Nitric oxide
- Formula: NO
- Molecular weight: 30.0061
- IUPAC Standard InChIKey: MWUXSHHQAYIFBG-UHFFFAOYSA-N
- CAS Registry Number: 10102-43-9
- Chemical structure:
This structure is also available as a 2d Mol file or as a computed 3d SD file
The 3d structure may be viewed using Java or Javascript. - Other names: Nitrogen oxide; Nitrogen monoxide; Nitrosyl radical; NO; Amidogen, oxo-; Nitrogen oxide (NO); UN 1660
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Henry's Law data
Go To: Top, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Rolf Sander
Henry's Law constant (water solution)
kH(T) = k°H exp(d(ln(kH))/d(1/T) ((1/T) - 1/(298.15 K)))
k°H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(kH))/d(1/T) = Temperature dependence constant (K)
k°H (mol/(kg*bar)) | d(ln(kH))/d(1/T) (K) | Method | Reference | Comment |
---|---|---|---|---|
0.0019 | 1400. | L | N/A | |
0.0019 | 1700. | Q | N/A | Only the tabulated data between T = 273. K and T = 303. K from missing citation was used to derive kH and -Δ kH/R. Above T = 303. K the tabulated data could not be parameterized by equation (reference missing) very well. The partial pressure of water vapor (needed to convert some Henry's law constants) was calculated using the formula given by missing citation. The quantities A and α from missing citation were assumed to be identical. |
0.0019 | C | N/A | ||
0.0019 | 1500. | L | N/A | |
0.0014 | M | N/A | ||
7.9×10-7 | 3800. | L | N/A |
Gas phase ion energetics data
Go To: Top, Henry's Law data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data evaluated as indicated in comments:
HL - Edward P. Hunter and Sharon G. Lias
L - Sharon G. Lias
Data compiled as indicated in comments:
B - John E. Bartmess
MM - Michael M. Meot-Ner (Mautner)
LL - Sharon G. Lias and Joel F. Liebman
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron
View reactions leading to NO+ (ion structure unspecified)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
IE (evaluated) | 9.2642 ± 0.00002 | eV | N/A | N/A | L |
Quantity | Value | Units | Method | Reference | Comment |
Proton affinity (review) | 531.8 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Quantity | Value | Units | Method | Reference | Comment |
Gas basicity | 505.3 | kJ/mol | N/A | Hunter and Lias, 1998 | HL |
Proton affinity at 298K
Proton affinity (kJ/mol) | Reference | Comment |
---|---|---|
526.1 ± 1.3 | Kuo, Zhang, et al., 1997 | T = 0K; Photoionization of HNO yields DHf(HNO+) from which PA(NO) is calculated at 0 K and 298K.; MM |
Ionization energy determinations
Appearance energy determinations
Ion | AE (eV) | Other Products | Method | Reference | Comment |
---|---|---|---|---|---|
N+ | 19.56 | O- | PI | Erman, Karawajczyk, et al., 1995 | LL |
N+ | 21.02 | O | PI | Erman, Karawajczyk, et al., 1995 | LL |
N+ | 19.56 ± 0.03 | O- | PI | Oertel, Schenk, et al., 1980 | LLK |
N+ | 19.6 ± 0.2 | O- | EI | Locht and Momigny, 1971 | LLK |
N+ | 19.94 ± 0.14 | O- | EI | Hierl and Franklin, 1967 | RDSH |
N+ | 34.1 ± 0.7 | O+ | EI | Appell, Durup, et al., 1966 | RDSH |
N+ | 19.55 ± 0.04 | O- | EI | Cloutier and Schiff, 1959 | RDSH |
N+ | 21.11 ± 0.04 | O | EI | Cloutier and Schiff, 1959 | RDSH |
N4+ | 21.78 ± 0.11 | O | EI | Hierl and Franklin, 1967 | RDSH |
O+ | 20.12 | N | PI | Erman, Karawajczyk, et al., 1995 | LL |
O+ | 20.1 ± 0.3 | N | EI | Doong and Bizot, 1973 | LLK |
O+ | 20.46 ± 0.10 | N | EI | Hierl and Franklin, 1967 | RDSH |
O+ | 20.11 ± 0.03 | N | EI | Cloutier and Schiff, 1959 | RDSH |
Anion protonation reactions
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 1511.6 ± 0.63 | kJ/mol | D-EA | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
Quantity | Value | Units | Method | Reference | Comment |
ΔrG° | 1484.0 ± 1.4 | kJ/mol | H-TS | Travers, Cowles, et al., 1989 | gas phase; ground state triplet anion; B |
Ion clustering data
Go To: Top, Henry's Law data, Gas phase ion energetics data, IR Spectrum, Mass spectrum (electron ionization), Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Michael M. Meot-Ner (Mautner) and Sharon G. Lias
Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.
Clustering reactions
By formula: NO- + NO = (NO- • NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 57.7 | kJ/mol | PI | Linn, Ono, et al., 1981 | gas phase |
ΔrH° | 56.9 | kJ/mol | PI | Ng, Tiedemann, et al., 1977 | gas phase |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
29. | 296. | SAMS | Puckett and Teague, 1971 | gas phase |
By formula: (NO- • NO) + NO = (NO- • 2NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 31. | kJ/mol | PI | Linn, Ono, et al., 1981 | gas phase |
Free energy of reaction
ΔrG° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
7.9 | 296. | SAMS | Puckett and Teague, 1971 | gas phase |
By formula: (NO- • 2NO) + NO = (NO- • 3NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15. | kJ/mol | PI | Linn, Ono, et al., 1981 | gas phase |
By formula: (NO- • 3NO) + NO = (NO- • 4NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 15. | kJ/mol | PI | Linn, Ono, et al., 1981 | gas phase |
By formula: (NO- • 4NO) + NO = (NO- • 5NO)
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔrH° | 9.6 | kJ/mol | PI | Linn, Ono, et al., 1981 | gas phase |
By formula: Ni+ + NO = (Ni+ • NO)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
123. (+6.7,-0.) | CID | Khan, Steele, et al., 1995 | gas phase; guided ion beam CID |
By formula: (Ni+ • NO) + NO = (Ni+ • 2NO)
Enthalpy of reaction
ΔrH° (kJ/mol) | T (K) | Method | Reference | Comment |
---|---|---|---|---|
115. (+5.0,-0.) | CID | Khan, Steele, et al., 1995 | gas phase; guided ion beam CID |
IR Spectrum
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Coblentz Society, Inc.
Gas Phase Spectrum
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Notice: Except where noted, spectra from this collection were measured on dispersive instruments, often in carefully selected solvents, and hence may differ in detail from measurements on FTIR instruments or in other chemical environments. More information on the manner in which spectra in this collection were collected can be found here.
Notice: Concentration information is not available for this spectrum and, therefore, molar absorptivity values cannot be derived.
Additional Data
View scan of original (hardcopy) spectrum.
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Download spectrum in JCAMP-DX format.
Owner | COBLENTZ SOCIETY Collection (C) 2018 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
Origin | WYANDOTTE CHEMICALS CORP., WYANDOTTE, MICHIGAN, USA |
Source reference | COBLENTZ NO. 1000 |
Date | 1960 |
State | GAS; $$ MATHESON CO. 99% PURE |
Instrument | Not specified, most likely a prism, grating, or hybrid spectrometer. |
Path length | 500 CM |
Resolution | 4 |
Sampling procedure | TRANSMISSION |
Data processing | DIGITIZED BY NIST FROM HARD COPY |
Mass spectrum (electron ionization)
Go To: Top, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Constants of diatomic molecules, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
View image of digitized spectrum (can be printed in landscape orientation).
Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 31 |
Constants of diatomic molecules
Go To: Top, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Klaus P. Huber and Gerhard H. Herzberg
Data collected through March, 1977
Symbol | Meaning |
---|---|
State | electronic state and / or symmetry symbol |
Te | minimum electronic energy (cm-1) |
ωe | vibrational constant – first term (cm-1) |
ωexe | vibrational constant – second term (cm-1) |
ωeye | vibrational constant – third term (cm-1) |
Be | rotational constant in equilibrium position (cm-1) |
αe | rotational constant – first term (cm-1) |
γe | rotation-vibration interaction constant (cm-1) |
De | centrifugal distortion constant (cm-1) |
βe | rotational constant – first term, centrifugal force (cm-1) |
re | internuclear distance (Å) |
Trans. | observed transition(s) corresponding to electronic state |
ν00 | position of 0-0 band (units noted in table) |
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
---|---|---|---|---|---|---|---|---|---|---|---|---|
For a detailed discussion of the electronic spectrum with particular emphasis on Rydberg ~ Rydberg and Rydberg ~ non-Rydberg interactions see Miescher and Huber, 1976; this review contains references to spectra of four isotopes as well as a short summary of theoretical calculations. | ||||||||||||
(2Σ-,2Δ,2Σ+) 2 | Broad unresolved peak in the oxygen K shell electron energy loss spectrum at 532.7 eV. 1 | |||||||||||
↳Wight and Brion, 1974 | ||||||||||||
Rydberg states converging to the nitrogen K edge at 410.2 (3Π) and 411.6 (1Π) eV, observed in X-ray absorption and electron energy loss spectra at 406.3, 407.3, 408.6 eV, ... | ||||||||||||
↳Morioka, Nakamura, et al., 1974; Wight and Brion, 1974 | ||||||||||||
(2Σ-) 4 | Two very weak bands in the X-ray absorption spectrum at 402.3 and 403.9 eV. 3 | |||||||||||
↳Morioka, Nakamura, et al., 1974 | ||||||||||||
(2Δ,2Σ+,2Σ-) 5 | Two very weak bands in the X-ray absorption spectrum at 402.3 and 403.9 eV. 3 | |||||||||||
↳Morioka, Nakamura, et al., 1974 | ||||||||||||
(2Σ-,2Δ,2Σ+) 7 | Strong unresolved peak in X-ray absorption and electron energy loss spectra at 399.8 eV.6 | |||||||||||
↳Morioka, Nakamura, et al., 1974; Wight and Brion, 1974 | ||||||||||||
Narayana 9 | Narayana and Price's absorption Rydberg series converging to c 3Π of NO+: | |||||||||||
4σ5σ21π42π ndλ ν = 175220 - R/(n+0.05)2, n = 3...7. All bands diffuse.8 | ||||||||||||
↳missing citation; Sasanuma, Morioka, et al., 1974 | ||||||||||||
4σ5σ21π42π npλ ν = 175220 - R/(n-0.70)2, n = 3...6. All bands diffuse.8 | ||||||||||||
↳missing citation; Sasanuma, Morioka, et al., 1974 | ||||||||||||
Fragments of an additional series Sasanuma, Morioka, et al., 1974. Additional cross sections 700 - 180 Å (143000 - 556000 cm-1). | ||||||||||||
↳Gardner, Lynch, et al., 1973; Lee, Carlson, et al., 1973 | ||||||||||||
Tanaka 11 | Tanaka's absorption Rydberg series converging to A 1Π(v=0) and b 3Π(v=0) of NP+: | |||||||||||
5σ1π42π npλ ν ≈ 147805 - R/(n-0.78)2; γ series, n=3...11.10 Also fragments of weak series with v'=1. | ||||||||||||
↳Tanaka, 1942; missing citation; Edqvist, Lindholm, et al., 1970 | ||||||||||||
5σ1π42π npλ ν ≈ 133570 - R/(n-0.70)2; β series, n=3...15.10 Also fragments of weak series with v'=1. | ||||||||||||
↳Tanaka, 1942; missing citation; Edqvist, Lindholm, et al., 1970 | ||||||||||||
1π32π nsσ Rydberg series converging to a 3Σ+, w 3Δ, b 3Σ-, A 1Σ-, W 1Δ of NO+. Only the first two or three members of each absorption series have been identified; long upper state progressions. Tables of absorption features 950 - 650 Å (105000 - 154000 cm-1) Tanaka, 1942, Huber, 1961*, Metzger, Cook, et al., 1967*. Absorption coefficients, photoionization and photodissociation yields Reese and Rosenstock, 1966, Metzger, Cook, et al., 1967, Watanabe, Matsunaga, et al., 1967, Bahr, Blake, et al., 1972, Hertz, Jochims, et al., 1974. | ||||||||||||
↳Edqvist, Lindholm, et al., 1970 | ||||||||||||
The band structure of the absorption spectrum from 80000 to 105000 cm-1 has not yet been analyzed. Absorption coefficients, photoionization efficiency curves Nicholson, 1963, Reese and Rosenstock, 1966, Watanabe, Matsunaga, et al., 1967; the data of Watanabe, Matsunaga, et al., 1967 are conveiently plotted in Figure 6 of Gardner and Samson, 1973 and Figure 4 of Kleimenov, Chizhov, et al., 1972. Autoionization processes have been studied by photoelectron spectroscopy Collin, Delwiche, et al., 1971, Gardner and Samson, 1973, Caprace, Delwiche, et al., 1976; partial cross-sections for the formation of vibrationally excited NO+ Kleimenov, Chizhov, et al., 1972. | ||||||||||||
Atlas of the absorption spectrum 1420 - 1250 Å (70400 - 80000 cm-1) Miescher and Alberti, 1976; for a photographic reproduction of the spectrum at longer wavelengths (1920 - 1400 Å) see Lagerqvist and Miescher, 1958. A useful quantitative low-resolution plot of the absorption from 2300 to 1100 Å may be found in Figure 2.1 of Miescher and Huber, 1976, adapted from Marmo, 1953. Absorption coefficients, photoionization efficiency curves Watanabe, Marmo, et al., 1953, Watanabe, Matsunaga, et al., 1967, Killgoar, Leroi, et al., 1973, and Ng, Mahan, et al., 1976 whose supersonic molecular beam technique made it possible to resolve the autoionization strucutre superimposed on the first four vibrational steps due to direct ionization. | ||||||||||||
Rydberg series converging to v=0...4 of X 1Σ+ of NO+ and fragments of series with v'=5: | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
nf series 12 | nf ← X | |||||||||||
↳missing citation; missing citation | ||||||||||||
ndδ series 13 | ndδ ← X | |||||||||||
↳missing citation; Miescher and Huber, 1976; missing citation | ||||||||||||
npπ,σ series 14 | npπ,σ ← X | |||||||||||
↳missing citation; Miescher and Huber, 1976; missing citation | ||||||||||||
nsσ series 15 | nsσ ← X | |||||||||||
↳missing citation; Miescher and Huber, 1976; missing citation | ||||||||||||
Several unnassigned non-Rydberg levels, mixed with Rydberg levels, near the dissociation limit 2D + 3P at 71627 cm-1. | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
6f | 71427 | 2376 H | 16.2 | 6f ← X | 71543 | |||||||
↳Miescher, 1966; missing citation | ||||||||||||
71427 | 2376 H | 16.2 | 6f ← X | 71662.6 H | ||||||||
