2,4,6,8,9,10-Hexaoxa-1,3,5,7-tetraarsatricyclo[3.3.1.13,7]decane
- Formula: As4O6
- Molecular weight: 395.6828
- IUPAC Standard InChI: InChI=1S/As4O6/c5-1-6-3-8-2(5)9-4(7-1)10-3
- IUPAC Standard InChIKey: KTTMEOWBIWLMSE-UHFFFAOYSA-N
- CAS Registry Number: 12505-67-8
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: 2,4,6,7,8,10-Hexaoxa-1,3,5,7-tetraarsatricyclo[3.3.1.13,7]decane; Arsentrioxid
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Gas phase ion energetics data
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
Ionization energy determinations
| IE (eV) | Method | Reference | Comment |
|---|---|---|---|
| 10.3 ± 0.3 | EI | Brittain, Lau, et al., 1982 | LBLHLM |
| 10.05 | PE | Egdell, Palmer, et al., 1980 | Vertical value; LLK |
| 10.01 ± 0.05 | PE | Diemann, 1977 | Vertical value; LLK |
| 10.05 | PE | Cannington and Whitfield, 1977 | Vertical value; LLK |
Appearance energy determinations
| Ion | AE (eV) | Other Products | Method | Reference | Comment |
|---|---|---|---|---|---|
| As2O3+ | 18.0 ± 1.0 | ? | EI | Brittain, Lau, et al., 1982 | LBLHLM |
| As3O4+ | 13.0 ± 0.3 | ? | EI | Brittain, Lau, et al., 1982 | LBLHLM |
| As4O5+ | 15.5 ± 0.5 | O | EI | Brittain, Lau, et al., 1982 | LBLHLM |
References
Go To: Top, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Brittain, Lau, et al., 1982
Brittain, R.D.; Lau, K.H.; Hildenbrand, D.L.,
Molecular species in the As-O system,
J. Phys. Chem., 1982, 86, 5072. [all data]
Egdell, Palmer, et al., 1980
Egdell, R.G.; Palmer, M.H.; Findlay, R.H.,
Electronic structure of the group 5 oxides: Photoelectron spectra and ab initio molecular orbital calculations,
Inorg. Chem., 1980, 19, 1314. [all data]
Diemann, 1977
Diemann, E.,
The orbital electronic structure of the As4O6 molecule by photoelectron spectroscopy,
Inorg. Chim. Acta, 1977, 24, 27. [all data]
Cannington and Whitfield, 1977
Cannington, P.H.; Whitfield, H.J.,
Photoelectron spectra of As4S3, P4S3, P4Se3, and As4O6,
J. Electron Spectrosc. Relat. Phenom., 1977, 10, 35. [all data]
Notes
Go To: Top, Gas phase ion energetics data, References
- Symbols used in this document:
AE Appearance energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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