C13

Gas phase ion energetics data

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: John E. Bartmess

Electron affinity determinations

EA (eV) Method Reference Comment
3.6000 ± 0.0043LPESAchiba, Kohno, et al., 2005EA=Vertical Detachment Energy. Ring Structure likely.
3.60 ± 0.10LPESYang, Taylor, et al., 1989EA given is Vertical Detachment Energy. probably ring structure
4.19999LPESKohno, Suzuki, et al., 1998Vertical Detachment Energy, linear isomer

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   1Su+
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 26341 ± 15 Ne 1Su+-X 370 380 Forney, Freivogel, et al., 1996
To = 24969 Ar Szczepanski, Fuller, et al., 2001
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
669 ± 20 Ne AB Forney, Freivogel, et al., 1996
424 ± 20 Ne AB Forney, Freivogel, et al., 1996
207 ± 20 Ne AB Forney, Freivogel, et al., 1996

State:   ?
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 18761 ± 7 Ne Forney, Freivogel, et al., 1996
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σg+ 1 2409 ± 10 Ne AB Forney, Freivogel, et al., 1996
2 2258 ± 10 Ne AB Forney, Freivogel, et al., 1996
6 307 ± 10 Ne AB Forney, Freivogel, et al., 1996

State:   a
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
Txx = 7750 ± 80 gas Kohno, Suzuki, et al., 1999

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
Σu+ 1808.96 gas DL Giesen, Van Orden, et al., 1994

Additional references: Jacox, 1998, page 356; Jacox, 2003, page 381

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.
xxEnergy separation between the band maxima of both the excited state and the ground state of a molecular cation, derived from a photoelectron spectrum.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Achiba, Kohno, et al., 2005
Achiba, Y.; Kohno, M.; Ohara, M.; Suzuki, S.; Shiromaru, H., Electron detachment spectroscopic study on carbon and silicon cluster anions, J. Electron Spectros. Rel. Phenom., 2005, 142, 3, 231-240, https://doi.org/10.1016/j.elspec.2004.09.016 . [all data]

Yang, Taylor, et al., 1989
Yang, S.; Taylor, K.J.; Craycraft, M.J.; Conceicao, J.; Pettiette, C.L.; Cherhnovsky, O.; Smalley, R.E., UPS of 2-30 Atom Carbon Clusters: Chains and Rings, Chem. Phys. Lett., 1989, 144, 5-6, 431, https://doi.org/10.1016/0009-2614(88)87291-9 . [all data]

Kohno, Suzuki, et al., 1998
Kohno, M.; Suzuki, S.; Shiromaru, H.; Moriwaki, T.; Achiba, Y., Ultraviolet Photoelectron Spectroscopy on the Linear Conformer of Negatively Charged Carbon Clusters Cn- (1- =n=16), Chem. Phys. Lett., 1998, 282, 3-4, 330, https://doi.org/10.1016/S0009-2614(97)01273-6 . [all data]

Forney, Freivogel, et al., 1996
Forney, D.; Freivogel, P.; Grutter, M.; Maier, J.P., Electronic absorption spectra of linear carbon chains in neon matrices. IV. C2n+1 n=2--7, J. Chem. Phys., 1996, 104, 13, 4954, https://doi.org/10.1063/1.471127 . [all data]

Szczepanski, Fuller, et al., 2001
Szczepanski, J.; Fuller, J.; Ekern, S.; Vala, M., Electronic absorption and resonance Raman spectra of large linear carbon clusters isolated in solid argon, Spectrochim. Acta A, 2001, 57, 4, 775, https://doi.org/10.1016/S1386-1425(00)00443-1 . [all data]

Kohno, Suzuki, et al., 1999
Kohno, M.; Suzuki, S.; Shiromaru, H.; Achiba, Y., Characterization of the lowest triplet states of linear form C[sub 2n+1] by anion photoelectron spectroscopy, J. Chem. Phys., 1999, 110, 8, 3781, https://doi.org/10.1063/1.478269 . [all data]

Giesen, Van Orden, et al., 1994
Giesen, T.F.; Van Orden, A.; Hwang, H.J.; Fellers, R.S.; Provencal, R.A.; Saykally, R.J., Infrared laser spectroscopy of the linear C13 carbon cluster, Science, 1994, 265, 5173, 756, https://doi.org/10.1126/science.11539187 . [all data]

Jacox, 1998
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement A, J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017 . [all data]

Jacox, 2003
Jacox, M.E., Vibrational and electronic energy levels of polyatomic transient molecules: supplement B, J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629 . [all data]

Notes

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