↳Miescher, 1966; missing citation | ||||||||||||
6dδ | (71342) | (2397) H | (23) | [1.86] | 6dδ ← X V | 71467 | ||||||
↳Miescher, 1966; missing citation; Miescher, 1976 | ||||||||||||
(71342) | (2397) H | (23) | [1.86] | 6dδ ← X V | 71586 16 Z | |||||||
↳Miescher, 1966; missing citation; Miescher, 1976 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
Z 2Σ+ 7sσ | 71224 | 2377 H | 16.4 | [1.938] | Z ← X V | 71340 | ||||||
↳Miescher, 1966; missing citation | ||||||||||||
71224 | 2377 H | 16.4 | [1.938] | Z ← X V | 71460 16 Z | |||||||
↳Miescher, 1966; missing citation | ||||||||||||
Y 2Σ+ 6pσ | 70614 | 2370 | 15.0 | [2.11] 17 | Y ← X V | 70728 | ||||||
↳Dressler and Miescher, 1965; Miescher, 1966; missing citation | ||||||||||||
70847 18 Z | ||||||||||||
↳Dressler and Miescher, 1965; Miescher, 1966; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
W 2Π 6pπ | 70512 | 2375 | 15.6 19 | W ← X | 70627 | |||||||
↳Dressler and Miescher, 1965; Miescher, 1966; missing citation | ||||||||||||
70747 | ||||||||||||
↳Dressler and Miescher, 1965; Miescher, 1966; missing citation | ||||||||||||
5f | 70079 | 2377 H | 16.5 | [1.988] 20 | 5f ← X | 70195 | ||||||
↳Dressler and Miescher, 1965; Miescher, 1966; missing citation | ||||||||||||
70315 21 | ||||||||||||
↳Dressler and Miescher, 1965; Miescher, 1966; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
U 2Δ5dδ | (69977) | 2371 | 16.4 22 | U ← X | (70090) | |||||||
↳Miescher, 1966; missing citation; Miescher, 1976 | ||||||||||||
(70210) | ||||||||||||
↳Miescher, 1966; missing citation; Miescher, 1976 | ||||||||||||
T 2Σ+6sσ | (69728) | 2372 | 15.7 23 | T ← X V | (69841) | |||||||
↳Miescher, 1966; missing citation | ||||||||||||
(69961) | ||||||||||||
↳Miescher, 1966; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
R 2Σ+5pσ | (68598) | [2.04] 24 25 | R ← X V | 68710.9 | ||||||||
↳Dressler and Miescher, 1965; missing citation | ||||||||||||
68830.7 18 Z | ||||||||||||
↳Dressler and Miescher, 1965; missing citation | ||||||||||||
Q 2Π5pπ 26 | Q ← X | 68526 | ||||||||||
↳Dressler and Miescher, 1965; missing citation | ||||||||||||
Q 2Π5pπ | 68646 | |||||||||||
↳Dressler and Miescher, 1965; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
O' 2Π 4dπ | (67762) 27 | (2371) | (16) | [2.022] 28 | O,O' → D | 14702.2 | ||||||
↳Huber, 1964; missing citation | ||||||||||||
14697.9 | ||||||||||||
↳Huber, 1964; missing citation | ||||||||||||
O 2Σ+ 4dσ | (67757) | (2371) | (16) | [1.990] 28 | O,O' → C | 15623 | ||||||
↳Huber, 1964; missing citation | ||||||||||||
15619 | ||||||||||||
↳Huber, 1964; missing citation | ||||||||||||
O,O' ← X | 67874.8 | |||||||||||
↳Miescher, 1966; missing citation | ||||||||||||
O,O' ← X | 67870.5 | |||||||||||
↳Miescher, 1966; missing citation | ||||||||||||
O,O' ← X | 67994.5 18 Z | |||||||||||
↳Miescher, 1966; missing citation | ||||||||||||
O,O' ← X | 67990.3 18 Z | |||||||||||
↳Miescher, 1966; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
4f | 67596 | 2381 H | 18.5 | [1.988] 20 | [1.0657] | 4f ← X | 67713 | |||||
↳Miescher, 1966; missing citation | ||||||||||||
67833 21 | ||||||||||||
↳Miescher, 1966; missing citation | ||||||||||||
N 2Δ4dδ | 67374 | 2375 29 | 15 29 | 1.969 29 | 0.026 29 | N → C 30 | 15238 29 | |||||
↳Huber, 1964; missing citation | ||||||||||||
N ↔ X V | 67489 | |||||||||||
↳Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
N ↔ X V | 67609 29 | |||||||||||
↳Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
S 2Σ+5sσ | 66900 | 2378 Z | 16.5 | 1.980 | 0.020 | S ← X V | 67016 | |||||
↳Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; Lagerqvist and Miescher, 1966 | ||||||||||||
67136 18 Z | ||||||||||||
↳Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; Lagerqvist and Miescher, 1966 | ||||||||||||
M 2Σ+4pσ | 64437 | 2352 Z | 19.5 | 2.022 31 | 0.018 | M ← X V | 64540 | |||||
↳Barrow and Miescher, 1957; Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
M ← X V | 64660 18 Z | |||||||||||
↳Barrow and Miescher, 1957; Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
K 2Π4pπ 34 | [1.895] 32 33 | K ← X V | 64167 | |||||||||
↳Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; missing citation | ||||||||||||
K 2Π4pπ | [1.895] 32 33 | K ← X V | 64287 18 35 Z | |||||||||
↳Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; missing citation | ||||||||||||
I 2Σ+ | (63500) 36 | I ← X R | ||||||||||
↳Dressler and Miescher, 1965; Miescher, 1976 | ||||||||||||
G 2Σ- | 62913.0 | 1085.54 Z | 11.083 37 | -0.1439 | 1.2523 38 | 0.0204 | 1.3427 | G ← X 39 R | 62384.7 | |||
↳missing citation; missing citation; Miescher, 1976 | ||||||||||||
62504.4 40 Z | ||||||||||||
↳missing citation; missing citation; Miescher, 1976 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
L 2Πi | (62500) 41 42 | L ← X | ||||||||||
↳Dressler and Miescher, 1965; missing citation | ||||||||||||
H' 2Π 3dπ | 62485.4 43 | 2371.3 Z | 16.17 | 2.015 44 | 0.021 | 1.0585 | H,H → D 45 | 9426.0 | ||||
↳Huber, Huber, et al., 1963; missing citation | ||||||||||||
9414.2 | ||||||||||||
↳Huber, Huber, et al., 1963; missing citation | ||||||||||||
H 2Σ+ 3dσ | 62473.4 | [2339.4] Z | 2.003 44 | 0.018 | 1.0617 | H,H' → C 45 | 10348 | |||||
↳Huber, Huber, et al., 1963; Huber, 1964; missing citation | ||||||||||||
10336 | ||||||||||||
↳Huber, Huber, et al., 1963; Huber, 1964; missing citation | ||||||||||||
H,H' → A 45 | 18518.2 | |||||||||||
↳Huber, Huber, et al., 1963; missing citation | ||||||||||||
H,H' → A 45 | 18506.4 | |||||||||||
↳Huber, Huber, et al., 1963; missing citation | ||||||||||||
H,H' ← X 46 | 62598.6 | |||||||||||
↳Huber and Miescher, 1963; Miescher, 1966; missing citation | ||||||||||||
62586.8 | ||||||||||||
↳Huber and Miescher, 1963; Miescher, 1966; missing citation | ||||||||||||
62718.4 40 Z | ||||||||||||
↳Huber and Miescher, 1963; Miescher, 1966; missing citation | ||||||||||||
62706.6 40 Z | ||||||||||||
↳Huber and Miescher, 1963; Miescher, 1966; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
F 2Δ3dδ | 61800 | 2394 47 | 20 47 | 1.982 47 | 0.023 47 | 1.067 | F → C 48 45 | 9670 47 | ||||
↳Huber, 1964; missing citation | ||||||||||||
F ↔ X 46 V | 61924 | |||||||||||
↳Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
F ↔ X 46 V | 62044 49 | |||||||||||
↳Lagerqvist and Miescher, 1962; Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
