Hydrochloric acid-d

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Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas-22.31kcal/molReviewChase, 1998Data last reviewed in June, 1977
Quantity Value Units Method Reference Comment
gas,1 bar46.066cal/mol*KReviewChase, 1998Data last reviewed in June, 1977

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (cal/mol*K)
    H° = standard enthalpy (kcal/mol)
    S° = standard entropy (cal/mol*K)
    t = temperature (K) / 1000.

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Temperature (K) 298. to 1300.1300. to 6000.
A 6.0644708.513970
B 1.6396910.307687
C 0.896536-0.041890
D -0.6340160.002762
E 0.031941-0.863706
F -24.09039-26.60631
G 53.0626054.21260
H -22.31000-22.31000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in June, 1977 Data last reviewed in June, 1977

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Ptriple0.12346atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.00007 atm
Ptriple0.12366atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.00007 atm
Ptriple0.12356atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.00005 atm; estimated for pure DCl, based on amount of H in samples
Quantity Value Units Method Reference Comment
Tc323.5KN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.32 K
Quantity Value Units Method Reference Comment
Pc79.15atmN/AHenderson, Lewis, et al., 1986Uncertainty assigned by TRC = 0.0791 atm; Vapor Pressure measured up to 226 K and Pc determined from fitted Wagner equation

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Reaction thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

Chlorine anion + Hydrochloric acid-d = (Chlorine anion • Hydrochloric acid-d)

By formula: Cl- + DCl = (Cl- • DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
16.8300.ICRLarson and McMahon, 1987gas phase; switching reaction(Cl-)HCl; Caldwell and Kebarle, 1985

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

IE (eV) Method Reference Comment
12.756 ± 0.005PEWeiss, Lawrence, et al., 1970RDSH

Ion clustering data

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

Chlorine anion + Hydrochloric acid-d = (Chlorine anion • Hydrochloric acid-d)

By formula: Cl- + DCl = (Cl- • DCl)

Bond type: Hydrogen bond (negative ion to hydride)

Free energy of reaction

ΔrG° (kcal/mol) T (K) Method Reference Comment
16.8300.ICRLarson and McMahon, 1987gas phase; switching reaction(Cl-)HCl; Caldwell and Kebarle, 1985

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Henderson, Lewis, et al., 1986
Henderson, C.; Lewis, D.G.; Prichard, P.C.; Staveley, L.A.K.; Fonseca, I.M.A.; Lobo, L.Q., Some thermodynamic properties of hydrogen chloride and deuterium chloride, J. Chem. Thermodyn., 1986, 18, 1077. [all data]

Larson and McMahon, 1987
Larson, J.W.; McMahon, T.B., Isotope Effects in Proton Transfer Reactions. An Ion Cyclotron Resonance Determination of the Equilibrium Deuterium Isotope Effect in the Bichloride Ion, J. Phys. Chem., 1987, 91, 3, 554, https://doi.org/10.1021/j100287a013 . [all data]

Caldwell and Kebarle, 1985
Caldwell, G.; Kebarle, P., The hydrogen bond energies of the bihalide ions XHX- and YHX-, Can. J. Chem., 1985, 63, 1399. [all data]

Weiss, Lawrence, et al., 1970
Weiss, M.J.; Lawrence, G.M.; Young, R.A., Photoelectron spectroscopy of HCI and DCI using molecular beams, J. Chem. Phys., 1970, 52, 2867. [all data]


Notes

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