SF6+
- Formula: F6S+
- Molecular weight: 146.055
- CAS Registry Number: 12507-38-9
- Information on this page:
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Vibrational and/or electronic energy levels
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Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Data compiled by: Marilyn E. Jacox
State: F
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 94450 ± 100 | gas | Potts, Lempka, et al., 1970 | |||||
Karlsson, Mattsson, et al., 1976 | |||||||
Holland, MacDonald, et al., 1995 | |||||||
Yencha, Thompson, et al., 1997 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
a1 | 1 | Sym. stretch | 690 ± 40 | gas | PE | Holland, MacDonald, et al., 1995 Yencha, Thompson, et al., 1997 | |
eg | 2 | 460 | T | gas | PE TPE | Holland, MacDonald, et al., 1995 Yencha, Thompson, et al., 1997 | |
State: E
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 57620 ± 100 | gas | Potts, Lempka, et al., 1970 | |||||
Karlsson, Mattsson, et al., 1976 | |||||||
Holland, MacDonald, et al., 1995 | |||||||
Yencha, Thompson, et al., 1997 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
ag | 1 | Sym. stretch | 540 ± 40 | gas | PE TPE | Holland, MacDonald, et al., 1995 Yencha, Thompson, et al., 1997 | |
State: D
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 33250 ± 150 | gas | Frost, McDowell, et al., 1967 | |||||
Potts, Lempka, et al., 1970 | |||||||
Karlsson, Mattsson, et al., 1976 | |||||||
Holland, MacDonald, et al., 1995 | |||||||
Yencha, Thompson, et al., 1997 | |||||||
Vib. sym. |
No. | Approximate type of mode |
cm-1 | Med. | Method | References | |
---|---|---|---|---|---|---|---|
ag | 1 | Sym. stretch | 590 ± 40 | gas | PE TPE | Karlsson, Mattsson, et al., 1976 Holland, MacDonald, et al., 1995 Yencha, Thompson, et al., 1997 | |
State: C
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 24360 ± 100 | U | gas | Frost, McDowell, et al., 1967 | ||||
Potts, Lempka, et al., 1970 | |||||||
Karlsson, Mattsson, et al., 1976 | |||||||
Holland, MacDonald, et al., 1995 | |||||||
Yencha, Thompson, et al., 1997 | |||||||
Yang, Agren, et al., 1998 | |||||||
State: A,B
Energy (cm-1) |
Med. | Transition | λmin (nm) |
λmax (nm) |
References | ||
---|---|---|---|---|---|---|---|
To = 12780 ± 240 | gas | Frost, McDowell, et al., 1967 | |||||
Potts, Lempka, et al., 1970 | |||||||
Karlsson, Mattsson, et al., 1976 | |||||||
Holland, MacDonald, et al., 1995 | |||||||
Yencha, Thompson, et al., 1997 | |||||||
Yang, Agren, et al., 1998 | |||||||
Additional references: Jacox, 1998, page 331; Jacox, 2003, page 347; Creasey, Lambert, et al., 1991; Creasey, Jones, et al., 1993
Notes
U | Upper bound |
T | Tentative assignment or approximate value |
o | Energy separation between the v = 0 levels of the excited and electronic ground states. |
References
Go To: Top, Vibrational and/or electronic energy levels, Notes
Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.
Potts, Lempka, et al., 1970
Potts, A.W.; Lempka, H.J.; Streets, D.G.; Price, W.C.,
Photoelectron spectra of the halides of elements in groups III, IV, V and VI,
Phil. Trans. Roy. Soc. (London), 1970, A268, 59. [all data]
Karlsson, Mattsson, et al., 1976
Karlsson, L.; Mattsson, L.; Jadrny, R.; Bergmark, T.; Siegbahn, K.,
Valence Electron Spectra of Benzene and the Hexafluorides of Sulphur, Molybdenum, Tungsten and Uranium.,
Phys. Scripta, 1976, 14, 5, 230, https://doi.org/10.1088/0031-8949/14/5/007
. [all data]
Holland, MacDonald, et al., 1995
Holland, D.M.P.; MacDonald, M.A.; Baltzer, P.; Karlsson, L.; Lundqvist, M.; Wannberg, B.; von Niessen, W.,
An experimental and theoretical study of the valence shell photoelectron spectrum of sulphur hexafluoride,
Chem. Phys., 1995, 192, 3, 333, https://doi.org/10.1016/0301-0104(94)00381-J
. [all data]
Yencha, Thompson, et al., 1997
Yencha, A.J.; Thompson, D.B.; Cormack, A.J.; Cooper, D.R.; Zubek, M.; Bolognesi, P.; King, G.C.,
Threshold photoelectron spectroscopy of SF6,
Chem. Phys., 1997, 216, 1-2, 227, https://doi.org/10.1016/S0301-0104(96)00372-2
. [all data]
Frost, McDowell, et al., 1967
Frost, D.C.; McDowell, C.A.; Sandhu, J.S.; Vroom, D.A.,
Photoelectron spectrum of sulfur hexafluoride at 584 A,
J. Chem. Phys., 1967, 46, 2008. [all data]
Yang, Agren, et al., 1998
Yang, L.; Agren, H.; Carravetta, V.; Vahtras, O.; Karlsson, L.; Wannberg, B., et al.,
Energy-dependent valence photoelectron spectra of SF6. Ab initio calculations and measurements,
J. Electron Spectrosc. Relat. Phenom., 1998, 94, 1-2, 163, https://doi.org/10.1016/S0368-2048(98)00085-1
. [all data]
Jacox, 1998
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement A,
J. Phys. Chem. Ref. Data, 1998, 27, 2, 115-393, https://doi.org/10.1063/1.556017
. [all data]
Jacox, 2003
Jacox, M.E.,
Vibrational and electronic energy levels of polyatomic transient molecules: supplement B,
J. Phys. Chem. Ref. Data, 2003, 32, 1, 1-441, https://doi.org/10.1063/1.1497629
. [all data]
Creasey, Lambert, et al., 1991
Creasey, J.C.; Lambert, I.R.; Tuckett, R.P.; Codling, K.; Fransinski, L.J.; Hatherly, P.A.; Stankiewicz, M.,
J. Chem. Soc., 1991, Faraday Trans. 87, 1287. [all data]
Creasey, Jones, et al., 1993
Creasey, J.C.; Jones, H.M.; Smith, D.M.; Tuckett, R.P.; Hatherly, P.A.; Codling, K.; Powis, I.,
Fragmentation of valence electronic states of CF+4 and SF+6 studied by threshold photoelectron-photoion coincidence spectroscopy,
Chem. Phys., 1993, 174, 3, 441, https://doi.org/10.1016/0301-0104(93)80010-7
. [all data]
Notes
Go To: Top, Vibrational and/or electronic energy levels, References
- Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
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