neptunium
- Formula: Np
- Molecular weight: 237
- IUPAC Standard InChIKey: LFNLGNPSGWYGGD-UHFFFAOYSA-N
- CAS Registry Number: 7439-99-8
- Chemical structure:
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Phase change data
Go To: Top, Gas phase ion energetics data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Antoine Equation Parameters
log10(P) = A − (B / (T + C))
P = vapor pressure (atm)
T = temperature (K)
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Temperature (K) | A | B | C | Reference | Comment |
---|---|---|---|---|---|
1617.99 to 2073.99 | 4.15147 | 19215.926 | -114.171 | Ackermann and Rauh, 1975 | Coefficents calculated by NIST from author's data. |
Gas phase ion energetics data
Go To: Top, Phase change data, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
L - Sharon G. Lias
Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 6.2655 ± 0.0002 | eV | N/A | N/A | L |
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
6.2655 ± 0.0002 | LS | Trautmann, 1994 | LL |
6.2657 | EVAL | Lide, 1992 | LL |
6.2657 ± 0.0005 | S | Worden and Conway, 1979 | LLK |
6.1 ± 0.1 | EI | Rauh and Ackermann, 1975 | LLK |
6.19 ± 0.12 | EVAL | Sugar, 1974 | LLK |
6.20 ± 0.12 | S | Sugar, 1973 | LLK |
6.16 ± 0.06 | SI | Smith and Hertel, 1969 | RDSH |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Ackermann and Rauh, 1975
Ackermann, R.J.; Rauh, E.G.,
The Thermodynamics of Vaporization of Neptunium and Plutonium,
J. Chem. Thermodyn., 1975, 7, 3, 211-218, https://doi.org/10.1016/0021-9614(75)90058-0
. [all data]
Trautmann, 1994
Trautmann, N.,
Accurate determination of the first ionization potential of actinides by laser spectroscopy,
J. Alloys Compd., 1994, 213/214, 28. [all data]
Lide, 1992
Lide, D.R. (Editor),
Ionization potentials of atoms and atomic ions
in Handbook of Chem. and Phys., 1992, 10-211. [all data]
Worden and Conway, 1979
Worden, E.F.; Conway, J.G.,
Laser spectroscopy of neptunium; first ionization potential, lifetimes and new high-lying energy levels of Np I,
J. Opt. Soc. Am., 1979, 69, 733. [all data]
Rauh and Ackermann, 1975
Rauh, E.G.; Ackermann, R.J.,
The first ionization potentials of neptunium and neptunium monoxide,
J. Chem. Phys., 1975, 62, 1584. [all data]
Sugar, 1974
Sugar, J.,
Revised ionization energies of the neutral actinides,
J. Chem. Phys., 1974, 60, 4103. [all data]
Sugar, 1973
Sugar, J.,
Ionization energies of the neutral actinides,
J. Chem. Phys., 1973, 59, 788. [all data]
Smith and Hertel, 1969
Smith, D.H.; Hertel, G.R.,
First ionization potentials of Th, Np, and Pu by surface ionization,
J. Chem. Phys., 1969, 51, 3105. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, References
- Symbols used in this document:
IE (evaluated) Recommended ionization energy - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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