germanium tetrabromide
- Formula: Br4Ge
- Molecular weight: 392.26
- CAS Registry Number: 13450-92-5
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Phase change data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔvapH° | 11.1 ± 0.07 | kcal/mol | N/A | Zelenina, Chusova, et al., 2004 | Based on data from 299. to 373. K. |
Quantity | Value | Units | Method | Reference | Comment |
ΔsubH° | 14.0 ± 0.29 | kcal/mol | N/A | Zelenina, Chusova, et al., 2004 | Based on data from 273. to 299. K. |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
3.071 | 299.3 | AC | Berezovskii, Zelenina, et al., 1999 | Based on data from 5. to 315. K. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
10.62 ± 0.04 | PI | Creasey, Lambert, et al., 1991 | LL |
10.75 | PE | Green, Green, et al., 1970 | RDSH |
10.8 ± 0.3 | EI | Uy, Muenow, et al., 1969 | RDSH |
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
Br+ | 22.3 ± 0.6 | ? | PI | Creasey, Lambert, et al., 1991 | LL |
Br+ | 22. ± 1. | ? | EI | Uy, Muenow, et al., 1969 | RDSH |
BrGe+ | 13.6 ± 0.1 | ? | PI | Creasey, Lambert, et al., 1991 | LL |
GeBr+ | 15. ± 1. | ? | EI | Uy, Muenow, et al., 1969 | RDSH |
Br2+ | 19.5 ± 0.5 | ? | EI | Uy, Muenow, et al., 1969 | RDSH |
GeBr2+ | 15. ± 1. | ? | EI | Uy, Muenow, et al., 1969 | RDSH |
Br3Ge+ | 10.97 ± 0.04 | Br | PI | Creasey, Lambert, et al., 1991 | LL |
GeBr3+ | 11.0 ± 0.3 | Br | EI | Uy, Muenow, et al., 1969 | RDSH |
Ge+ | 21.4 ± 0.5 | ? | PI | Creasey, Lambert, et al., 1991 | LL |
Ge+ | 20. ± 1. | ? | EI | Uy, Muenow, et al., 1969 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Zelenina, Chusova, et al., 2004
Zelenina, L.N.; Chusova, T.P.; Stenin, Yu.G.,
Zh. Fiz. Khim., 2004, 78, 4, 598. [all data]
Berezovskii, Zelenina, et al., 1999
Berezovskii, G.A.; Zelenina, L.N.; Chusova, T.P.; Paukov, I.E.,
Thermodynamic functions of germanium tetrabromide in temperature interval 5-315 K,
Zh. Fiz. Khim., 1999, 73, 8, 1504. [all data]
Creasey, Lambert, et al., 1991
Creasey, J.C.; Lambert, I.R.; Tuckett, R.P.; Codling, K.; Leszek, J.F.; Hatherly, P.A.; Stankiewicz, M.,
Photoionization mass-spectrometric study of fragmentation of SiBr4 and GeBr4 in the range 400-1220 A,
J. Chem. Soc. Faraday Trans., 1991, 87, 3717. [all data]
Green, Green, et al., 1970
Green, J.C.; Green, M.L.H.; Joachim, P.J.; Orchard, A.F.; Turner, D.W.,
A study of the bonding in the group IV tetrahalides by photoelectron spectroscopy,
Phil. Trans. Roy. Soc. (London), 1970, A268, III. [all data]
Uy, Muenow, et al., 1969
Uy, O.M.; Muenow, D.W.; Margrave, J.L.,
Mass spectrometric studies at high temperatures. Part 35. Stabilities of gaseous GeCl2 and GeBr2,
J. Chem. Soc. Faraday Trans., 1969, 65, 1296. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy ΔfusH Enthalpy of fusion ΔsubH° Enthalpy of sublimation at standard conditions ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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