E 2Σ+4sσ | 60628.8 | 2375.3 Z | 16.43 | 1.9863 50 | 0.182 | 5.6E-6 | E → D 45 51 | 7571.5 | ||||
↳Feast, 1950; Heath, 1959 | ||||||||||||
E → A 45 | 16663.63 Z | |||||||||||
↳missing citation; missing citation | ||||||||||||
E ← X 52 V | 60744.1 | |||||||||||
↳Tanaka, Seya, et al., 1951; Ueda, 1955; missing citation; Dressler and Miescher, 1965 | ||||||||||||
60863.8 40 Z | ||||||||||||
↳Tanaka, Seya, et al., 1951; Ueda, 1955; missing citation; Dressler and Miescher, 1965 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
B' 2Δi | 60364.2 53 | 1217.4 54 | 15.61 54 | 1.322 54 | 0.021 54 | 1.302 | B' → C 55 | |||||
↳Huber, 1964; missing citation | ||||||||||||
B' → B 56 52 V | 14508.6 | |||||||||||
↳Baer and Miescher, 1952; Ogawa, 1953; Ogawa and Shimauchi, 1956; Huber, 1964 | ||||||||||||
14538.7 | ||||||||||||
↳Baer and Miescher, 1952; Ogawa, 1953; Ogawa and Shimauchi, 1956; Huber, 1964 | ||||||||||||
B' ↔ X 56 57 52 R | 59900.7 | |||||||||||
↳Baer and Miescher, 1951; Baer and Miescher, 1952; Sutcliffe and Walsh, 1953; Tanaka, 1953; Ueda, 1955; missing citation; Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
60020.4 40 Z | ||||||||||||
↳Baer and Miescher, 1951; Baer and Miescher, 1952; Sutcliffe and Walsh, 1953; Tanaka, 1953; Ueda, 1955; missing citation; Dressler and Miescher, 1965; missing citation; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
D 2Σ+ 3pσ | 53084.7 | 2323.90 Z | 22.885 58 | 0.75 | 2.0026 59 | 0.02175 | [5.8E-6] | 1.0618 | D → A 60 45 | 9092.17 Z | ||
↳Feast, 1950; Huber, 1964; missing citation; missing citation | ||||||||||||
D ↔ X 60 52 61 V | 53172.7 | |||||||||||
↳missing citation; missing citation; Gero, Schmid, et al., 1944; Baer and Miescher, 1952; Tanaka, 1953; Ogawa, 1955; Deezsi and Matrai, 1957; missing citation; Lagerqvist and Miescher, 1966; missing citation; Poland and Broida, 1971 | ||||||||||||
53292.4 40 Z | ||||||||||||
↳missing citation; missing citation; Gero, Schmid, et al., 1944; Baer and Miescher, 1952; Tanaka, 1953; Ogawa, 1955; Deezsi and Matrai, 1957; missing citation; Lagerqvist and Miescher, 1966; missing citation; Poland and Broida, 1971 | ||||||||||||
C 2Πr 3pπ | 52126 62 | 2395 63 | 15 63 | 2.000 63 64 | 0.030 63 | 1.062 | C → A 64 65 | 8172 | ||||
↳Heath, 1959; missing citation; missing citation | ||||||||||||
C ↔ X 64 66 67 V | 52251 | |||||||||||
↳missing citation; Schmid, 1928; missing citation; Gaydon, 1944; Herzberg, Lagerqvist, et al., 1956; missing citation; Lagerqvist and Miescher, 1966; missing citation; Poland and Broida, 1971 | ||||||||||||
52371 | ||||||||||||
↳missing citation; Schmid, 1928; missing citation; Gaydon, 1944; Herzberg, Lagerqvist, et al., 1956; missing citation; Lagerqvist and Miescher, 1966; missing citation; Poland and Broida, 1971 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
b (4Σ-) | (48680) | 1206 68 H | 15 | b → a V | 10395 68 H | |||||||
↳missing citation; missing citation | ||||||||||||
10375 68 H | ||||||||||||
↳missing citation; missing citation | ||||||||||||
10350 68 H | ||||||||||||
↳missing citation; missing citation | ||||||||||||
10323 68 H | ||||||||||||
↳missing citation; missing citation | ||||||||||||
10300 68 H | ||||||||||||
↳missing citation; missing citation | ||||||||||||
10272 68 H | ||||||||||||
↳missing citation; missing citation | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
B 2Πr | 45942.6 69 | 1039.8 70 Z | 8.32 | 0.17 | 1.152 70 | 0.012 | 4.9E-6 | 1.4167 | B ↔ X 71 72 67 R | 45392.1 73 Z | ||
↳missing citation; missing citation; missing citation; Schmid, 1928; Sutcliffe and Walsh, 1953; missing citation; Ogawa, 1955; Ogawa and Shimauchi, 1956; Deezsi and Matrai, 1957; missing citation; missing citation; Lagerqvist and Miescher, 1962; Lagerqvist and Miescher, 1966; Engleman, Rouse, et al., 1970 | ||||||||||||
45913.6 | 1037.2 70 Z | 7.70 | 0.10 | 1.092 70 74 | 0.012 | 4.9E-6 | 1.4167 | 45481.7 73 Z | ||||
↳missing citation; missing citation; missing citation; Schmid, 1928; Sutcliffe and Walsh, 1953; missing citation; Ogawa, 1955; Ogawa and Shimauchi, 1956; Deezsi and Matrai, 1957; missing citation; missing citation; Lagerqvist and Miescher, 1962; Lagerqvist and Miescher, 1966; Engleman, Rouse, et al., 1970 | ||||||||||||
A 2Σ+ 3sσ | 43965.7 | 2374.31 Z | 10.106 75 | -0.0465 | 1.9965 76 77 78 | 0.01915 76 | 5.4E-6 | 1.06434 | A ↔ X 79 80 81 67 V | 44080.5 | ||
↳missing citation; Schmid, 1928; Gero and Schmid, 1948; Ogawa, 1955; Deezsi and Matrai, 1957; Koczkas, 1959; Engleman, Rouse, et al., 1970 | ||||||||||||
44200.2 82 Z | ||||||||||||
↳missing citation; Schmid, 1928; Gero and Schmid, 1948; Ogawa, 1955; Deezsi and Matrai, 1957; Koczkas, 1959; Engleman, Rouse, et al., 1970 | ||||||||||||
State | Te | ωe | ωexe | ωeye | Be | αe | γe | De | βe | re | Trans. | ν00 |
a (4Πi) | (38440) | 1017 H | 11 | (a → X) 83 | (38000) | |||||||
↳Broida and Peyron, 1960; Frosch and Robinson, 1964 | ||||||||||||
X 2Πr | 119.82 84 | 1904.040 Z | 14.100 85 | [1.72016] 86 | 0.0182 | [10.23E-6] 86 | 1.15077 | 3/2 ← 1/2 87 | 119.73 88 Z | |||
↳Brown, Cole, et al., 1972 | ||||||||||||
0 | 1904.204 Z | 14.075 85 | [1.67195] 86 89 | 0.0171 | [0.54E-6] 86 | 1.15077 | ||||||
↳Brown, Cole, et al., 1972 | ||||||||||||
Rotation vibration sp.: 4→2 | ||||||||||||
↳Horn and Dickey, 1964 | ||||||||||||
Rotation vibration sp.: 4←0 | ||||||||||||
↳Meyer, Haeusler, et al., 1965; Meyer and Haeusler, 1965 | ||||||||||||
Rotation vibration sp.: 3→1 | ||||||||||||
↳Horn and Dickey, 1964 | ||||||||||||
Rotation vibration sp.: 3←0 90 91 | ||||||||||||
↳Nichols, Hause, et al., 1955; Arcas, Haeusler, et al., 1963; Meyer, Haeusler, et al., 1964; Olman, McNelis, et al., 1964; Meyer, Haeusler, et al., 1965 | ||||||||||||
Rotation vibration sp.: 2←1 | ||||||||||||
↳Guerra, Sanchez, et al., 1977 | ||||||||||||
Rotation vibration sp.: 2↔0 90 91 92 | ||||||||||||
↳Nichols, Hause, et al., 1955; Horn and Dickey, 1964; Olman, McNelis, et al., 1964; Meyer, Haeusler, et al., 1965 | ||||||||||||
Rotation vibration sp.: 1↔0 90 91 92 93 94 95 96 97 | ||||||||||||
↳Shaw, 1956; Thompson and Green, 1956; missing citation; James and Thibault, 1964; Keck and Hause, 1968; Valentin, Boissy, et al., 1976; Johns, Reid, et al., 1977 | ||||||||||||
Rotation sp. 98 | ||||||||||||
