CF3OOO
- Formula: CF3O3
- Molecular weight: 117.0041
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: ?
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
Tx = 41000 | O2 | von Ahsen, Willner, et al., 2003 | |||||
State: X
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
1 | OO stretch | 1500 | w m | O2 | IR | von Ahsen, Willner, et al., 2003 | |
2 | CO stretch | 1223 | vs | O2 | IR | von Ahsen, Willner, et al., 2003 | |
3 | CF a-stretch | 1211 | s | O2 | IR | von Ahsen, Willner, et al., 2003 | |
4 | CF a-stretch | 1182 | s | O2 | IR | von Ahsen, Willner, et al., 2003 | |
5 | CF s-stretch | 895 | w | O2 | IR | von Ahsen, Willner, et al., 2003 | |
6 | CF3 umbrella | 615 | w | O2 | IR | von Ahsen, Willner, et al., 2003 | |
8 | CF3 deform. | 581 | w | O2 | IR | von Ahsen, Willner, et al., 2003 | |
9 | CF3 scissors | 450 | w | O2 | IR | von Ahsen, Willner, et al., 2003 | |
11 | OOO bend | 239 | w | O2 | IR | von Ahsen, Willner, et al., 2003 | |
12 | O-O2 stretch | 219 | w | O2 | IR | von Ahsen, Willner, et al., 2003 | |
Notes
w | Weak |
m | Medium |
s | Strong |
vs | Very strong |
x | Energy separation between the band maximum of the excited electronic state and the v = 0 level of the ground state. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
von Ahsen, Willner, et al., 2003
von Ahsen, S.; Willner, H.; Francisco, J.S.,
The Trifluoromethyltrioxy Radical, CF3OOO,
Angew. Chem. Ind. Ed., 2003, 42, 38, 4690, https://doi.org/10.1002/anie.200351909
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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