bromine chloride

• Formula: BrCl
• Molecular weight: 115.357
• IUPAC Standard InChI: InChI=1S/BrCl/c1-2 Copy

  
• IUPAC Standard InChIKey: CODNYICXDISAEA-UHFFFAOYSA-N Copy
• CAS Registry Number: 13863-41-7
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Bromine monochloride
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Henry's Law data
  • Gas phase ion energetics data
  • Ion clustering data
  • Constants of diatomic molecules
  • References
  • Notes
• Other data available:
  • Gas phase thermochemistry data
  • Reaction thermochemistry data
• Data at other public NIST sites:
  • Microwave spectra (on physics lab web site)
  • Gas Phase Kinetics Database
• Options:
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Henry's Law data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Rolf Sander

Henry's Law constant (water solution)

k_H(T) = k°_H exp(d(ln(k_H))/d(1/T) ((1/T) - 1/(298.15 K)))
k°_H = Henry's law constant for solubility in water at 298.15 K (mol/(kg*bar))
d(ln(k_H))/d(1/T) = Temperature dependence constant (K)

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LBLHLM - Sharon G. Lias, John E. Bartmess, Joel F. Liebman, John L. Holmes, Rhoda D. Levin, and W. Gary Mallard
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Ion clustering data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Note: Please consider using the reaction search for this species. This page allows searching of all reactions involving this species. Searches may be limited to ion clustering reactions. A general reaction search form is also available.

Clustering reactions

BrCl₂^- +  = (BrCl₂^- • )

By formula: BrCl₂^- + BrCl = (BrCl₂^- • BrCl)

Constants of diatomic molecules

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Klaus P. Huber and Gerhard H. Herzberg

Data collected through June, 1976

Notes

References

Go To: Top, Henry's Law data, Gas phase ion energetics data, Ion clustering data, Constants of diatomic molecules, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Irsa and Friedman, 1958
Irsa, A.P.; Friedman, L., Mass spectra of halogen fluorides, J. Inorg. Nucl. Chem., 1958, 6, 77. [all data]

Dyke, Josland, et al., 1984
Dyke, J.M.; Josland, G.D.; Snijders, J.G.; Boerrigter, P.M., Ionization energies of the diatomic halogens and interhalogens studied with relativistic hartree-fock-slater calculations, Chem. Phys., 1984, 91, 419. [all data]

Lee, Smith, et al., 1979
Lee, L.C.; Smith, G.P.; Moseley, J.T.; Cosby, P.C.; Guest, J.A., Photodissociation and photodetachment of Cl₂-, ClO-, Cl₃-, and BrCl₂-, J. Chem. Phys., 1979, 70, 3237. [all data]

Check, Faust, et al., 2001
Check, C.E.; Faust, T.O.; Bailey, J.M.; Wright, B.J.; Gilbert, T.M.; Sunderlin, L.S., Addition of Polarization and Diffuse Functions to the LANL2DZ Basis Set for P-Block Elements, J. Phys. Chem. A,, 2001, 105, 34, 8111, https://doi.org/10.1021/jp011945l . [all data]

Haranath and Rao, 1957
Haranath, P.B.V.; Rao, P.T., Emission spectra of mixed halogens. Part II: IBr and BrCl, Indian J. Phys., 1957, 31, 368. [all data]

Coxon, 1974
Coxon, J.A., Rotational vibrational analysis of the B³Π(O⁺)-X¹Σ⁺ band system of ⁷⁹Br³⁵Cl and ⁸¹Br³⁵Cl, J. Mol. Spectrosc., 1974, 50, 142. [all data]

Hadley, Bina, et al., 1974
Hadley, S.G.; Bina, M.J.; Brabson, G.D., The a³Π_O⁺ → X¹Σ⁺ system of bromine chloride, J. Phys. Chem., 1974, 78, 1833. [all data]

Wight, Ault, et al., 1975
Wight, C.A.; Ault, B.S.; Andrews, L., Laser-induced fluorescence and resonance Raman spectra of interhalogen diatomics isolated in inert matrices at 12 K, J. Mol. Spectrosc., 1975, 56, 239. [all data]

Mattraw, Pachucki, et al., 1954
Mattraw, H.C.; Pachucki, C.F.; Hawkins, N.J., Equilibrium constant, infrared spectrum, and thermodynamic properties of bromine chloride, J. Chem. Phys., 1954, 22, 1117. [all data]

Brooks and Crawford, 1955
Brooks, W.V.F.; Crawford, B., Jr., Vibrational intensities. V. BrCl and ICl, J. Chem. Phys., 1955, 23, 363. [all data]

Clyne and Coxon, 1967
Clyne, M.A.A.; Coxon, J.A., The formation and detection of some low-lying excited electronic states of BrCl and other halogens, Proc. R. Soc. London A, 1967, 298, 424. [all data]

Holzer, Murphy, et al., 1970
Holzer, W.; Murphy, W.F.; Bernstein, H.J., Resonance Raman effect and resonance fluoroscence in halogen gases, J. Chem. Phys., 1970, 52, 399. [all data]

Smith, Tidwell, et al., 1950
Smith, D.F.; Tidwell, M.; Williams, D.V.P., The microwave spectrum of BrCl, Phys. Rev., 1950, 79, 1007. [all data]

Wallart, 1972
Wallart, F., Study of vibrational hot bands by Raman spectroscopy - application to chlorine and bromine chloride, Can. J. Spectrosc., 1972, 17, 128. [all data]

Stull and Prophet, 1971
Stull, D.R.; Prophet, H., JANAF Thermochemical Tables. Second Edition, Office of SRD (NSRDS-NBS 37), Washington, D.C., 1971, 0. [all data]

Notes

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• Symbols used in this document:
  

  d(ln(kH))/d(1/T)	Temperature dependence parameter for Henry's Law constant
  k°H	Henry's Law constant at 298.15K
  ΔrG°	Free energy of reaction at standard conditions
  ΔrH°	Enthalpy of reaction at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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