PhN radical

• Formula: C₆H₅N
• Molecular weight: 91.1106
• CAS Registry Number: 2655-25-6
• Information on this page:
  • Gas phase ion energetics data
  • Vibrational and/or electronic energy levels
  • References
  • Notes
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Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   ?

State:   ?

State:   a

State:   X

Additional references: Jacox, 1994, page 442; Jacox, 1998, page 370

Notes

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Drzaic and Brauman, 1984
Drzaic, P.S.; Brauman, J.I., A determination of the singlet-triplet splitting in phenylnitrene via photoelectron detachment, J. Am. Chem. Soc., 1984, 106, 3443. [all data]

Mcdonald and Davidson, 1993
Mcdonald, R.N.; Davidson, S.J., Electron Photodetachment of the Phenylnitrene Anion Radical - EA, ΔH(degrees(f), and the Singlet Triplet Splitting for Phenylnitrene, J. Chem. Soc. Chem. Comm., 1993, 115, 23, 10857, https://doi.org/10.1021/ja00076a049 . [all data]

Travers, Cowles, et al., 1992
Travers, M.J.; Cowles, D.C.; Clifford, E.P.; Ellison, G.B., Photoelectron Spectroscopy of the Phenylnitrene Anion, J. Am. Chem. Soc., 1992, 114, 22, 8699, https://doi.org/10.1021/ja00048a053 . [all data]

Wijeratne, Da Fonte, et al., 2009
Wijeratne, N.R.; Da Fonte, M.; Ronenius, A.; Wyss, P.J.; Tahmassebi, D.; Wenthold, P.G., Photoelectron Spectroscopy of Chloro-Substituted Phenylnitrene Anions, J. Phys. Chem. A, 2009, 113, 34, 9467-9473, https://doi.org/10.1021/jp9039594 . [all data]

Hayes and Sheridan, 1990
Hayes, J.C.; Sheridan, R.S., The IR spectrum of triplet phenylnitrene. On the origin of didehydroazepine in low temperature matrices, J. Am. Chem. Soc., 1990, 112, 15, 5879, https://doi.org/10.1021/ja00171a038 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Notes

Go To: Top, Gas phase ion energetics data, Vibrational and/or electronic energy levels, References

• Symbols used in this document:
  

  EA	Electron affinity

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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