Hydrogen chloride
- Formula: ClH
- Molecular weight: 36.461
- IUPAC Standard InChIKey: VEXZGXHMUGYJMC-UHFFFAOYSA-N
- CAS Registry Number: 7647-01-0
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Isotopologues:
- Other names: Hydrochloric ccid; Anhydrous hydrochloric acid; Chlorohydric acid; Hydrochloric acid gas; Hydrochloride; Muriatic acid; Salzsaeure; HCl; Hydrochloric acid, anhydrous; Hydrogen-chloride-anhydrous-; Acide chlorhydrique; Acido cloridrico; Chloorwaterstof; Chlorowodor; Chlorwasserstoff; NA 1789; Spirits of salt; UN 1050; UN 1789; UN 2186; Anhydrous hydrogen chloride; Hydrogen chloride (acid); Marine acid; Soldering acid; Spirit of salt; Spirits of salts; Hydrogen chloride (HCl); NSC 77365; Hydrochloric acid
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Phase change data
Go To: Top, IR Spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
Tfus | 161.15 | K | N/A | Beckmann and Waentig, 1910 | Uncertainty assigned by TRC = 2. K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Ptriple | 0.13800 | bar | N/A | Henderson, Lewis, et al., 1986 | Uncertainty assigned by TRC = 0.00006 bar; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Tc | 324.68 | K | N/A | Henderson, Lewis, et al., 1986 | Uncertainty assigned by TRC = 0.03 K; TRC |
Quantity | Value | Units | Method | Reference | Comment |
Pc | 82.56 | bar | N/A | Henderson, Lewis, et al., 1986 | Uncertainty assigned by TRC = 0.0824 bar; VP measured up to 219 K and Pc determined from fitted Wagner equation; TRC |
Enthalpy of vaporization
ΔvapH (kJ/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
16.2 | 188. | C | Giauque and Wiebe, 1928 | AC |
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (bar)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
122.3 to 188.3 | 3.60765 | 535.172 | -39.847 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
188.3 to 309.4 | 4.57389 | 868.358 | 1.754 | Stull, 1947 | Coefficents calculated by NIST from author's data. |
Enthalpy of sublimation
ΔsubH (kJ/mol) | Temperature (K) | Reference | Comment |
---|---|---|---|
19.7 | 127. | Ser and Larher, 1990 | Based on data from 121. to 133. K.; AC |
19.6 | 142. | Ser and Larher, 1990 | Based on data from 134. to 150. K.; AC |
IR Spectrum
Go To: Top, Phase change data, References, Notes
Data compiled by: Coblentz Society, Inc.
- GAS (200 mmHg DILUTED TO A TOTAL PRESSURE OF 600 mmHg WITH N2); DOW KBr FOREPRISM; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 4 cm-1 resolution
- GAS (200 mmHg, N2 ADDED, TOTAL PRESSURE 600 mmHg); DOW KBr FOREPRISM-GRATING; DIGITIZED BY NIST FROM HARD COPY (FROM TWO SEGMENTS); 2 cm-1 resolution
References
Go To: Top, Phase change data, IR Spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Beckmann and Waentig, 1910
Beckmann, E.; Waentig, P.,
Cryoscopic Measurements at Low Temperatures,
Z. Anorg. Chem., 1910, 67, 17. [all data]
Henderson, Lewis, et al., 1986
Henderson, C.; Lewis, D.G.; Prichard, P.C.; Staveley, L.A.K.; Fonseca, I.M.A.; Lobo, L.Q.,
Some thermodynamic properties of hydrogen chloride and deuterium chloride,
J. Chem. Thermodyn., 1986, 18, 1077. [all data]
Giauque and Wiebe, 1928
Giauque, W.F.; Wiebe, R.,
THE ENTROPY OF HYDROGEN CHLORIDE. HEAT CAPACITY FROM 16°K. TO BOILING POINT. HEAT OF VAPORIZATION. VAPOR PRESSURES OF SOLID AND LIQUID,
J. Am. Chem. Soc., 1928, 50, 1, 101-122, https://doi.org/10.1021/ja01388a013
. [all data]
Stull, 1947
Stull, Daniel R.,
Vapor Pressure of Pure Substances. Organic and Inorganic Compounds,
Ind. Eng. Chem., 1947, 39, 4, 517-540, https://doi.org/10.1021/ie50448a022
. [all data]
Ser and Larher, 1990
Ser, Frederic; Larher, Yves,
Sublimation pressures of hydrogen chloride,
The Journal of Chemical Thermodynamics, 1990, 22, 4, 407-412, https://doi.org/10.1016/0021-9614(90)90129-E
. [all data]
Notes
Go To: Top, Phase change data, IR Spectrum, References
- Symbols used in this document:
Pc Critical pressure Ptriple Triple point pressure Tc Critical temperature Tfus Fusion (melting) point ΔsubH Enthalpy of sublimation ΔvapH Enthalpy of vaporization - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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