Aluminum tris(acetylacetonate)

• Formula: C₁₅H₂₁AlO₆
• Molecular weight: 324.3052
• IUPAC Standard InChI: InChI=1S/3C5H8O2.Al/c3*1-4(6)3-5(2)7;/h3*3,6H,1-2H3;/q;;;+3/p-3/b3*4-3-; Copy

  
• IUPAC Standard InChIKey: KILURZWTCGSYRE-LNTINUHCSA-K Copy
• CAS Registry Number: 13963-57-0
• Chemical structure:
  This structure is also available as a 2d Mol file or as a computed 3d SD file
  The 3d structure may be viewed using Java or Javascript.
• Other names: Tris(2,4-pentanedionato)aluminum; Aluminum, tris(2,4-pentanedionato-O,O')-, (OC-6-11)-; Aluminum, tris(2,4-pentanedionato)-; Aluminum acetylacetonate; Aluminum(III) acetylacetonate; Tris(acetylacetonato)aluminum; Tris(acetylacetone)aluminum; Tris(acetylacetonyl)aluminum; tris(pentane-2,4-dionato)aluminum; Aluminum 2,4-pentanedionate; Aluminum triacetylacetonate; Tris(acetylacetonato) aluminium; Tris(acetylacetonato) aluminium(III); Aluminum, tris(2,4-pentanedionato-κO,κO')-, (OC-6-11)-; Aluminum, tris(2,4-pentanedionato-κO2,κO4)-, (OC-6-11)-; NSC 4650; Tris(2,4-pentanedione)aluminum; Aluminum Chelate A; aluminium tris(2,4-pentanedionato-O,O')
• Permanent link for this species. Use this link for bookmarking this species for future reference.
• Information on this page:
  • Gas phase thermochemistry data
  • Condensed phase thermochemistry data
  • Phase change data
  • Gas phase ion energetics data
  • Mass spectrum (electron ionization)
  • References
  • Notes
• Data at other public NIST sites:
  • X-ray Photoelectron Spectroscopy Database, version 5.0
• Options:
  • Switch to calorie-based units

Data at NIST subscription sites:

• NIST / TRC Web Thermo Tables, professional edition (thermophysical and thermochemical data)

NIST subscription sites provide data under the NIST Standard Reference Data Program, but require an annual fee to access. The purpose of the fee is to recover costs associated with the development of data collections included in such sites. Your institution may already be a subscriber. Follow the links above to find out more about the data in these sites and their terms of usage.

Gas phase thermochemistry data

Go To: Top, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: José A. Martinho Simões

Condensed phase thermochemistry data

Go To: Top, Gas phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Constant pressure heat capacity of solid

Phase change data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Gas phase ion energetics data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
TRC - Thermodynamics Research Center, NIST Boulder Laboratories, Chris Muzny director
AC - William E. Acree, Jr., James S. Chickos
MS - José A. Martinho Simões
DH - Eugene S. Domalski and Elizabeth D. Hearing

Enthalpy of sublimation

Enthalpy of fusion

Entropy of fusion

Gas phase ion energetics data

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Mass spectrum (electron ionization), References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled as indicated in comments:
LL - Sharon G. Lias and Joel F. Liebman
LLK - Sharon G. Lias, Rhoda D. Levin, and Sherif A. Kafafi
RDSH - Henry M. Rosenstock, Keith Draxl, Bruce W. Steiner, and John T. Herron

Ionization energy determinations

Appearance energy determinations

Mass spectrum (electron ionization)

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, References, Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Data compiled by: NIST Mass Spectrometry Data Center, William E. Wallace, director

Spectrum

Notice: This spectrum may be better viewed with a Javascript and HTML 5 enabled browser.

For Zoom

1.) Enter the desired X axis range (e.g., 100, 200)

2.) Check here for automatic Y scaling

3.) Press here to zoom

Additional Data

References

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), Notes

Data compilation copyright by the U.S. Secretary of Commerce on behalf of the U.S.A. All rights reserved.