↳Gallagher and Johnson, 1956; Palik and Rao, 1956; Favero, Mirri, et al., 1959; Hall and Dowling, 1966; Brown, Cole, et al., 1972 | ||||||||||||
Raman sp. 99 | ||||||||||||
↳Renschler, Hunt, et al., 1969; Shotton and Jones, 1970 | ||||||||||||
EPR sp. | ||||||||||||
↳Brown and Radford, 1966; Ashford, Jarke, et al., 1972; Jarke, Ashford, et al., 1976 | ||||||||||||
Hyperfine Λ doubl. sp. q | ||||||||||||
↳Neumann, 1970; Meerts and Dymanus, 1972; Meerts, 1976 |
Notes
1 | Excitation of a 1s0 electron to the 2π orbital. |
2 | Rydberg states converging to the nitrogen K edge at 410.2 (3Π) and 411.6 (1Π) eV, observed in X-ray absorption and electron energy loss spectra at 406.3, 407.3, 408.6 eV, ... |
3 | Tentatively interpreted as arising from two-electron excitation from the 1sN and lπ to the 2π orbital Morioka, Nakamura, et al., 1974. Only one peak (404.7 eV) is observed in the electron energy loss spectrum Wight and Brion, 1974. |
4 | Two very weak bands in the X-ray absorption spectrum at 402.3 and 403.9 eV. 3 |
5 | Strong unresolved peak in X-ray absorption and electron energy loss spectra at 399.8 eV.6 |
6 | Excitation of a 1sN electron to the 2π orbital. |
7 | Narayana and Price's absorption Rydberg series converging to c 3Π of NO+: |
8 | Photoionization yields (NO+, N+, O+) in the region of these Rydberg series Hertz, Jochims, et al., 1974, 2. |
9 | Fragments of an additional series Sasanuma, Morioka, et al., 1974. Additional cross sections 700 - 180 Å (143000 - 556000 cm-1). |
10 | The Rydberg formulae do not accurately reproduce the observed bands owing to the slow variation of the quantum defect with n. |
11 | 1π32π nsσ Rydberg series converging to a 3Σ+, w 3Δ, b 3Σ-, A 1Σ-, W 1Δ of NO+. Only the first two or three members of each absorption series have been identified; long upper state progressions. Tables of absorption features 950 - 650 Å (105000 - 154000 cm-1) Tanaka, 1942, Huber, 1961*, Metzger, Cook, et al., 1967*. Absorption coefficients, photoionization and photodissociation yields Reese and Rosenstock, 1966, Metzger, Cook, et al., 1967, Watanabe, Matsunaga, et al., 1967, Bahr, Blake, et al., 1972, Hertz, Jochims, et al., 1974. |
12 | n = 4...15. Sharp rotational structure. |
13 | Joinging on to F 2Δ(n=3), N 2Δ(n=4), U 2Δ(n=5), and incompletely observed to n=8. Perturbations by stable and unstable states. |
14 | Joining on to C 2Π, D 2Σ+(n=3), K 2Π, M 2Σ+(n=4), Q 2Π, R 2Σ+(n=5), and W 2Π, Y 2Σ+(n=6); bands of varying diffuseness have been observed to n=11. The influence of the unstable A' 2Σ+ state is briefly discussed in Miescher, 1976. |
15 | Joining on to A 2Σ+(n=3), E 2Σ+(n=4), S 2Σ+(n=5), T 2Σ+(n=6) Z 2Σ+(n=7). The Be values decrease from 1.997 (n=3) to 1.713 for the highest observed state (n=11) as a consequence of nsσ ~ (n-1)dσ interactions.28 Sharp rotational structure. |
16 | These band origins refer to N'=0 (non-existent for Λ ≠ 0) in the excited state and to the hypothetical level J"=0 of the X 2Π1/2 ground state, in accordance with definitions adopted in these tables. The corresponding numbers for the X 2Π3/2 component are obtained by subtracting 119.7 cm-1. |
17 | v=1,2,3 diffuse |
18 | See 16. |
19 | v=0 perturbed by non-Rydberg level; v=1,2,3 very diffuse |
20 | B value of the NO+ core. For details of the analysis and derived core parameters (polarizability, quadrupole moment) see Jungen and Miescher, 1969. |
21 | Energy of the Δ (or L = 2) component relative to the hypothetical level J"=0, calculated using results from the analysis of the 14N18O spectrum; see Jungen and Miescher, 1969. |
22 | Partial rot. Analyses for v=0,1 (15N18O). Perturbations by non-Rydberg levels. V=2,3,4 diffuse to varying degrees. |
23 | v=0 coincides with I(v=6) and E(v=4), strong perturbation. B1 = 1.92. |
24 | The interaction between R 2Σ+(v=0), I 2Σ+(v=5?), and the continuous A' 2Σ+ state has been observed in the spectra of four isotopes; see Figure 2.5 of Miescher and Huber, 1976. |
25 | v=1,2 diffuse |
26 | v=0,1 mixed with non-Rydberg levels, v=2,3,4 diffuse. |
27 | A slight mixing of the ground state into the ndπ components is responsible for the larger than expected spin-orbit coupling in H'(A = +0.96, ξ = +0.92) and O'(A = +0.36, ξ = +0.34); see Jungen, 1970, also Kovacs, 1963, Suter, 1969, Miescher, 1971. |
28 | Strong l-uncoupling, η(v=0) = 1.92, 3d and η(v=0) = 1.88, 4d for 3d and 4d, respectively Miescher, 1971. The magnitude of η was interpreted in terms of s~d mixing Jungen, 1970; the interaction matrix elements are 910 (4sσ ~3dσ) and 430 cm-1 (5sσ~4dσ). The non-negligible spin-orbit coupling in ndπ (see 27) gives rise to small perturbations between e levels of the 2Π F1 and F2 components Huber and Miescher, 1963, Kovacs, 1963, Suter, 1969, Miescher, 1971. Additional perturbations in H,H' by Rydberg and non-Rydberg levels Miescher, 1971. For H,H'(v=3) only Π- has been observed. The Π+ and Σ+ components of 0,0'(v=0) are weakly predissociated for all N, Π- above N=16 Suter, 1969. |
29 | Approximate deperturbed constants, see 54; v=3 at 74580 cm-1 is very diffuse Miescher, 1976. |
30 | The N→C 0-0 band is strongly mixed with B'→C 7-0; see 55. |
31 | Heterogeneous perturbations by levels of B 2Π Jungen and Miescher, 1968. Levels having v≥1 are diffuse to varying degrees. |
32 | A small perturbation by L 2Π(v=2?) affects the first few rotational levels in v=0; higher vibrational levels (v=1,2,3) are strongly mixed with non-Rydberg states (B 2Π and L 2Π). |
33 | Λ-type doubling, Δ vfe(F1) = +0.034N(N+1). |
34 | v=0...3 observed. |
35 | Deperturbed. |
36 | Five levels (v=4...8?) have been observed for various isotopes in the region 67800 - 72000 cm-1. Erratic behaviour with regard to diffuseness and isotopes shifts on account of interactions with the unstable A' 2Σ+ state and with npσ Rydberg states. See also Ben-Aryeh, 1973. |
37 | ωeye = -0.1439. The levels v=10,11,12 are diffuse and lie above the limit 2D + 3P; v=13 not observed. See also Ben-Aryeh, 1973. |
38 | Small perturbations in isotope spectra. |
39 | Absorption in rare gas matrices Roncin, Damany, et al., 1967,197, in high pressure argon Miladi, le Falher, et al., 1975. |
40 | See 16. |
41 | A ~ -80. |
42 | Fragments of several levels (vibr. Numbering not established) in perturbations with levels of B, C, K. Constants comparable to B Π. |
43 | See 27. |
