Cyclohexane, fluoro-
- Formula: C6H11F
- Molecular weight: 102.1499
- IUPAC Standard InChIKey: GOBGVVAHHOUMDK-UHFFFAOYSA-N
- CAS Registry Number: 372-46-3
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Cyclohexyl fluoride; Fluorocyclohexane
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Condensed phase thermochemistry data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔfH°liquid | -89.40 ± 0.20 | kcal/mol | Ccr | Schaffer, Verevkin, et al., 1997 | |
Quantity | Value | Units | Method | Reference | Comment |
ΔcH°liquid | -893.54 ± 0.20 | kcal/mol | Ccr | Schaffer, Verevkin, et al., 1997 |
Phase change data
Go To: Top, Condensed phase thermochemistry data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tc | 667.93 | K | N/A | D'Souza and Teja, 1987 | Uncertainty assigned by TRC = 3. K; Ambrose's procedure; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 51.0495 | atm | N/A | D'Souza and Teja, 1987 | Uncertainty assigned by TRC = 0.987 atm; Ambrose's procedure; TRC |
Quantity | Value | Units | Method | Reference | Comment |
ΔvapH° | 8.95 ± 0.17 | kcal/mol | V | Schaffer, Verevkin, et al., 1997 | ALS |
ΔvapH° | 8.96 ± 0.07 | kcal/mol | GS | Schaffer, Verevkin, et al., 1997 | Based on data from 271. to 301. K.; AC |
Enthalpy of vaporization
ΔvapH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
8.37 | 331. | A | Stephenson and Malanowski, 1987 | Based on data from 316. to 373. K.; AC |
Enthalpy of fusion
ΔfusH (kcal/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
0.617 | 285.3 | Gonthier-Vassal and Szwarc, 1986 | AC |
References
Go To: Top, Condensed phase thermochemistry data, Phase change data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Schaffer, Verevkin, et al., 1997
Schaffer, F.; Verevkin, S.P.; Rieger, H.J.; Beckhaus, H.D.; Ruchardt, C.,
Enthalpies of formation of a series of fluorinated hydrocarbons and strain-free group increments to assess polar and anomeric stabilization and strain,
Liebigs Ann., 1997, 1333-1344. [all data]
D'Souza and Teja, 1987
D'Souza, R.; Teja, A.S.,
The prediction of the vapor pressures of carboxylic acids,
Chem. Eng. Commun., 1987, 61, 13. [all data]
Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw,
Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2
. [all data]
Gonthier-Vassal and Szwarc, 1986
Gonthier-Vassal, Anne; Szwarc, Henri,
Glassy crystals. Glass transitions in crystalline fluoro-, cyano-, and isocyano-cyclohexane,
Chemical Physics Letters, 1986, 129, 1, 5-8, https://doi.org/10.1016/0009-2614(86)80158-0
. [all data]
Notes
Go To: Top, Condensed phase thermochemistry data, Phase change data, References
- Symbols used in this document:
Pc Critical pressure Tc Critical temperature ΔcH°liquid Enthalpy of combustion of liquid at standard conditions ΔfH°liquid Enthalpy of formation of liquid at standard conditions ΔfusH Enthalpy of fusion ΔvapH Enthalpy of vaporization ΔvapH° Enthalpy of vaporization at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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