Methylene, difluoro-

• Formula: CF₂
• Molecular weight: 50.0075
• IUPAC Standard InChI: InChI=1S/CF2/c2-1-3 Copy

  
• IUPAC Standard InChIKey: LTVOKYUPTHZZQH-UHFFFAOYSA-N Copy
• CAS Registry Number: 2154-59-8
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Calcium difluoride; Difluoromethylene
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Reaction thermochemistry data
  • Gas phase ion energetics data
  • Ion clustering data
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Vibrational and/or electronic energy levels
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Electron-Impact Ionization Cross Sections (on physics web site)
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
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• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

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Reaction thermochemistry data

Go To: Top, Gas phase ion energetics data, Ion clustering data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. A general reaction search form is also available. Future versions of this site may rely on reaction search pages in place of the enumerated reaction displays seen below.

Individual Reactions

(CF₃^- • 4294967295) +  = CF₃^-

By formula: (CF₃^- • 4294967295CF₂) + CF₂ = CF₃^-

(CAS Reg. No. 53959-80-1 • 4294967295) +  = CAS Reg. No. 53959-80-1

By formula: (CAS Reg. No. 53959-80-1 • 4294967295CF₂) + CF₂ = CAS Reg. No. 53959-80-1

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
B - John E. Bartmess

View reactions leading to CF₂⁺ (ion structure unspecified)

Electron affinity determinations

Ionization energy determinations

Appearance energy determinations

Ion clustering data

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

(CF₃^- • 4294967295) +  = CF₃^-

By formula: (CF₃^- • 4294967295CF₂) + CF₂ = CF₃^-

References

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Deyerl, Alconcel, et al., 2001
Deyerl, H.J.; Alconcel, L.S.; Continetti, R.E., Photodetachment imaging studies of the electron affinity of CF3, J. Phys. Chem. A, 2001, 105, 3, 552-557, https://doi.org/10.1021/jp003137k . [all data]

Bartmess, Scott, et al., 1979
Bartmess, J.E.; Scott, J.A.; McIver, R.T., Jr., The gas phase acidity scale from methanol to phenol, J. Am. Chem. Soc., 1979, 101, 6047. [all data]

Paulino and Squires, 1991
Paulino, J.A.; Squires, R.R., Carbene Thermochemistry from Collision-Induced Dissociation Threshold Energy Measurements - The Heats of Formation of X1A1 CF2 and X1A1 CCl2, J. Am. Chem. Soc., 1991, 113, 15, 5573, https://doi.org/10.1021/ja00015a009 . [all data]

Paulino and Squires, 1991, 2
Paulino, J.A.; Squires, R.R., Carbene Anion Complexes - Unusual Structural and Thermochemical Features of alpha-Halocarbanions in the Gas Phase, J. Am. Chem. Soc., 1991, 113, 5, 1845, https://doi.org/10.1021/ja00005a067 . [all data]

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Schwartz, Davico, et al., 1999
Schwartz, R.L.; Davico, G.E.; Ramond, T.M.; Lineberger, W.C., Singlet-triplet splittings in CX2 (X = F, Cl, Br, I) dihalocarbenes via negative ion photoelectron spectroscopy, J. Phys. Chem. A, 1999, 103, 41, 8213-8221, https://doi.org/10.1021/jp992214c . [all data]

Murray, Leopold, et al., 1988
Murray, K.K.; Leopold, D.G.; Miller, T.M.; Lineberger, W.C., Photoelectron Spectroscopy of the Halocarbene Anions HCF^-, HCCl^-, HCBr^-, HCI^-, CF₂^-, and CCl₂^-, J. Chem. Phys., 1988, 89, 9, 5442, https://doi.org/10.1063/1.455596 . [all data]

Born, Ingemann, et al., 1994
Born, M.; Ingemann, S.; Nibbering, N.M.M., Heats of formation of mono-halogen-substituted carbenes. Stability and reactivity of CHX(center dot-) (X=F, Cl, Pr, and I) radical anions, J. Am. Chem. Soc., 1994, 116, 16, 7210, https://doi.org/10.1021/ja00095a025 . [all data]

