Disiloxane, hexamethyl-

• Formula: C₆H₁₈OSi₂
• Molecular weight: 162.3775
• IUPAC Standard InChI: InChI=1S/C6H18OSi2/c1-8(2,3)7-9(4,5)6/h1-6H3 Copy

  
• IUPAC Standard InChIKey: UQEAIHBTYFGYIE-UHFFFAOYSA-N Copy
• CAS Registry Number: 107-46-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
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• Other names: Bis(trimethylsilyl) ether; Bis(trimethylsilyl) oxide; Fluka AG; Hexamethyldisiloxane; ((CH3)3Si)2O; Oxybis(trimethylsilane); Silane, oxybis(trimethyl)-; Dow corning 200/0.65; H7310; HMDSO; Belsil DM 0.65; Disiloxane, 1,1,1,3,3,3-hexamethyl-; KF 96L; NSC 43346; OS 10; SWS-F 221; DC 200 FLUID (Salt/Mix)
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• Information on this page:
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Other data available:
  • Condensed phase thermochemistry data
  • Phase change data
  • IR Spectrum
  • Gas Chromatography
• Data at other public NIST sites:
  • Gas Phase Kinetics Database
  • X-ray Photoelectron Spectroscopy Database, version 5.0
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

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Additional Data

References

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Hunter and Lias, 1998
Hunter, E.P.; Lias, S.G., Evaluated Gas Phase Basicities and Proton Affinities of Molecules: An Update, J. Phys. Chem. Ref. Data, 1998, 27, 3, 413-656, https://doi.org/10.1063/1.556018 . [all data]

Seefeldt, Moller, et al., 1985
Seefeldt, R.; Moller, W.; Schmidt, M., Zur elektronenstossionisierung des hexamethyldisiloxans (HMDS), Z. Phys. Chem. (Leipzig), 1985, 266, 797. [all data]

Molder, Pikver, et al., 1983
Molder, U.H.; Pikver, R.J.; Koppel, I.A., Photoelectron spectra of molecules. 2. Ethers, Org. React. (N.Y. Engl. Transl.), 1983, 20, 208. [all data]

Hess, Lampe, et al., 1965
Hess, G.G.; Lampe, F.W.; Sommer, L.H., An electron impact study of ionization and dissociation of trimethylsilanes, J. Am. Chem. Soc., 1965, 87, 5327. [all data]

Starzewski, Dieck, et al., 1974
Starzewski, K.A.O.; Dieck, H.T.; Bock, H., Photoelectron spectra molecular properties. XXIII. Photoelectron spectra of silicon-substituted ylidic systems, J. Organomet. Chem., 1974, 65, 311. [all data]

Borossay, Csakvari, et al., 1971
Borossay, J.; Csakvari, B.; Szepes, L., Determination of bond energies of organic silicon compounds on the basis of appearance potentials, Int. J. Mass Spectrom. Ion Phys., 1971, 7, 47. [all data]

Notes

Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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