44 | See 28. |
45 | For experimental and theoretical f values see Wray, 1969, Groth, Kley, et al., 1971 and Gallusser and Dressler, 1971, respectively. |
46 | Also observed by non-resonant multiphoton ionization spectroscopy Johnson, Berman, et al., 1975. |
47 | Approximate deperturbed constants; see 54. |
48 | Lines of the perturbed F→C 1-1 band are prominent in the NO laser spectrum Miescher, 1974; see 54, 55. |
49 | missing note |
50 | v=3,4 somewhat diffuse, v=5 sharp. Emission observed from v≤2; Huber, 1964 reports an abrupt breaking-off in the E→A 2-2 band for an upper state energy of 68100 cm-1. |
51 | E→C not observed, in agreement with theoretical predictions Gallusser and Dressler, 1971 regarding the dipole transition strengths of E→C and E→D. |
52 | For references to Franck-Condon factor calculations see the review by Ortenberg and Antropov, 1967. |
53 | A0= -2.2 Jungen, 1966, A1= -2.4 Jungen, 1966, ..., A9= -4.9 Jungen, 1966. |
54 | Deperturbed constants; B' 2Δ interacts strongly with F 2Δ (matrix element He~(F 2Δ) ~ 450 cm-1) and N 2Δ (He ~ 400) Felenbok and Lefebvre-Brion, 1966, Jungen, 1966; see also 57. Perturbations by B 2Π are unobservably small because of unfavorable Franck-Condon factors Field, Gottscho, et al., 1975. |
55 | Fragments of two bands, 4-1 at 9800 cm-1 and 7-0 at 15300 cm-1, both appearing on account of configuration interaction, in the upper state with F 2Δ and N 2Δ, respectively, in the lower state with B 2Π. Lines of the 4-1 band, together with F→C 1-1, are seen in the NO laser spectrum Huber, 1964, 2, Jungen, Miescher, et al., 1966, Broida and Miescher, 1973, Miescher, 1974. |
56 | Lifetime τ(v=1) = 75 ns Brzozowski, Elander, et al., 1974. |
57 | An experimentally deperturbed spectrum of B'-X is observed in matrix absorption Roncin, Damany, et al., 1967, Roncin, 1968, Boursey, 1976. A gradual deperturbation in the gas phase is induced by increasingly high foreign gas pressures Miladi, le Falher, et al., 1975. |
58 | ωeze = -0.22, v≤4 Barrow and Miescher, 1957, not including v=5 and v=6 Lagerqvist and Miescher, 1966. The vibrational constants clearly differ from those of other Rydberg 2Σ states or of the NO+ ground state. It has been suggested [see e.g. Miescher, 1971, also Ben-Aryeh, 1973] that there is an avoided crossing of the potential curves of D 2Σ+ and A' 2Σ+ (unstable, arising from 4S+3P). |
59 | From Barrow and Miescher, 1957. Heterogeneous perturbations by B 2Π; for details see Jungen and Miescher, 1968. According to Huber, 1964 the rotational structure of D→A 1-1, 2-2, 3-3 breaks off abruptly at D state energies of 59270 cm-1 in v=1,2 and 60100 cm-1 in v=3. |
60 | Lifetimes τ(v=0) = 18.4 ns Hesser, 1968, τ(v=0)= 19.0 ns Benoist D'Azy, Lopez-Delgado, et al., 1975, τ(v=0)= 25.7 ns Brzozowski, Elander, et al., 1974; τ(v=1) = 26.4 ns Brzozowski, Elander, et al., 1974. |
61 | f00 = 0.0025 Bethke, 1959, f10 = 0.0046 Bethke, 1959, f20 = 0.0033 Bethke, 1959; from integrated absorption intensities Bethke, 1959. See also Ory, 1964, Callear and Pilling, 1970. |
62 | A0 = +3.0 cm-1 Ackermann and Miescher, 1968. |
63 | Approximate deperturbed constants; strong interaction with B 2Π, see 70. Λ-type doubling, Δ vfe(F1) = +0.016N(N+l). |
64 | Weak predissociation in v=0 above N=3 or 4 [see Miescher, 1974, Dingle, Freedman, et al., 1975 and 100]. The predissociation is assumed to occur via the continuum of the a 4Π state and causes a reduction of the measured lifetimes in v=0 from 20 ns for N ~< 4 to 3 ns for N ~> 4 Benoist D'Azy, Lopez-Delgado, et al., 1975; τ(v=1) ≤ 0.3 ns. No emission has been observed from levels having v≥1. |
65 | See 45. |
66 | f00 = 0.0023 Bethke, 1959, Mandelman and Carrington, 1974, higher value in Callear and Pilling, 1970; f10 = 0.0058 Bethke, 1959, f20 = 0.0027 Bethke, 1959. See also Ory, 1964. |
67 | See 52 RKR Franck-Condon factors for the β bands Jain and Sahni, 1968, Generosa and Harris, 1970, for the γ bands Jain and Sahni, 1968, Spindler, Isaacson, et al., 1970. |
68 | A different vibrational numbering was suggested by Gilmore, 1965. |
69 | Av = +31.32 + 1.152(v+1/2) + 0.0448(v+1/2)2. The expression represents the data of Engleman, Rouse, et al., 1970 for the first seven levels. Av increases to +77 for v=25; see Lagerqvist and Miescher, 1966. |
70 | Effective constants for v ≤5 Callear and Smith, 1965. The reevaluation of the constants by Engleman, Rouse, et al., 1970, based on new measurements of the β bands and using a modified Hill-Van Vleck expression, gave G(v) = 1037.45(v+1/2) - 7.472(v+1/2)2 + 0.07253~(v+1/2)3, Bv = 1.1250 - 0.0l348(v+1/2) + 0.000125~(v+1/2)2. The highest level observed in emission is v'=7 [mixed with C(v=0)] Deezsi, 1960, Ackermann and Miescher, 1969; vibrational levels as high as v'=29 have been identified in the absorption spectrum Dressler and Miescher, 1965. They are strongly perturbed by interaction with the Rydberg states C 2Π (matrix element He(C 2Π) ~1200 cm-1) and K 2Π (He(K 2Π) ~800); see Lagerqvist and Miescher, 1958, Felenbok and Lefebvre-Brion, 1966. A complete deperturbation, taking also into account the interaction with L 2Π, was attempted by Bartholdi, Leoni, et al., 1971; more recent results by Gallusser and Dressler (ωe = 1025.0 Boursey and Roncin, 1975, ωexe = 4.52 Boursey and Roncin, 1975, ωeye = -0.0846 Boursey and Roncin, 1975) are quoted by Boursey and Roncin, 1975 who observed the deperturbed spectrum of B 2Π in matrix absorption Roncin, Damany, et al., 1967, Roncin, 1968. A similar deperturbation is induced by high pressure foreign gases Miladi, le Falher, et al., 1975. Heterogeneous interactions with levels of D 2Σ+ and M 2Σ+ are discussed by Jungen and Miescher, 1968. |
71 | Radiative lifetimes τ(v=0) = 1.99 μs Brzozowski, Elander, et al., 1974, τ(v=1)= 1.78 μs Brzozowski, Elander, et al., 1974, τ(v=4)= 1.65 μs Brzozowski, Elander, et al., 1974. Jeunehomme and Duncan, 1964 give somewhat longer lifetimes. |
72 | f00 = 2.5E-8 Hasson and Nicholls, 1971; fv'0 values increase to 4.6E-5 for v'=6 Bethke, 1959, Hasson and Nicholls, 1971, Farmer, Hasson, et al., 1972. Above v'=7 the intensities are governed by the strong interactions with the 3p and 4p Rydberg states; see 70. See also Antropov, Dronov, et al., 1964, Ory, 1964, Marr, 1964, Antropov, 1968. |
73 | Referring to the hypothetical J=0 levels in both upper and lower state. |
