F2PS

Vibrational and/or electronic energy levels

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: Marilyn E. Jacox

State:   B
 Energy 
 (cm-1) 		  Med.   Transition   λmin 
 (nm) 		  λmax 
 (nm) 		  References
To = 13115.7 gas B-X 530 770 Yang, Clouthier, et al., 2009
Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PF2 s-stretch 859.9 gas LF Yang, Clouthier, et al., 2009
2 PS stretch 646.5 gas LF Yang, Clouthier, et al., 2009
3 PF2 scissor 401.3 gas LF Yang, Clouthier, et al., 2009
4 FPF wag 300.1 gas LF Yang, Clouthier, et al., 2009

State:   X

Vib. 
sym. 		  No.   Approximate 
 type of mode 		  cm-1   Med.   Method   References
a' 1 PF2 s-stretch 886 gas LF Yang, Clouthier, et al., 2009
2 PS stretch 608 gas LF Yang, Clouthier, et al., 2009
3 PF2 scissor 387 gas LF Yang, Clouthier, et al., 2009
4 FPF wag 314 gas LF Yang, Clouthier, et al., 2009

Notes

oEnergy separation between the v = 0 levels of the excited and electronic ground states.

References

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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Yang, Clouthier, et al., 2009
Yang, J.; Clouthier, D.J.; Tarroni, R., Heavy atom nitroxyl radicals. IV. Experimental and theoretical studies of the F[sub 2]P=S free radical in the gas phase, J. Chem. Phys., 2009, 131, 22, 224311, https://doi.org/10.1063/1.3270160 . [all data]

Notes

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