1,2,4-Trioxolane


Gas phase thermochemistry data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Glushko Thermocenter, Russian Academy of Sciences, Moscow

Constant pressure heat capacity of gas

Cp,gas (J/mol*K) Temperature (K) Reference Comment
34.2950.Dorofeeva O.V., 1992p=1 bar. Selected Cp(T) values are in good agreement with those calculated by [ Kuhne H., 1976], while S(T) values are about 6 J/mol*K larger. This discrepancy is due to taking into account of optical isomers for C2 conformation by [ Dorofeeva O.V., 1992].
39.24100.
44.36150.
50.83200.
63.79273.15
68.9 ± 4.0298.15
69.23300.
89.72400.
107.83500.
122.65600.
134.68700.
144.53800.
152.69900.
159.511000.
165.261100.
170.131200.
174.291300.
177.841400.
180.901500.

Phase change data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: William E. Acree, Jr., James S. Chickos

Enthalpy of vaporization

ΔvapH (kJ/mol) Temperature (K) Method Reference Comment
34.8281.AStephenson and Malanowski, 1987Based on data from 273. to 289. K. See also Garvin and Schubert S.J., 1956.

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi

Ionization energy determinations

IE (eV) Method Reference Comment
10.1PEBrown and Marcinko, 1978LLK
10.67 ± 0.03PEBrown and Marcinko, 1978Vertical value; LLK

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Dorofeeva O.V., 1992
Dorofeeva O.V., Ideal gas thermodynamic properties of oxygen heterocyclic compounds. Part 1. Three-membered, four-membered and five-membered rings, Thermochim. Acta, 1992, 194, 9-46. [all data]

Kuhne H., 1976
Kuhne H., Spectroscopic study of the ozone-ethylene reaction. Matrix-infrared spectra of three isotopic ethylene ozonides., J. Phys. Chem., 1976, 80, 1238-1247. [all data]

Stephenson and Malanowski, 1987
Stephenson, Richard M.; Malanowski, Stanislaw, Handbook of the Thermodynamics of Organic Compounds, 1987, https://doi.org/10.1007/978-94-009-3173-2 . [all data]

Garvin and Schubert S.J., 1956
Garvin, David; Schubert S.J., The Vapor Phase Infrared Spectra Of The Ozonides Of Ethylene, Propylene And Isobutylent, J. Phys. Chem., 1956, 60, 6, 807-808, https://doi.org/10.1021/j150540a030 . [all data]

Brown and Marcinko, 1978
Brown, R.S.; Marcinko, R.W., Photoelectron spectra of the ozonides of ethylene, cyclopentene, and cyclohexene. Experimental evidence for the magnitude of the "pure" inductive effect of an ether oxygen on ionization energy, J. Am. Chem. Soc., 1978, 100, 5584. [all data]


Notes

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