74 | Λ-type doubling Huber, 1964. Δ vfe(v=0)= -0.0064(J+1/2) Huber, 1964. |
75 | Engleman, Rouse, et al., 1970 |
76 | Rotational constants reevaluated from data in Barrow and Miescher, 1957 and Engleman, Rouse, et al., 1970; the equilibrium constants of the latter appear unreliable. |
77 | Spin splitting constant γ(v=3) = -0.0027650, μel(v=3)=1.10 D. These constants, as well as eqQ and magnetic hf constants, have been recalculated by Woods and Dixon, 1976 from the optical-rf double resonance experiment of Bergeman and Zare, 1974; see also Green, 1972 Walch and Goddard, 1975. Hanle effect German, Zare, et al., 1971, Gouedard, 1972, Weinstock, Zare, et al., 1972. |
78 | According to Gero and Schmid, 1948, Deezsi, 1959 the intensity of the emission bands drops sharply at N'=74,64,52,38 in v'= 0,1,2,3, respectively; bands with v'≥4 have not been observed in emission. |
79 | Radiative lifetimes τ(v=0) = 215 ns Zacharias, Halpern, et al., 1976, τ(v=1) = 203 ns Zacharias, Halpern, et al., 1976,τ(v=2) = 174 ns Zacharias, Halpern, et al., 1976; good agreement with Brzozowski, Elander, et al., 1974 except for v=2 where these authors find τ(v=2) = 195 ns Zacharias, Halpern, et al., 1976. See also Jeunehomme, 1966, Weinstock, Zare, et al., 1972, Benoist D'Azy, Lopez-Delgado, et al., 1975. |
80 | f00 = 0.00038 Weber and Penner, 1957, Bethke, 1959, Pery-Thorne and Banfield, 1970, Farmer, Hasson, et al., 1972, Hasson, Farmer, et al., 1972, f10= 0.00081 Weber and Penner, 1957, Bethke, 1959, Pery-Thorne and Banfield, 1970, Farmer, Hasson, et al., 1972, Hasson, Farmer, et al., 1972, f20= 0.00069 Weber and Penner, 1957, Bethke, 1959, Pery-Thorne and Banfield, 1970, Farmer, Hasson, et al., 1972, Hasson, Farmer, et al., 1972, f30= 0.00030 Weber and Penner, 1957, Bethke, 1959, Pery-Thorne and Banfield, 1970, Farmer, Hasson, et al., 1972, Hasson, Farmer, et al., 1972; weighted average values. Variation of transition moment with r Marr, 1964, Callear, Pilling, et al., 1966, Jeunehomme, 1966, Antropov, Kolesnikov, et al., 1967, Antropov, 1968, Jain and Sahni, 1968, Bubert, 1972; see also Poland and Broida, 1971. |
81 | Also observed in two-photon excitation Bray, Hochstrasser, et al., 1974, Bray, Hochstrasser, et al., 1975, Zacharias, Halpern, et al., 1976 and magnetic rotation spectra Robinson, 1967. 15N16O band head measurements Cisak, Danielak, et al., 1970. |
82 | see 16 . |
83 | Assignment uncertain, only observed in rare gas matrices. Predicted lifetime τ= 0.1 s Lefebvre-Brion and Guerin, 1968. See also Zarur and Chiu, 1973. |
84 | Av = +123.26 - 0.1906(v+1/2) - 0.0108(v+1/2)2; from the analysis of β and γ bands having v"≤16 Engleman, Rouse, et al., 1970. Much more precise constants for v=0 and 1 (A eff=123.1393 v=0 and A eff=122.8935 v=1, respectively) and their J dependence have been determined from measurements on the vibration-rotation fundamental and on the pure rotation spectrum Valentin, Boissy, et al., 1976, Johns, Reid, et al., 1977. See also Brown, Cole, et al., 1972, Mizushima, Evenson, et al., 1972. |
85 | ωeye = 0.0110 (2Π3/2) James and Thibault, 1964, Meyer, Haeusler, et al., 1965 and ωeye= 0.0077 (2Π1/2) James and Thibault, 1964, Meyer, Haeusler, et al., 1965; these are effective vibrational constants obtained from rotation-vibration spectra James and Thibault, 1964, Meyer, Haeusler, et al., 1965. Valentin, Boissy, et al., 1976, Johns, Reid, et al., 1977 have accurately evaluated ΔG(1/2) = 1875.972 Valentin, Boissy, et al., 1976, Johns, Reid, et al., 1977; see 84. Engleman, Rouse, et al., 1970, see 84, give the following expression, valid for v≤l6: G(v) = 1904.405(v+1/2) - 14.1870(v+1/2)2 + 0.02400(v+1/2)3 - 0.00093(v+1/2)4, v≤16. The vibrational levels have been observed to v=23 Brook and Kaplan, 1954. |
86 | Effective rotational constants from rotation Gallagher and Johnson, 1956, Favero, Mirri, et al., 1959, Hall and Dowling, 1966 and rotation-vibration spectra Hakuta and Uehara, 1975, Valentin, Boissy, et al., 1976. Precise B and D values for v=0 and 1 have been calculated by Johns, Reid, et al., 1977, see 84, B0 = 1.696115, B1 = 1.678544; D0 = 5.34E-6, D1 = 5.37E-6; good agreement with Valentin, Boissy, et al., 1976. Engleman, Rouse, et al., 1970, see 84, give the following expression for v≤l6: Bv = 1.70427 - 0.01728(v+1/2) - 0.000037(v+1/2)2 Engleman, Rouse, et al., 1970. |
87 | Observed in the electronic-rotational Raman spectrum Rasetti, 1930 Fast, Welsh, et al., 1969, Lepard, 1970, and as magnetic dipole transition in the far IR Brown, Cole, et al., 1972. Laser Zeeman spectrum Mizushima, Evenson, et al., 1972. |
88 | See 73. |
89 | Λ-type doubling, Δ vfe ~ (+)0.0117(J+1/2). Precise Λ-doubling constants have been evaluated by Meerts and Dymanus, 1972, Meerts, 1976, Valentin, Boissy, et al., 1976, Johns, Reid, et al., 1977, the variation of p and q with v agrees with the measurements of Guerra, Sanchez, et al., 1977. |
90 | Magnetic rotation Mann and Hause, 1960, Aubel and Hause, 1966, Buckingham and Segal, 1968, Keck and Hause, 1968, 2, Blum, Nill, et al., 1973. |
91 | Integrated band intensities, dipole moment function Schurin and Ellis, 1966, Michels, 1971, Chandraiah and Cho, 1973, Konkov and Vorontsov, 1973; Billingsley, 1975, Billingsley, 1976. |
92 | 2-O band of 15N18O Griggs and Rao, 1967, 1-0 band of 15N16,18O Fletcher and Begun, 1957, Griggs and Rao, 1967, Keck and Hause, 1968. |
93 | Λ-doubling, nuclear hfs, and Zeeman splittings Blum, Nill, et al., 1972, Nill, Blum, et al., 1972. 2Π3/2 laser magnetic resonance spectra Zeiger, Blum, et al., 1973, Hakuta and Uehara, 1975. |
94 | Laser Stark spectrum Hoy, Johns, et al., 1975; μel(2Π1/2,v=0) = 0.1574 D Hoy, Johns, et al., 1975 (see also 102), μel(2Π1/2,v=1) = 0.1416 D. For 2Π3/2 the difference μel(v=1) - μel(v=0) = -0.01735 D was determined. |
95 | From pressure-broadened linewidths Tejwani, Golden, et al., 1976 derive a value of Qm= 2.4E-26 esu cm2 Tejwani, Golden, et al., 1976 for the quadrupole moment of NO. Earlier results are reviewed in this paper. |
96 | Absorption spectrum of CO laser radiation by NO Richton, 1976, Hanson, Monat, et al., 1976, Garside, Ballik, et al., 1977. |
97 | Δv=1 sequence in emission Mantz, Shafer, et al., 1976. Several laser lines have been observed in the P branches of the 6-5, ..., 11-10 bands Deutsch, 1966. |
