Mercury, diphenyl-
- Formula: C12H10Hg
- Molecular weight: 354.80
- IUPAC Standard InChI: InChI=1S/2C6H5.Hg/c2*1-2-4-6-5-3-1;/h2*1-5H;
- IUPAC Standard InChIKey: HWMTUNCVVYPZHZ-UHFFFAOYSA-N
- CAS Registry Number: 587-85-9
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Benzene, mercuriodi-; Diphenylmercury
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Gas phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: José A. Martinho Simões
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°gas | 410. ± 80. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing
| Quantity | Value | Units | Method | Reference | Comment |
|---|---|---|---|---|---|
| ΔfH°solid | 300. ± 80. | kJ/mol | AVG | N/A | Average of 7 values; Individual data points |
| Quantity | Value | Units | Method | Reference | Comment |
| ΔcH°solid | -6434.2 ± 7.9 | kJ/mol | CC-SB | Carson and Wilmshurst, 1971 | MS |
| ΔcH°solid | -6431.2 ± 7.5 | kJ/mol | CC-SB | Fairbrother and Skinner, 1956 | Please also see Cox and Pilcher, 1970.; MS |
| ΔcH°solid | -6549.2 | kJ/mol | CC-SB | Berthelot, 1899 | Please also see Berthelot, 1900.; MS |
Constant pressure heat capacity of solid
| Cp,solid (J/mol*K) | Temperature (K) | Reference | Comment |
|---|---|---|---|
| 225.5 | 298.5 | Smith and Andrews, 1931 | T = 102 to 346 K. Value is unsmoothed experimental datum.; DH |
Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 8.32 | PE | Furlani, Piancastelli, et al., 1981 | LLK |
| 9.4 ± 0.2 | EI | Glockling, Irwin, et al., 1976 | LLK |
| 8.30 ± 0.03 | PI | Rodionov, Potapov, et al., 1973 | LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| C6H5Hg+ | 11.5 ± 0.2 | C6H5 | EI | Glockling, Irwin, et al., 1976 | LLK |
| Hg+ | 10.0 ± 0.2 | ? | EI | Glockling, Irwin, et al., 1976 | LLK |
References
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Carson and Wilmshurst, 1971
Carson, A.S.; Wilmshurst, B.R.,
J. Chem. Thermodyn., 1971, 3, 251. [all data]
Fairbrother and Skinner, 1956
Fairbrother, D.M.; Skinner, H.A.,
Trans. Faraday Soc., 1956, 52, 956. [all data]
Cox and Pilcher, 1970
Cox, J.D.; Pilcher, G.,
Thermochemistry of Organic and Organometallic Compounds
in Academic Press, New York, 1970. [all data]
Berthelot, 1899
Berthelot, M.,
Compt. Rend., 1899, 129, 918. [all data]
Berthelot, 1900
Berthelot, M.,
Ann. Chim. Phys., 1900, 20, 158. [all data]
Smith and Andrews, 1931
Smith, R.H.; Andrews, D.H.,
Thermal energy studies. II. Phenyl derivatives of metals,
J. Am. Chem. Soc., 1931, 53, 3661-3667. [all data]
Furlani, Piancastelli, et al., 1981
Furlani, C.; Piancastelli, M.N.; Cauletti, C.; Faticanti, F.; Ortaggi, G.,
He(I) and He(II) photoelectron spectra of some organomercury compounds with carbon π-systems,
J. Electron Spectrosc. Relat. Phenom., 1981, 22, 309. [all data]
Glockling, Irwin, et al., 1976
Glockling, F.; Irwin, J.G.; Morrison, R.J.; Sweeney, J.J.,
A mass spectroscopic study of organomercurials and mercuric halides,
Inorg. Chim. Acta, 1976, 19, 267. [all data]
Rodionov, Potapov, et al., 1973
Rodionov, A.N.; Potapov, V.K.; Rogozhin, K.L.,
Photoionization of certain aromatic heteroorganic compounds,
High Energy Chem., 1973, 7, 249, In original 278. [all data]
Notes
Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy Cp,solid Constant pressure heat capacity of solid ΔcH°solid Enthalpy of combustion of solid at standard conditions ΔfH°gas Enthalpy of formation of gas at standard conditions ΔfH°solid Enthalpy of formation of solid at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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