CaSH

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   C
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 16075.13 gas C-X 597 647 Fernando, Ram, et al., 1991
Sheridan, Dick, et al., 2006
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 CaS stretch 312 gas LF Fernando, Ram, et al., 1991

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15859.46 gas B-X 607 659 Fernando, Ram, et al., 1991
Scurlock, Henderson, et al., 1994
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 CaS stretch 320 gas LF Fernando, Ram, et al., 1991

State:   A
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 15380.29 gas A-X 626 679 Fernando, Ram, et al., 1991
Jarman and Bernath, 1993
Sheridan, Dick, et al., 2006
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 CaS stretch 318 gas LF Fernando, Ram, et al., 1991

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 3 CaS stretch 326 gas LF Fernando, Ram, et al., 1991

Additional references: Jacox, 1994, page 28; Jacox, 1998, page 140; Taleb-Bendiab, Scappini, et al., 1996

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Fernando, Ram, et al., 1991
Fernando, W.T.M.L.; Ram, R.S.; O'Brien, L.C.; Bernath, P.F., Gas-phase inorganic chemistry: laser spectroscopy of calcium and strontium monothiolates and monohydrosulfides, J. Phys. Chem., 1991, 95, 7, 2665, https://doi.org/10.1021/j100160a009 . [all data]

Sheridan, Dick, et al., 2006
Sheridan, P.M.; Dick, M.J.; Wang, J.-G.; Bernath, P.F., High-resolution investigation of the excited electronic states of CaSH and SrSH by laser excitation spectroscopy -- ARTICLE WITHDRAWN, Mol. Phys., 2006, 104, 20-21, 3245, https://doi.org/10.1080/00268970601075253 . [all data]

Scurlock, Henderson, et al., 1994
Scurlock, C.T.; Henderson, T.; Bosely, S.; Jung, K.Y.; Steimle, T.C., Molecular beam optical Stark spectroscopy of CaSH, J. Chem. Phys., 1994, 100, 8, 5481, https://doi.org/10.1063/1.467166 . [all data]

Jarman and Bernath, 1993
Jarman, C.N.; Bernath, P.F., A high-resolution analysis of the A 2A'--X 2A' transition of CaSH by laser excitation spectroscopy, J. Chem. Phys., 1993, 98, 9, 6697, https://doi.org/10.1063/1.464762 . [all data]

Jacox, 1994
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules, American Chemical Society, Washington, DC, 1994, 464. [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Taleb-Bendiab, Scappini, et al., 1996
Taleb-Bendiab, A.; Scappini, F.; Amano, T.; Watson, J.K.G., Millimeter-wave spectra of CaSH and CaSD, J. Chem. Phys., 1996, 104, 19, 7431, https://doi.org/10.1063/1.471458 . [all data]

Notes

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