Iron, tris(1,3-diphenyl-1,3-propanedionato-O,O')-, (OC-6-11)-
- Formula: C45H33FeO6
- Molecular weight: 725.585
- IUPAC Standard InChIKey: JWPHPBLJVLHKOZ-VPWWGWCISA-K
- CAS Registry Number: 14405-49-3
- Chemical structure:
This structure is also available as a 2d Mol file - Other names: Iron, tris(1,3-diphenyl-1,3-propanedionato)-; Iron, tris(dibenzoylmethanato)-; Tris(dibenzoylmethanato)iron; Iron(III) 1,3-diphenyl-1,3-dipropanedionate; Iron, tris-1,3-diphenyl-1,3-propanedionato-O,O')-
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Phase change data
Go To: Top, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: William E. Acree, Jr., James S. Chickos
Quantity | Value | Units | Method | Reference | Comment |
---|---|---|---|---|---|
ΔsubH° | 49.7 ± 0.48 | kcal/mol | N/A | Bardi, Brunetti, et al., 1996 | |
ΔsubH° | 50. ± 1. | kcal/mol | N/A | Bardi, Brunetti, et al., 1996 | See also MacLaren and Gregory, 1955. |
Enthalpy of sublimation
ΔsubH (kcal/mol) | Temperature (K) | Method | Reference | Comment |
---|---|---|---|---|
47. ± 2. | 700. | TE | Bardi, Brunetti, et al., 1996 | Based on data from 680. to 720. K. See also Sime and Gregory, 1960. |
47.1 ± 0.5 | 817. | GS | Bardi, Brunetti, et al., 1996 | Based on data from 673. to 962. K. See also MacLaren and Gregory, 1955. |
47.1 ± 1. | 670. | ME | Bardi, Brunetti, et al., 1996 | Based on data from 623. to 718. K. See also MacLaren and Gregory, 1955. |
Gas phase ion energetics data
Go To: Top, Phase change data, Mass spectrum (electron ionization), UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Sharon G. Lias and Joel F. Liebman
Ionization energy determinations
IE (eV) | Method | Reference | Comment |
---|---|---|---|
9.7 | PE | Shcheka and Vovna, 1992 | Vertical value |
Mass spectrum (electron ionization)
Go To: Top, Phase change data, Gas phase ion energetics data, UV/Visible spectrum, References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director
Spectrum
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Additional Data
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Due to licensing restrictions, this spectrum cannot be downloaded.
Owner | NIST Mass Spectrometry Data Center Collection (C) 2014 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
---|---|
NIST MS number | 18691 |
UV/Visible spectrum
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Spectrum
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Additional Data
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Source | Lang (editor), 1967 |
---|---|
Owner | INEP CP RAS, NIST OSRD Collection (C) 2007 copyright by the U.S. Secretary of Commerce on behalf of the United States of America. All rights reserved. |
Origin | INSTITUTE OF ENERGY PROBLEMS OF CHEMICAL PHYSICS, RAS |
Source reference | RAS UV No. 19158 |
Instrument | Cary II M |
Melting point | 275-276 |
References
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Bardi, Brunetti, et al., 1996
Bardi, Gianpiero; Brunetti, Bruno; Piacente, Vincenzo,
Vapor Pressure and Standard Enthalpies of Sublimation of Iron Difluoride, Iron Dichloride, and Iron Dibromide,
J. Chem. Eng. Data, 1996, 41, 1, 14-20, https://doi.org/10.1021/je950115w
. [all data]
MacLaren and Gregory, 1955
MacLaren, R.O.; Gregory, N.W.,
The Vapor Pressure of Iron(II) Bromide,
J. Phys. Chem., 1955, 59, 2, 184-186, https://doi.org/10.1021/j150524a022
. [all data]
Sime and Gregory, 1960
Sime, R.J.; Gregory, N.W.,
VAPOR PRESSURES OF FeCl 2 , FeBr 2 AND FeI 2 BY THE TORSION EFFUSION METHOD,
J. Phys. Chem., 1960, 64, 1, 86-89, https://doi.org/10.1021/j100830a021
. [all data]
Shcheka and Vovna, 1992
Shcheka, O.L.; Vovna, V.I.,
Electronic structure of some copper(II) and iron(III) -diketonates,
J. Electron Spectrosc. Relat. Phenom., 1992, 60, 211. [all data]
Lang (editor), 1967
Lang (editor), L.,
Absorption Spectra in the Ultraviolet and Visible Region, 1967, 9, 123. [all data]
Notes
Go To: Top, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), UV/Visible spectrum, References
- Symbols used in this document:
ΔsubH Enthalpy of sublimation ΔsubH° Enthalpy of sublimation at standard conditions - Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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