Martinho Simões
Martinho Simões, J.A., Private communication (see http://webbook.nist.gov/chemistry/om/). [all data]

Cavell and Pilcher, 1977
Cavell, K.J.; Pilcher, G., J. Chem. Soc. Faraday Trans. I, 1977, 73, 1590. [all data]

Hill and Irving, 1966
Hill, J.O.; Irving, R.J., J. Chem. Soc. (A), 1966, 971.. [all data]

Teghil, Ferro, et al., 1981
Teghil, R.; Ferro, D.; Bencivenni, L.; Pelino, M., A thermodynamic study of the sublimation processes of aluminum and copper acetylacetonates, Thermochim. Acta, 1981, 44, 213-222. [all data]

Grinberg, Lazarev, et al., 1986
Grinberg, Ya.Kh.; Lazarev, V.B.; Zavernyaev, A.Yu.; Shreider, V.A.; Chepik, S.D., Enthalpies of fusion of aluminium(III), chromium(III), zirconium(IV), and zinc(II) acetylacetonates, Zhur. Fiz. Khim., 1986, 60, 1044. [all data]

Murray and Hill, 1983
Murray, J.P.; Hill, J.O., DSC determination of the fusion and sublimation enthalpy of bis(2,4-pentanedionato)beryllium(II) and tris(2,4-pentanedionato)aluminium(III), Thermochim. Acta, 1983, 63, 211. [all data]

Grinberg, Lazarev, et al., 1986, 2
Grinberg, Ya.Kh.; Lazarev, V.B.; Zavernyaev, A.Yu.; Shreider, V.A.; Chepik, S.D., Zh. Fiz. Khim., 1986, 60, 1386. [all data]

Semyannikov, Igumenov, et al., 2006
Semyannikov, P.P.; Igumenov, I.K.; Trubin, S.V.; Chusova, T.P.; Semenova, Z.I., Thermodynamics of sublimation of aluminium triacetylacetonate, Thermochimica Acta, 2006, 451, 1-2, 80-83, https://doi.org/10.1016/j.tca.2006.08.008 . [all data]

Naghibi-Bidokhti, 1977
Naghibi-Bidokhti, H., , Ph.D. Thesis, University of Surrey, 1977. [all data]

da Silva and Ferrao, 1988
da Silva, M.A.V. Ribeiro; Ferrao, Maria Luisa C.C.H., Energetics of metal-oxygen bonds in metal complexes of β-diketones, Polym. J., 1988, 60, 8, https://doi.org/10.1351/pac198860081225 . [all data]

Irving and Ribeiro da Silva, 1975
Irving, R.J.; Ribeiro da Silva, M.A.V., J. Chem. Soc., Dalton Trans., 1975, 1257.. [all data]

Irving and da Silva, 1975
Irving, Roger J.; da Silva, Manuel A.V. Ribeiro, Thermochemistry of tri(tropolonato)- and tri(4-methyltropolonato)-aluminium(III), J. Chem. Soc., Dalton Trans., 1975, 13, 1257, https://doi.org/10.1039/dt9750001257 . [all data]

Siddiqi, Siddiqui, et al., 2007
Siddiqi, M. Aslam; Siddiqui, Rehan A.; Atakan, Burak, Thermal stability, sublimation pressures and diffusion coefficients of some metal acetylacetonates, Surface and Coatings Technology, 2007, 201, 22-23, 9055-9059, https://doi.org/10.1016/j.surfcoat.2007.04.036 . [all data]

Fahlman and Barron, 2000
Fahlman, Bradley D.; Barron, Andrew R., Substituent effects on the volatility of metal ?-diketonates, Adv. Mater. Opt. Electron., 2000, 10, 3-5, 223-232, https://doi.org/10.1002/1099-0712(200005/10)10:3/5<223::AID-AMO411>3.0.CO;2-M . [all data]

Lazarev, Greenberg, et al., 1988
Lazarev, V.B.; Greenberg, J.H.; Ozerova, Z.P.; Sharpataya, G.A., DSC and vapour pressure investigation of some β-diketonates, Journal of Thermal Analysis, 1988, 33, 3, 797-799, https://doi.org/10.1007/BF02138589 . [all data]

Volkov, Mazurenko, et al., 1978
Volkov, S.V.; Mazurenko, E.A.; Bublik, Z.N., Effect of the nature of substituents in β-diketonates on their thermodynamic characteristics, Str., Svoistva Primen. β [Beta]-Diketonatov Met., [Mater. Vses. Semin.], 3rd, V.I. Spitsyn, ed(s)., 1978, 119-122. [all data]