Harland and Thynne, 1972
Harland, P.W.; Thynne, J.C.J., Ionisation of perfluorocyclobutane by electron impact, Int. J. Mass Spectrom. Ion Phys., 1972, 10, 11. [all data]

Thynne and MacNeil, 1970
Thynne, J.C.J.; MacNeil, K.A.G., Ionisation of Tetrafluoroethylene by Electron Impact, Int. J. Mass Spectrom. Ion Phys., 1970, 5, 3-4, 329, https://doi.org/10.1016/0020-7381(70)80026-2 . [all data]

Page and Goode, 1969
Page, F.M.; Goode, G.C., Negative Ions and the Magnetron., Wiley, NY, 1969. [all data]

Buckley, Johnson, et al., 1995
Buckley, T.J.; Johnson, R.D.; Huie, R.E.; Zhang, Z.; Kuo, S.C.; Klemm, R.B., Ionization energies, appearance energies, and thermochemistry of CF₂O and FCO, J. Phys. Chem., 1995, 99, 4879. [all data]

Goto, Nakamura, et al., 1994
Goto, M.; Nakamura, K.; Toyoda, H.; Sugai, H., Cross section measurements for electron-impact dissociation of CHF₃ into neutral and ionic fragments, Jpn. J. Appl. Phys. Part 1, 1994, 33, 3602. [all data]

Tarnovsky and Becker, 1993
Tarnovsky, V.; Becker, K., Absolute partial cross sections for the parent ionization of the CF_x (x = 1-3) free radicals by electron impact, J. Chem. Phys., 1993, 98, 7868. [all data]

Hildenbrand, 1975
Hildenbrand, D.L., Vertical ionization potential of the CF₂ radical, Chem. Phys. Lett., 1975, 32, 30. [all data]

Dyke, Golob, et al., 1974
Dyke, J.M.; Golob, L.; Jonathan, N.; Morris, A.; Okuda, M., Vacuum ultraviolet photoelectron spectroscopy of transient species. Part 4. Difluoromethylene and ozone, J. Chem. Soc. Faraday Trans. 2, 1974, 70, 1828. [all data]

Reinke, Kraessig, et al., 1973
Reinke, D.; Kraessig, R.; Baumgartel, H., Photoreactions of small organic molecules, Z. Naturforsch. A:, 1973, 28, 1021. [all data]

Hildenbrand, 1973
Hildenbrand, D.L., Mass spectrometric studies of some gaseous sulfur fluorides, J. Phys. Chem., 1973, 77, 897. [all data]

Ehlert, 1969
Ehlert, T.C., Bonding in C₁ and C₂ fluorides, J. Phys. Chem., 1969, 73, 949. [all data]

Zmbov, Uy, et al., 1968
Zmbov, K.F.; Uy, M.; Margrave, J.L., Mass spectrometric study of the high-temperature equilibrium C₂F₄ = 2CF₂ and the heat of formation of the CF₂ radical, J. Am. Chem. Soc., 1968, 90, 5090. [all data]

Pottie, 1965
Pottie, R.F., Ionization potential and heat of formation of the difluoromethylene radical, J. Chem. Phys., 1965, 42, 2607. [all data]

Fisher, Homer, et al., 1965
Fisher, I.P.; Homer, J.B.; Lossing, F.P., Free radicals by mass spectrometry. XXXIII. Ionization potentials of CF₂, CF₃CF₂, CF₃CH₂, n-C₃F₇, and i-C₃F₇ radicals, J. Am. Chem. Soc., 1965, 87, 957. [all data]

Tarnovsky, Kurunczi, et al., 1993
Tarnovsky, V.; Kurunczi, P.; Rogozhnikov, D.; Becker, K., Absolute cross sections for the dissociative electron impact ionization of the CFx (x=1-3) free radicals, Int. J. Mass Spectrom. Ion Processes, 1993, 128, 181. [all data]

Notes

Go To: Top, Reaction thermochemistry data, Gas phase ion energetics data, Ion clustering data, References

• Symbols used in this document:
  

  AE	Appearance energy
  EA	Electron affinity
  IE (evaluated)	Recommended ionization energy
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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