98 | Zeeman effect Mizushima, Cox, et al., 1955, Stark effect Burrus and Graybeal, 1958, both in 2Π1/2. |
99 | See also references in 87. |
100 | From the breaking-off below N'=4 in the C→A 0-0 band emitted during radiative recombination of N and 0 atoms via inverse predissociation Dingle, Freedman, et al., 1975, see also Mandelman, Carrington, et al., 1973; in good agreement with Callear and Pilling, 1970, 2. A very slightly higher value, i.e. 6.4977 ≤ D00 ≤ 6.5007 eV Miescher, 1974, is suggested Miescher, 1974 by the failure to detect F→C laser transitions ending on the lowest C level observed in the N + O recombination spectrum. |
101 | Extrapolation of selected rotational lines in the nf←X Rydberg series Miescher, 1974, 2, Miescher, 1976, based on the fine structure analysis of the 4f and 5f complexes Jungen and Miescher, 1969. |
102 | μel =0.15872 D, 2Π1/2(v=0,J=1/2) Neumann, 1970 from Stark effect; |
References
Go To: Top, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Constants of diatomic molecules, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
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Lagerqvist, A.; Miescher, E.,
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The absorption spectrum of nitric oxide in the far-ultraviolet region,
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Band spectra in the Schumann region of NO and N2+ with enriched nitrogen-15,
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Band spectra of nitric oxide in the visible and near infra-red regions,
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Ogawa and Shimauchi, 1956
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Rotational constants of B' state of nitric oxide and (vibrational and rotational constants of X2Πr and B2Πr),
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Baer and Miescher, 1951
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Ein neues Bandensystem des NO-Molekuls,
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On the emission spectra of the β-, γ- and Σ-systems of nitric oxide,
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Deezsi and Matrai, 1957
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Billingsley, F.P., II,
Multiconfiguration self-consistent-field calculation of the dipole moment function and potential curve of NO(X2Π),
J. Chem. Phys., 1975, 62, 864. [all data]
Billingsley, 1976
Billingsley, F.P., II,
Calculated vibration-rotation intensities for NO(X2Π),
J. Mol. Spectrosc., 1976, 61, 53. [all data]
Griggs and Rao, 1967
Griggs, J.L., Jr.; Rao, K.N.,
Vibration rotation bands of 15N18O,
J. Mol. Spectrosc., 1967, 22, 383. [all data]
Fletcher and Begun, 1957
Fletcher, W.H.; Begun, G.M.,
Fundamental of N15O,
J. Chem. Phys., 1957, 27, 579. [all data]
Blum, Nill, et al., 1972
Blum, F.A.; Nill, K.W.; Calawa, A.R.; Harman, T.C.,
Observation of nuclear hyperfine splitting in the infrared vibration-rotation absorption spectrum of the NO molecule,
Chem. Phys. Lett., 1972, 15, 144. [all data]
Nill, Blum, et al., 1972
Nill, K.W.; Blum, F.A.; Calawa, A.R.; Harman, T.C.,
Observation of Λ-doubling and Zeeman splitting in the fundamental infrared absorption band of nitric oxide,
Chem. Phys. Lett., 1972, 14, 234. [all data]
Zeiger, Blum, et al., 1973
Zeiger, H.J.; Blum, F.A.; Nill, K.W.,
Observation of strong nonlinearities in the high field Zeeman spectrum of NO at 1876 cm-1,
J. Chem. Phys., 1973, 59, 3968. [all data]
Hoy, Johns, et al., 1975
Hoy, A.R.; Johns, J.W.C.; McKellar, A.R.W.,
Stark spectroscopy with the CO laser: dipole moments, hyperfine structure, and level crossing effects in the fundamental band of NO,
Can. J. Phys., 1975, 53, 2029. [all data]
Tejwani, Golden, et al., 1976
Tejwani, G.D.T.; Golden, B.M.; Yeung, E.S.,
Pressure-broadened linewidths of nitric oxide,
J. Chem. Phys., 1976, 65, 5110. [all data]
Richton, 1976
Richton, R.E.,
NO line parameters measured by CO laser transmittance,
Appl. Opt., 1976, 15, 1686. [all data]
Hanson, Monat, et al., 1976
Hanson, R.K.; Monat, J.P.; Kruger, C.H.,
Absorption of CO laser radiation by NO,
J. Quant. Spectrosc. Radiat. Transfer, 1976, 16, 705. [all data]
Garside, Ballik, et al., 1977
Garside, B.K.; Ballik, E.A.; Elsherbiny, M.; Shewchun, J.,
Resonance absorption measurements of NO with a line-tunable CO laser: spectroscopic data for pollution monitoring,
Appl. Opt., 1977, 16, 398. [all data]
Mantz, Shafer, et al., 1976
Mantz, A.W.; Shafer, S.A.; Rao, K.N.,
Emission spectrum of nitric oxide between 5 μm and 7 μm,
Appl. Opt., 1976, 15, 599. [all data]
Deutsch, 1966
Deutsch, T.F.,
No molecular laser,
Appl. Phys. Lett., 1966, 9, 295. [all data]
Mizushima, Cox, et al., 1955
Mizushima, M.; Cox, J.T.; Gordy, W.,
Zeeman effect in the rotational spectrum of NO,
Phys. Rev., 1955, 98, 1034. [all data]
Burrus and Graybeal, 1958
Burrus, C.A.; Graybeal, J.D.,
Stark effect at 2.0 and 1.2 millimeters wavelength: nitric oxide,
Phys. Rev., 1958, 109, 1553. [all data]
Mandelman, Carrington, et al., 1973
Mandelman, M.; Carrington, T.; Young, R.A.,
Predissociation and its inverse, using resonance absorption NO(C2Π) = N + O,
J. Chem. Phys., 1973, 58, 84. [all data]
Callear and Pilling, 1970, 2
Callear, A.B.; Pilling, M.J.,
Fluorescence of nitric oxide. Part 7. Quenching rates of NO C2Π(v = O), its rate of radiation to NO A2Σ+, energy transfer efficiencies, and mechanisms of predissociation,
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Miescher, 1974, 2
Miescher, E.,
The Rydberg series of the NO molecule converging to the first ionization limit 1340 Å
in Vacuum ultraviolet radiation physics, Koch, Haensel, Kunz, ed(s)., Pergamon-Veiweg, Braunschweig, 1974, 61-63. [all data]
Notes
Go To: Top, Henry's Law data, Gas phase ion energetics data, Ion clustering data, IR Spectrum, Mass spectrum (electron ionization), Constants of diatomic molecules, References
- Symbols used in this document:
AE Appearance energy IE (evaluated) Recommended ionization energy T Temperature d(ln(kH))/d(1/T) Temperature dependence parameter for Henry's Law constant k°H Henry's Law constant at 298.15K ΔrG° Free energy of reaction at standard conditions ΔrH° Enthalpy of reaction at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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