113006
. [all data]
Beck, Weis, et al., 1994
Beck, R.D.; Weis, P.; Brauchle, G.; Kappes, M.M.,
Mechanistic aspects of fullerene coalescence upon ultraviolet laser desorption from thin films,
J. Chem. Phys., 1994, 100, 262. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
EA Electron affinity ΔsubH Enthalpy of sublimation - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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