Fontaine, Pommier, et al., 1972
Fontaine, R.; Pommier, C.; Guiochon, G., Bull. Soc. Chim. Fr., 1972, 8, 3011. [all data]

Berg and Truemper, 1960
Berg, Eugene W.; Truemper, Joseph T., A STUDY OF THE VOLATILE CHARACTERISTICS OF VARIOUS METAL β-DIKETONE CHELATES, J. Phys. Chem., 1960, 64, 4, 487-490, https://doi.org/10.1021/j100833a029 . [all data]

Berg and Truemper, 1965
Berg, Eugene W.; Truemper, Joseph T., Vapor pressure-temperature data for various metal β-diketone chelates, Analytica Chimica Acta, 1965, 32, 245-252, https://doi.org/10.1016/S0003-2670(00)88930-8 . [all data]

Sabolovic, Mrak, et al., 2004
Sabolovic, Jasmina; Mrak, Zeljko; Kostrun, Sanja; Janekovic, August, Is the Enthalpy of Fusion of Tris(acetylacetonato)metal(III) Complexes Affected by Their Potential Energy in the Crystal State?, Inorg. Chem., 2004, 43, 26, 8479-8489, https://doi.org/10.1021/ic048900u . [all data]

Beech and Lintonbon, 1971
Beech, Graham; Lintonbon, Roger M., Thermal and kinetic studies of some complexes of 2,4-pentanedione, Thermochimica Acta, 1971, 3, 2, 97-105, https://doi.org/10.1016/0040-6031(71)80003-5 . [all data]

Akopyan, Vovna, et al., 1990
Akopyan, M.E.; Vovna, V.I.; Kleimenov, S.N.; Lopatin, S.N.; Ustinov, A.Yu., Photoelectron spectroscopy of aluminum, chromium, and iron tris-B-diketonates, Opt. Spectrosc., 1990, 69, 53. [all data]

Westmore, Reimer, et al., 1981
Westmore, J.B.; Reimer, M.L.J.; Reichert, C., Ionization energies of metal chelates. Acetylacetonates, trifluoroacetylacetonates, and hexafluoroacetylacetonates of trivalent metals of the first transition series, Can. J. Chem., 1981, 59, 1797. [all data]

Schildcrout, Pearson, et al., 1968
Schildcrout, S.M.; Pearson, R.G.; Stafford, F.E., Ionization potentials of tris(-diketonate)metal(III) complexes and Koopmans' theorem, J. Am. Chem. Soc., 1968, 90, 4006. [all data]

Bancroft, Reichert, et al., 1968
Bancroft, G.M.; Reichert, C.; Westmore, J.B., Mass spectral studies of metal chelates. II. Mass spectra and appearance potentials of acetylacetonates of trivalent metals of the first transition series, Inorg. Chem., 1968, 7, 870. [all data]

Notes

Go To: Top, Gas phase thermochemistry data, Condensed phase thermochemistry data, Phase change data, Gas phase ion energetics data, Mass spectrum (electron ionization), References

• Symbols used in this document:
  

  AE	Appearance energy
  Cp,solid	Constant pressure heat capacity of solid
  S°solid,1 bar	Entropy of solid at standard conditions (1 bar)
  Tfus	Fusion (melting) point
  ΔfH°gas	Enthalpy of formation of gas at standard conditions
  ΔfH°solid	Enthalpy of formation of solid at standard conditions
  ΔfusH	Enthalpy of fusion
  ΔfusS	Entropy of fusion
  ΔsubH	Enthalpy of sublimation
  ΔsubH°	Enthalpy of sublimation at standard conditions
  ΔvapH°	Enthalpy of vaporization at standard conditions

• Data from NIST Standard Reference Database 69: NIST Chemistry WebBook
• The National Institute of Standards and Technology (NIST) uses its best efforts to deliver a high quality copy of the Database and to verify that the data contained therein have been selected on the basis of sound scientific judgment. However, NIST makes no warranties to that effect, and NIST shall not be liable for any damage that may result from errors or omissions in the Database.
• Customer support for NIST Standard Reference Data products.