Fluorine nitrate

Data at NIST subscription sites:

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.


Gas phase thermochemistry data

Go To: Top, Phase change data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Quantity Value Units Method Reference Comment
Δfgas10.46kJ/molReviewChase, 1998Data last reviewed in March, 1963
Quantity Value Units Method Reference Comment
gas,1 bar292.93J/mol*KReviewChase, 1998Data last reviewed in March, 1963

Gas Phase Heat Capacity (Shomate Equation)

Cp° = A + B*t + C*t2 + D*t3 + E/t2
H° − H°298.15= A*t + B*t2/2 + C*t3/3 + D*t4/4 − E/t + F − H
S° = A*ln(t) + B*t + C*t2/2 + D*t3/3 − E/(2*t2) + G
    Cp = heat capacity (J/mol*K)
    H° = standard enthalpy (kJ/mol)
    S° = standard entropy (J/mol*K)
    t = temperature (K) / 1000.

View plot Requires a JavaScript / HTML 5 canvas capable browser.

View table.

Temperature (K) 298. to 1100.1100. to 6000.
A 31.64016106.1380
B 160.55641.081908
C -133.7537-0.217921
D 40.671790.015041
E -0.310670-8.304028
F -6.052282-43.14792
G 287.1847389.4522
H 10.4600010.46000
ReferenceChase, 1998Chase, 1998
Comment Data last reviewed in March, 1963 Data last reviewed in March, 1963

Phase change data

Go To: Top, Gas phase thermochemistry data, Vibrational and/or electronic energy levels, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director

Quantity Value Units Method Reference Comment
Tboil231.KN/AYost and Beerbower, 1935Uncertainty assigned by TRC = 4. K

In addition to the Thermodynamics Research Center (TRC) data available from this site, much more physical and chemical property data is available from the following TRC products:


Vibrational and/or electronic energy levels

Go To: Top, Gas phase thermochemistry data, Phase change data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   X


Vib. 
sym. 
 No.   Approximate 
 type of mode 
 cm-1   Med.   Method   References

a' 1 NO2 a-stretch 1760.9 vs gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
1 NO2 a-stretch 1758.4 Ne IR Casper, Dixon, et al., 1994
2 NO2 s-stretch 1301.2 vs gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
2 NO2 s-stretch 1300.9 Ne IR Casper, Dixon, et al., 1994
3 OF stretch 927 m gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
3 OF stretch 929.8 Ne IR Casper, Dixon, et al., 1994
4 NO2 scissors 803.4 s gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
4 NO2 scissors 802.7 Ne IR Casper, Dixon, et al., 1994
5 O-N stretch 632.9 w gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
5 O-N stretch 635.0 Ne IR Casper, Dixon, et al., 1994
6 NO2 rock 458.5 m s gas IR Ra Arvia, Cafferata, et al., 1963
Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
Casper, Dixon, et al., 1994
6 NO2 rock 459.9 Ne IR Casper, Dixon, et al., 1994
7 OF rock 302.6 w gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
7 OF rock 300.0 Ne IR Casper, Dixon, et al., 1994
a 8 NO2 wag 707.3 m gas IR Miller, Bernitt, et al., 1967
Casper, Dixon, et al., 1994
8 NO2 wag 710.0 Ne IR Casper, Dixon, et al., 1994
9 Torsion 151.6 w gas IR Ra Miller, Bernitt, et al., 1967
Shamir, Yellin, et al., 1974
9 Torsion 161.0 Ne IR Casper, Dixon, et al., 1994

Additional references: Jacox, 1998, page 302

Notes

wWeak
mMedium
sStrong
vsVery strong

References

Go To: Top, Gas phase thermochemistry data, Phase change data, Vibrational and/or electronic energy levels, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Chase, 1998
Chase, M.W., Jr., NIST-JANAF Themochemical Tables, Fourth Edition, J. Phys. Chem. Ref. Data, Monograph 9, 1998, 1-1951. [all data]

Yost and Beerbower, 1935
Yost, D.M.; Beerbower, A., The Reaction of Cluorine with Nitric Acid and With Solid Potassium Nitrate to Form NO3F, J. Am. Chem. Soc., 1935, 57, 782. [all data]

Arvia, Cafferata, et al., 1963
Arvia, A.J.; Cafferata, L.F.R.; Schumacher, H.J., Das Infrarotspektrum und die Struktur von NO3Cl und NO3F, Chem. Ber., 1963, 96, 5, 1187, https://doi.org/10.1002/cber.19630960502 . [all data]

Miller, Bernitt, et al., 1967
Miller, R.H.; Bernitt, D.L.; Hisatsune, I.C., Spectrochim. Acta, 1967, 23A, 223. [all data]

Shamir, Yellin, et al., 1974
Shamir, J.; Yellin, D.; Claassen, H.H., Isr. J. Chem., 1974, 12, 1015. [all data]

Casper, Dixon, et al., 1994
Casper, B.; Dixon, D.A.; Mack, H.-G.; Ulic, S.E.; Willner, H.; Oberhammer, H., Molecular Structure of Fluorine Nitrate: Dangerous for Experiment and Theory, J. Am. Chem. Soc., 1994, 116, 18, 8317, https://doi.org/10.1021/ja00097a044 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]


Notes

Go To: Top, Gas phase thermochemistry data, Phase change data, Vibrational and/or electronic energy levels, References