Fluorine nitrate

Formula: FNO₃
Molecular weight: 81.0033
IUPAC Standard InChI: InChI=1S/FNO3/c1-5-2(3)4
IUPAC Standard InChIKey: VHFBTKQOIBRGQP-UHFFFAOYSA-N
CAS Registry Number: 7789-26-6
Chemical structure:
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Vibrational and/or electronic energy levels

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Data compiled by: Marilyn E. Jacox

State: X

Vib. sym.	No.	Approximate type of mode	cm^-1		Med.	Method	References


a'	1	NO₂ a-stretch	1760.9	vs	gas	IR Ra	Arvia, Cafferata, et al., 1963 Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974 Casper, Dixon, et al., 1994
	1	NO₂ a-stretch	1758.4		Ne	IR	Casper, Dixon, et al., 1994
	2	NO₂ s-stretch	1301.2	vs	gas	IR Ra	Arvia, Cafferata, et al., 1963 Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974 Casper, Dixon, et al., 1994
	2	NO₂ s-stretch	1300.9		Ne	IR	Casper, Dixon, et al., 1994
	3	OF stretch	927	m	gas	IR Ra	Arvia, Cafferata, et al., 1963 Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974 Casper, Dixon, et al., 1994
	3	OF stretch	929.8		Ne	IR	Casper, Dixon, et al., 1994
	4	NO₂ scissors	803.4	s	gas	IR Ra	Arvia, Cafferata, et al., 1963 Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974 Casper, Dixon, et al., 1994
	4	NO₂ scissors	802.7		Ne	IR	Casper, Dixon, et al., 1994
	5	O-N stretch	632.9	w	gas	IR Ra	Arvia, Cafferata, et al., 1963 Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974 Casper, Dixon, et al., 1994
	5	O-N stretch	635.0		Ne	IR	Casper, Dixon, et al., 1994
	6	NO₂ rock	458.5	m s	gas	IR Ra	Arvia, Cafferata, et al., 1963 Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974 Casper, Dixon, et al., 1994
	6	NO₂ rock	459.9		Ne	IR	Casper, Dixon, et al., 1994
	7	OF rock	302.6	w	gas	IR Ra	Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974
	7	OF rock	300.0		Ne	IR	Casper, Dixon, et al., 1994
a	8	NO₂ wag	707.3	m	gas	IR	Miller, Bernitt, et al., 1967 Casper, Dixon, et al., 1994
	8	NO₂ wag	710.0		Ne	IR	Casper, Dixon, et al., 1994
	9	Torsion	151.6	w	gas	IR Ra	Miller, Bernitt, et al., 1967 Shamir, Yellin, et al., 1974
	9	Torsion	161.0		Ne	IR	Casper, Dixon, et al., 1994

Additional references: Jacox, 1998, page 302

Notes

Weak

Medium

Strong

Very strong

References

Go To: Top, Vibrational and/or electronic energy levels, Notes

Arvia, Cafferata, et al., 1963
Arvia, A.J.; Cafferata, L.F.R.; Schumacher, H.J., Das Infrarotspektrum und die Struktur von NO3Cl und NO3F, Chem. Ber., 1963, 96, 5, 1187, https://doi.org/10.1002/cber.19630960502 . [all data]

Miller, Bernitt, et al., 1967
Miller, R.H.; Bernitt, D.L.; Hisatsune, I.C., Spectrochim. Acta, 1967, 23A, 223. [all data]

Shamir, Yellin, et al., 1974
Shamir, J.; Yellin, D.; Claassen, H.H., Isr. J. Chem., 1974, 12, 1015. [all data]

Casper, Dixon, et al., 1994
Casper, B.; Dixon, D.A.; Mack, H.-G.; Ulic, S.E.; Willner, H.; Oberhammer, H., Molecular Structure of Fluorine Nitrate: Dangerous for Experiment and Theory, J. Am. Chem. Soc., 1994, 116, 18, 8317, https://doi.org/10.1021/ja00097a044 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

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Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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